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CAI combustion has the potential to be the most clean combustion technology in internal combustion engines and is being intensively researched. Following the previous research on CAI combustion of gasoline fuel, systematic investigation is being carried out on the application of bio-fuels in CAI combustion. As part of an on-going research project, CAI combustion of methanol and ethanol was studied on a single-cylinder direct gasoline engine with an air-assisted injector. The CAI combustion was achieved by trapping part of burnt gas within the cylinder through using short-duration camshafts and early closure of the exhaust valves. During the experiment the engine speed was varied from 1200rpm to 2100rpm and the air/fuel ratio was altered from the stoichiometry to the misfire limit. Their combustion characteristics were obtained by analysing cylinder pressure trace.