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Technical Paper

Combustion Characteristics of PRF and TSF Ethanol Blends with RON 98 in an Instrumented CFR Engine

2018-09-10
2018-01-1672
The CFR F1 engine is the standard testing apparatus used for rating the research octane number (RON) of gasoline fuels. Unlike the motor octane number (MON) method, where the intake port temperature after the carburetor is controlled by an electric heater, the mixture temperature can vary during the RON test due to the heat of vaporization (HoV) of the fuel. Ethanol is receiving increasing attention as a high octane and high HoV fuel component. This work presents an analysis of the combustion characteristics during the RON rating of ethanol fuel blends according to the standard ASTM D2699 method, highlighting the effects of ethanol concentration and base fuel composition. All fuels were blended to a constant RON of 98. Ethanol levels varied from 0 to 50 vol% and the base fuels were surrogate blends composed of primary reference fuels (PRF), toluene standardization fuels (TSF), and a four component gasoline surrogate.
Technical Paper

Comprehensive Cradle to Grave Life Cycle Analysis of On-Road Vehicles in the United States Based on GREET

2024-04-09
2024-01-2830
To properly compare and contrast the environmental performance of one vehicle technology against another, it is necessary to consider their production, operation, and end-of-life fates. Since 1995, Argonne’s GREET® life cycle analysis model (Greenhouse gases, Regulated Emissions, and Energy use in Technologies) has been annually updated to model and refine the latest developments in fuels and materials production, as well as vehicle operational and composition characteristics. Updated cradle-to-grave life cycle analysis results from the model’s latest release are described for a wide variety of fuel and powertrain options for U.S. light-duty and medium/heavy-duty vehicles. Light-duty vehicles include a passenger car, sports utility vehicle (SUV), and pick-up truck, while medium/heavy-duty vehicles include a Class 6 pickup-and-delivery truck, Class 8 day-cab (regional) truck, and Class 8 sleeper-cab (long-haul) truck.
Technical Paper

Defining the Boundary Conditions of the CFR Engine under MON Conditions, and Evaluating Chemical Kinetic Predictions at RON and MON for PRFs

2021-04-06
2021-01-0469
Expanding upon the authors’ previous work which utilized a GT-Power model of the Cooperative Fuels Research (CFR) engine under Research Octane Number (RON) conditions, this work defines the boundary conditions of the CFR engine under Motored Octane Number (MON) test conditions. The GT-Power model was validated against experimental CFR engine data for primary reference fuel (PRF) blends between 60 and 100 under standard MON conditions, defining the full range of interest of MON for gasoline-type fuels. The CFR engine model utilizes a predictive turbulent flame propagation sub-model, and a chemical kinetic solver for the end-gas chemistry. The validation was performed simultaneously for thermodynamic and chemical kinetic parameters to match in-cylinder pressure conditions, burn rate, and knock point prediction with experimental data, requiring only minor modifications to the flame propagation model from previous model iterations.
Technical Paper

Development and Validation of a Three Pressure Analysis (TPA) GT-Power Model of the CFR F1/F2 Engine for Estimating Cylinder Conditions

2018-04-03
2018-01-0848
The CFR engine is the widely accepted platform to test standard Research Octane Number (RON) and Motored Octane Number (MON) for determining anti-knock characteristics of motor fuels. With increasing interest in engine downsizing, up-torquing, and alternative fuels for modern spark ignition (SI) engines, there is a need to better understand the conditions that fuels are subjected to in the CFR engine during octane rating. To take into account fuel properties, such as fuel heat of vaporization, laminar flame speed and auto-ignition chemistry; and understand their impacts on combustion knock, it is essential to estimate accurate cylinder conditions. In this study, the CFR F1/F2 engine was modeled using GT-Power with the Three Pressure Analysis (TPA) and the model was validated for different fuels and engine conditions.
Journal Article

Development of a Supercharged Octane Number and a Supercharged Octane Index

2023-04-11
2023-01-0251
Gasoline knock resistance is characterized by the Research and Motor Octane Number (RON and MON), which are rated on the CFR octane rating engine at naturally aspirated conditions. However, modern automotive downsized boosted spark ignition (SI) engines generally operate at higher cylinder pressures and lower temperatures relative to the RON and MON tests. Using the naturally aspirated RON and MON ratings, the octane index (OI) characterizes the knock resistance of gasolines under boosted operation by linearly extrapolating into boosted “beyond RON” conditions via RON, MON, and a linear regression K factor. Using OI solely based on naturally aspirated RON and MON tests to extrapolate into boosted conditions can lead to significant errors in predicting boosted knock resistance between gasolines due to non-linear changes in autoignition and knocking characteristics with increasing pressure conditions.
Journal Article

Effect of Intake Temperature and Engine Speed on the Auto-Ignition Reactivity of the Fuels for HCCI Fuel Rating

2021-04-06
2021-01-0510
The current research octane number (RON) and motor octane number (MON) gasoline tests are inadequate for describing the auto-ignition reactivity of fuels in homogeneous charge compression ignition (HCCI) combustion. Intake temperature and engine speed are two important parameters when trying to understand the fuel auto-ignition reactivity in HCCI combustion. The objective of this study was to understand the effect of high intake temperature (between 100 and 200 °C) and engine speed (600 and 900 rpm) on the auto-ignition HCCI reactivity ratings of fuels using an instrumented Cooperative Fuel Research (CFR) engine. The fuels used for this study included blends of iso-octane/n-heptane, toluene/n-heptane, ethanol/n-heptane, and gasolines with varying chemical compositions and octane levels. The CFR engine was operated at 600 and 900 rpm with an intake pressure of 1.0 bar and an excess air ratio (lambda) of 3.
Journal Article

Effects of Fuel Laminar Flame Speed Compared to Engine Tumble Ratio, Ignition Energy, and Injection Strategy on Lean and EGR Dilute Spark Ignition Combustion

2017-03-28
2017-01-0671
Previous studies have shown that fuels with higher laminar flame speed also have increased tolerance to EGR dilution. In this work, the effects of fuel laminar flame speed on both lean and EGR dilute spark ignition combustion stability were examined. Fuels blends of pure components (iso-octane, n-heptane, toluene, ethanol, and methanol) were derived at two levels of laminar flame speed. Each fuel blend was tested in a single-cylinder spark-ignition engine under both lean-out and EGR dilution sweeps until the coefficient of variance of indicated mean effective pressure increased above thresholds of 3% and 5%. The relative importance of fuel laminar flame speed to changes to engine design parameters (spark ignition energy, tumble ratio, and port vs. direct injection) was also assessed.
Journal Article

Effects of Lambda on Knocking Characteristics and RON Rating

2019-04-02
2019-01-0627
The knock resistance of fuels has been historically measured using the ASTM RON and MON methods. However, significant discrepancies between the fuel octane number and knock-limited performance in modern spark-ignited (SI) engines have been well-documented. Differences between the operating conditions of the Cooperative Fuels Research (CFR) engine during RON rating and those attained in modern SI engines have been highlighted in the literature. While octane ratings are performed for each fuel on the CFR engine at the lambda that provides the highest knockmeter reading, modern SI engines are generally operated at stoichiometry and knock intensity is based on the high frequency cylinder pressure oscillations associated with knocking combustion. In the present work, an instrumented CFR engine was used to analyze lambda effects on both the conventional knockmeter RON rating method and cylinder pressure transducer based knock intensity.
Technical Paper

Evaluation of Ignition Timing Predictions Using Control-Oriented Models in Kinetically-Modulated Combustion Regimes

2012-04-16
2012-01-1136
Knock integrals and corresponding ignition delay (τ) correlations are often used in model-based control algorithms in order to predict ignition timing for kinetically modulated combustion regimes such as HCCI and PCCI. They can also be used to estimate knock-inception during conventional SI operation. The purpose of this study is to investigate the performance of various τ correlations proposed in the literature, including those developed based on fundamental data from shock tubes and rapid compression machines, those based on predictions from isochoric simulations using detailed chemical kinetic mechanisms, and those deduced from data of operating engines. A 0D engine simulation framework is used to compare the correlation performance where evaluations are based on the temperatures required at intake valve closure (TIVC) in order to achieve a fixed CA50 point over a range of conditions.
Technical Paper

Hydrocarbon Speciation in Blended Gasoline-Natural Gas Operation on a Spark-Ignition Engine

2016-10-17
2016-01-2169
The high octane rating and more plentiful domestic supply of natural gas make it an excellent alternative to gasoline. Recent studies have shown that using natural gas in dual fuel engines provides one possible strategy for leveraging the advantages of both natural gas and gasoline. In particular, such engines been able to improve overall engine efficiencies and load capacity when they leverage direct injection of the natural gas fuel. While the benefits of these engine concepts are still being explored, differences in fuel composition, combustion process and in-cylinder mixing could lead to dramatically different emissions which can substantially impact the effectiveness of the engine’s exhaust aftertreatment system. In order to explore this topic, this study examined the variations in speciated hydrocarbon emissions which occur for different fuel blends of E10 and compressed natural gas and for different fuel injection strategies on a spark-ignition engine.
Journal Article

Insights into Engine Knock: Comparison of Knock Metrics across Ranges of Intake Temperature and Pressure in the CFR Engine

2018-04-03
2018-01-0210
Of late there has been a resurgence in studies investigating parameters that quantify combustion knock in both standardized platforms and modern spark-ignition engines. However, it is still unclear how metrics such as knock (octane) rating, knock onset, and knock intensity are related and how fuels behave according to these metrics across a range of conditions. As part of an ongoing study, the air supply system of a standard Cooperative Fuel Research (CFR) F1/F2 engine was modified to allow mild levels of intake air boosting while staying true to its intended purpose of being the standard device for American Society for Testing and Materials (ASTM)-specified knock rating or octane number tests. For instance, the carburation system and intake air heating manifold are not altered, but the engine was equipped with cylinder pressure transducers to enable both logging of the standard knockmeter readout and state-of-the-art indicated data.
Technical Paper

Numerical Investigation of the Impact of Fuel Injection Strategies on Combustion and Performance of a Gasoline Compression Ignition Engine

2021-04-06
2021-01-0404
Gasoline compression ignition is a promising strategy to achieve high thermal efficiency and low emissions with limited modifications to the conventional diesel engine hardware. It is a partially premixed concept which derives its superiority from higher volatility and longer ignition delay of gasoline-like fuels combined with higher compression ratio typical of diesel engines. The present study investigates the combustion process in a gasoline compression ignition engine using computational fluid dynamics. Simulations are carried out on a single cylinder of a multi cylinder heavy-duty compression ignition engine which operates at a compression ratio of 17:1 and an engine speed of 1038 rev/min. In this study, a late fuel injection strategy is used because it is less sensitive to combustion kinetics compared to early injection strategies, which in turn is a better choice to assess the performance of the spray model.
Technical Paper

Optimizing Thermal Efficiency of a Multi-Cylinder Heavy Duty Engine with E85 Gasoline Compression Ignition

2019-04-02
2019-01-0557
Gasoline compression ignition (GCI) using a single gasoline-type fuel for direct/port injection has been shown as a method to achieve low-temperature combustion with low engine-out NOx and soot emissions and high indicated thermal efficiency. However, key technical barriers to achieving low temperature combustion on multi-cylinder engines include the air handling system (limited amount of exhaust gas recirculation (EGR)) as well as mechanical engine limitations (e.g. peak pressure rise rate). In light of these limitations, high temperature combustion with reduced amounts of EGR appears more practical. Previous studies with 93 AKI gasoline demonstrated that the port and direct injection strategy exhibited the best performance, but the premature combustion event prevented further increase in the premixed gasoline fraction and efficiency.
Technical Paper

Quantifying Uncertainty in Predictions of Kinetically Modulated Combustion: Application to HCCI Using a Detailed Transportation Fuel Model

2018-04-03
2018-01-1251
Simulation of chemical kinetic processes in combustion engine environments has become ubiquitous towards the understanding of combustion phenomenology, the evaluation of controlling parameters, and the design of configurations and/or control strategies. Such calculations are not free from error however, and the interpretation of simulation results must be considered within the context of uncertainties in the chemical kinetic model. Uncertainties arise due to structural issues (e.g., included/missing reaction pathways), as well as inaccurate descriptions of kinetic rate parameters and thermochemistry. In fundamental apparatuses like rapid compression machines and shock tubes, computed constant-volume ignition delay times for simple, single-component fuels can have variations on the order of factors of 2-4.
Journal Article

Reduced Order Modeling of Engine Transients for Gasoline Compression Ignition Combustion Control

2020-09-15
2020-01-2000
This work focuses on reducing the computational effort of a 0-dimensional combustion model developed for compression ignition engines operating on gasoline-like fuels. As in-cylinder stratification significantly contributes to the ignition delay, which in turn substantially influences the entire gasoline compression ignition combustion process, previous modeling efforts relied on the results of a 1-dimensional spray model to estimate the in-cylinder fuel stratification. Insights obtained from the detailed spray model are leveraged within this approach and applied to a reduced order model describing the spray propagation. Using this computationally efficient combustion model showed a reduction in simulation time by three orders of magnitude for an entire engine cycle over the combustion model with the 1-dimensional spray model.
Technical Paper

Residual Gas Fraction Measurement and Estimation of the CFR Octane Rating Engine Operating Under HCCI Conditions

2023-09-29
2023-32-0010
The autoignition chemistry of fuels depends on the pressure, temperature, and time history that the fuel-air mixture experiences during the compression stroke. While piezoelectric pressure transducers offer excellent means of pressure measurement, temperature measurements are not commonly available and must be estimated. Even if the pressure and temperature at the intake and exhaust ports are measured, the residual gas fraction (RGF) within the combustion chamber requires estimation and greatly impacts the temperature of the fresh charge at intake valve closing. This work replaced the standard D1 Detonation Pickup of a CFR engine with a rapid sampling valve to allow for in-cylinder gas sampling at defined crank-angle times during the compression stroke. The extracted cylinder contents were captured in an emissions sample bag and its composition was subsequently analyzed in an AVL i60 emissions bench.
Technical Paper

The Impact of Fuel Injection Strategies and Compression Ratio on Combustion and Performance of a Heavy-Duty Gasoline Compression Ignition Engine

2022-08-30
2022-01-1055
Gasoline compression ignition using a single gasoline-type fuel has been shown as a method to achieve low-temperature combustion with low engine-out NOx and soot emissions and high indicated thermal efficiency. However, key technical barriers to achieving low temperature combustion on multi-cylinder engines include the air handling system (limited amount of exhaust gas recirculation) as well as mechanical engine limitations (e.g. peak pressure rise rate). In light of these limitations, high temperature combustion with reduced amounts of exhaust gas recirculation appears more practical. Furthermore, for high temperature Gasoline compression ignition, an effective aftertreatment system allows high thermal efficiency with low tailpipe-out emissions. In this work, experimental testing was conducted on a 12.4 L multi-cylinder heavy-duty diesel engine operating with high temperature gasoline compression ignition combustion using EEE gasoline.
Journal Article

Towards Developing an Unleaded High Octane Test Procedure (RON>100) Using Toluene Standardization Fuels (TSF)

2020-09-15
2020-01-2040
An increase in spark-ignition engine efficiency can be gained by increasing the engine compression ratio, which requires fuels with higher knock resistance. Oxygenated fuel components, such as methanol, ethanol, isopropanol, or iso-butanol, all have a Research Octane Number (RON) higher than 100. The octane numbers (ON) of fuels are rated on the CFR F1/F2 engine by comparing the knock intensity of a sample fuel relative to that of bracketing primary reference fuels (PRF). The PRFs are a binary blend of iso-octane, which is defined to an ON of 100, and n-heptane, which represents an ON of 0. Above 100 ON, the PRF scale continues by adding diluted tetraethyl lead (TEL) to iso-octane. However, TEL is banned from use in commercial gasoline because of its toxicity. The ASTM octane number test methods have a “Fit for Use” test that validate the CFR engine’s compliance with the octane testing method by verifying the defined ON of toluene standardization fuels (TSF).
Technical Paper

Transmission Shifting Analysis and Model Validation for Medium Duty Vehicles

2023-04-11
2023-01-0196
Over the past couple of years, Argonne National Laboratory has tested, analyzed, and validated automobile models for the light duty vehicle class, including several types of powertrains including conventional, hybrid electric, plug-in hybrid electric and battery electric vehicles. Argonne’s previous works focused on the light duty vehicle models, but no work has been done on medium and heavy-duty vehicles. This study focuses on the validation of shifting control in advanced automatic transmission technologies for medium duty vehicles by using Argonne’s model-based high-fidelity, forward-looking, vehicle simulation tool, Autonomie. Different medium duty vehicles, from Argonne’s own fleet, including the Ram 2500, Ford F-250 and Ford F-350, were tested with the equipment for OBD (on-board diagnostics) signal data record. For the medium duty vehicles, a workflow process was used to import test data.
Journal Article

Zero Dimension Heat Release Modeling for Gasoline, Ethanol, Isobutanol and Diisobutylene Operating in Compression Ignition with Varying Injection Strategies

2023-04-11
2023-01-0188
Gasoline compression ignition shows great potential in reducing NOx and soot emissions with competitive thermal efficiency by leveraging the properties of gasoline fuels and the high compression ratio of compression ignition engines operating air-dilute. Meanwhile, its control becomes challenging due to not only the properties of different gasoline-type fuels but also the impacts of injection strategies on the in-cylinder reactivity. As such, a computationally efficient zero-dimension combustion model can significantly reduce the cost of control development. In this study, a previously developed zero-dimension combustion model for gasoline compression ignition was extended to multiple gasoline-type fuel blends and a port fuel injection/direct fuel injection strategy. Tests were conducted on a 12.4-liter heavy-duty engine with five fuel blends.
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