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A detailed study is undertaken to examine how 2010+ diesel engine exhaust emissions change when a soybean-derived B20 biodiesel fuel is used instead of a conventional ultra-low sulfur diesel fuel and to investigate how these changes impact the aftertreatment system. Particulate matter (PM) emissions for each fuel are characterized in terms of mass emissions, size distributions, organic versus soot fraction, metals content, and particle morphology. PM mass recorded by Dekati Mass Monitor, thermal analysis of quartz filters, and calculated from particle size distributions consistently shows a 2 - 3 fold decrease in engine-out soot emissions over a wide mid-load range when changing from ULSD to B20 fuel. This is partly due to a decrease in particle number and partly to a decrease in average size. HC and NO emissions, in contrast, exhibit little change with fuel type.

Two different implementations of Partial Flow Dilution (PFD) methodology designed for gravimetric particulate matter (PM) sampling are evaluated for applicability to light-duty chassis emissions testing. Filter PM measurements were collected and compared to constant volume sampler (CVS) full dilution tunnel PM filter measurements and other real-time PM measurement technologies, using gasoline vehicles generating a range of 0.1 to 10.0 mg/mile PM. Exhaust samples were collected for each phase of the Federal Test Procedure (FTP-75) with a fourth filter sample collected for the US06 supplemental cycle. Both PFDs satisfactorily met proportionality criteria for conventional combustion engines, but some improvements are needed for hybrid electric vehicles (HEVs). The PM mass collected scaled linearly with the CVS tunnel samples, with slopes of 1.03 and 0.74 for the two PFDs.

Particle number emissions are measured with two instruments according to the upcoming European emission regulations for light-duty diesel passenger vehicles and compared to data from other methods, including the current regulatory total particulate matter (PM) mass, photo-acoustic soot sensor (PASS) and engine exhaust particle sizer (EEPS). At the very low emission levels of diesel particulate filter (DPF) equipped vehicles, the solid particle number data correlate well with soot mass and with particle number measured by EEPS, if only those particles belonging to the accumulation mode are considered in the latter case. PN differences of ≻100% between tests of the same vehicle are observed. Comparison of the two PN instruments and the photoacoustic soot sensor show that these are systematic differences which originate primarily with the vehicle and not from instrument uncertainties.