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To detect an air-fuel ratio in wide range is very important to control the automotive engines with low fuel consumption and low exhaust emissions. Although the application of zirconia electrolyte for this purpose has been proposed by the authors several years ago, there remained several problems due to the contamination of gas diffusion apertures which are exposed to the exhaust gas environment. Here the behavior of ions transported in zirconia electrolyte have been analyzed to optimize the structure and characteristics, and to guarantee the long life operation of sensor. Gas contents and their reactions in combustion process under the wide range air-fuel ratio have been analyzed, and these results were reflected to the analysis of ion transportation in zirconia electrolyte. Experimental results supported the analytical results, and they showed the possibilities of long life operation of zirconia air-fuel ratio sensor utilizing ion transportation phenomena.

The detection range of an air-fuel ratio sensor is expanded in the rich A/F region. Using a simulation technique, the limiting cause of the detection range in the rich A/F region is identified as insufficient combustion rates of CO and H2 with O2 on the electrode, which prevent realization of a limited diffusion state which is necessary to detect the air-fuel ratio. Applying an improved diffusion layer to decrease the diffusion rates and an improved electrode to increase the combustion rates, it is demonstrated that the detection limit can be expanded to λ=0.6 while that of a conventional sensor is λ=0.8.