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This paper reports on DaimlerChrysler's participation in the Ad Hoc Diesel Fuels Test Program. This program was initiated by the U.S. Department of Energy and included major U.S. auto makers, major U.S. oil companies, and the Department of Energy. The purpose of this program was to identify diesel fuels and fuel properties that could facilitate the successful use of compression ignition engines in passenger cars and light-duty trucks in the United States at Tier 2 and LEV II tailpipe emissions standards. This portion of the program focused on minimizing engine-out particulates and NOx by using selected fuels, (not a matrix of fuel properties,) in steady state dynamometer tests on a modern, direct injection, common rail diesel engine.

The following paper highlights the results of a vehicle emission improvement program with emphasis on two main points: In the initial phase, various combinations of Pd and Pt-based three-way catalyst technologies were evaluated on a TLEV and a LEV calibrated vehicle in order to generate ULEV exhaust gas levels. One goal in this portion of the study was to achieve technical equivalence between a viable Pd-based technology and a newly developed Pt-based technology. A combination of the Pd- and Pt-based technologies was able to meet the ULEV and part of the ULEV II regulations in the test vehicle after a catalyst aging cycle that resembles 50,000 miles of vehicle driving. In the later phase, a mathematical algorithm based on the original TLEV and LEV vehicle data was developed in order to conduct computer modeling of the exhaust gas aftertreatment system. This algorithm described the kinetic behavior of the individual catalysts over a broad range of reaction conditions.

Into the early-part of the next century, automotive emission standards are becoming stricter around the world. The electrically-heated catalyst (EHC) is well known as an effective technology for the reduction of cold-start hydrocarbon emissions without a significant increase in back pressure. Our extruded, alternator powered EHC (APEHC) manufactured with a unique canning method and equipped with a reliable, water proof electrode has demonstrated excellent durability and reliability, as stated in our previous SAE paper (#960340). The APEHC system discussed in this paper has achieved the Ultra-Low-Emission Vehicle (ULEV) standards, after 100,000 miles of fleet testing, without any failure. This is the final milestone in addressing the EHC as a realistic-production technology for ULEV. With the ability to meet ULEV/Stage III emission targets without a significant increase in back pressure, the EHC will be applied to an especially high performance vehicle with a large displacement engine.

This research is aimed at development of the catalyst for gasoline automobiles which uses only palladium (Pd) among platinum group metals (PGMs). And the conformity emission category aimed at LEV III-SULEV30. For evaluation, the improvement effect was verified for 2013 model year (MY) ACCORD (LEV II-SULEV) as the reference. As compared with Pd-rhodium (Rh) catalyst, a Pd-only catalyst had the low purification performance of nitrogen oxides (NOx), and there was a problem in the drop in dispersion of Pd by sintering, and phosphorus (P) poisoning.

Aiming for higher output power, greater fuel economy and reduced exhaust emissions, a new V-6 3.5-liter i-VTEC Variable Cylinder Management (VCM) engine has been developed. This engine uses a cylinder-deactivation mechanism with VTEC technology that allows the number of cylinders to be controlled in three modes (three, four or all six cylinders), according to the operating conditions. This adds a four-cylinder mode to the conventional cylinder- deactivation engine. In addition to increasing the number of cylinder- deactivation modes, the new hydraulic circuits, a hydraulic pressure switching mechanism and a switchover control were also developed. These make it possible to instantaneously switch the active cylinders without impairing drivability, in the same manner as a conventional engine.

The high conversion efficiency required by the modern three-way catalyst (TWC) is dependent on oxygen storage material functionality and capacity. To successfully model a TWC, it is critical that the oxygen storage function in the catalyst be adequately represented. The original oxygen storage model (a simple “bucket” model) included in one of Ford's TWC models, SIMTWC, was developed for vehicle programs meeting LEV emission standards. Application of SIMTWC to test data from vehicles targeting more stringent emission standards, such as ULEV and PZEV, revealed limitations in the accuracy of the original bucket model. To address these limitations, an improved kinetic model of oxygen storage is being developed. This new model is more kinetically-detailed than the old model.

In order to contribute to the resolution of global environmental problems and to respond to the issue of diminishing resources, the Civic Hybrid, a hybrid passenger automobile has been developed to achieve both low emissions and low fuel consumption. The hybrid system takes the conventional Honda IMA (Integrated Motor Assist) system as its foundation. 4-cylinder, 1.3L SOHC, 2-plug engine i-DSI (DSI: Dual and Sequential Ignition) has been selected and modified for lean burn combustion. In addition, a cylinder idling system to increase the amount of electrical energy regenerated during deceleration has been adopted, among other technology. The ultra-thin DC brushless motor has been modified with its magnetic circuit to improve maximum regenerative torque by approximately 30%. Thanks to a new power train that improves CVT transfer efficiency, low fuel consumption of 48mpg in the city and 47mpg on the highway (the 5MT vehicle is 46mpg in the city and 51mpg on the highway) is achieved.

With the increasing number of automobiles, the worldwide problem of air pollution is becoming more serious. The necessity of reducing tail-pipe emissions is as high as ever, and in countries all over the world the regulations are becoming stricter. The emissions at times such as after engine cold start, when the three-way catalyst (TWC) has not warmed up, accounts for the majority of the emissions of these pollutants from vehicles. This is caused by the characteristic of the TWC that if a specific temperature is not exceeded, TWC cannot purify the emissions. In other words, if the catalyst could be warmed up at an early stage after engine start, this would provide a major contribution to reducing the emissions. Therefore, this research is focused on the substrate weight and investigated carrying out major weight reduction by making the porosity of the substrate larger than that of conventional products.

Recently, automotive emission regulations are being further tightened, such as the Tier III/LEV III in the U.S. As a result, reducing cost of after-treatment systems to meet these strict regulations has become an urgent issue, and then the demand for high-precision air-fuel ratio (A/F) control which can achieve this cost reduction is high [1]. On the other hand, in order to meet rapidly changing market needs, it is becoming difficult to keep enough development periods that enable sufficient calibration by trial-and-error, such as feedback-gain calibration. This leads to an increase in three-way catalytic converter costs in some cases. For these reasons, it is necessary to construct control system that can make full use of hardware capabilities, can shorten development periods regardless of the skill level of engineers.

Measuring the real-world performance of emission control technologies is an important aspect in the development of advanced low-emission vehicles. In addition, data acquired from such measurements can be used to improve the accuracy of air quality predictive models. Honda has developed an on-board sampling/analysis system capable of measuring on-road emissions at ULEV levels and below. Ambient air can be analyzed simultaneously. This FTIR-based system can measure several species; this paper will focus on NMHC, NOX, and CO. Techniques were developed to address the challenges associated with acquiring accurate real-time data at concentrations below 1 ppm in an on-road vehicle. Validation studies performed with reference gases and vehicle exhaust indicate a very good correlation between the on-road analyzer system and classic bench methods for all target compounds. Dynamic studies performed by the University of California, Riverside, also show good correlation.

The Automotive Industry/Government Emissions Research CRADA (AIGER) has been working to develop a new methodology for the direct determination of nonmethane hydrocarbons (DNMHC) in vehicle testing. This new measurement technique avoids the need for subtraction of a separately determined methane value from the total hydrocarbon measurement as is presently required by the Code of Federal Regulations. This paper will cover the historical aspects of the development program, which was initiated in 1993 and concluded in 2002. A fast, gas chromatographic (GC) column technology was selected and developed for the measurement of the nonmethane hydrocarbons directly, without any interference or correction being caused by the co-presence of sample methane. This new methodology chromatographically separates the methane from the nonmethane hydrocarbons, and then measures both the methane and the backflushed, total nonmethane hydrocarbons using standard flame ionization detection (FID).

The two liter DOHC-VTEC engine developed for the Honda S2000 produces 179kW (240HP, which is 120HP per liter). It is the highest output power among all naturally aspirated two liter engines ever mass-produced. It also achieves an exhaust emission level within National LEV standards. The new engine utilizes a redesigned VTEC cylinder head, in which MIM (metal injection molding) rocker arms are used. The new cylinder block with a ladder frame structure for its lower part, a newly developed camshaft drive chain and gear system and a metal honeycomb catalyst with an air pump start-up system are also utilized.

With the total amount of air pollution caused by vehicle emissions on the increase, the problem has now became a global concern, and various regulatory measures have been put into effect in each region of the world. This is especially true in California, U.S.A, where countermeasures have been adopted early. There, the ULEV (Ultra Low Emission Vehicle) standard, which was ones deemed impossible for gasoline engines to meet, is now in effect. In response to these developments, Honda announced the ULEV system for a 2.2 liter gasoline engine with a closed-coupled catalytic converter (CC) and an under-floor catalytic converter (UF) at the beginning of 1995, and reported on the system's emission characteristics. 1) A new ULEV system has been developed based on the previous system but using only UF, aiming for marketable improvements in product characteristics such as higher output. The new system features the ultra low heat capacity and high heat insulating (ULOC) exhaust manifold.

With the adoption of the California Low-Emission Vehicle Regulations and the associated lower emission standards such as LEV (Low-Emission Vehicle in 1990), ULEV (Ultra-Low-Emission Vehicle), and LEV II (1998 with SULEV-Super Ultra Low Emission Vehicle), concerns were raised by emissions researchers over the accuracy and reliability of collecting and analyzing emissions measurements at such low levels. The primary concerns were water condensation, optimizing dilution ratios, and elimination of background contamination. These concerns prompted a multi-year research program looking at several new sampling techniques. This paper will describe the cooperative research conducted into one of these new technologies, namely the Bag Mini-Diluter (BMD) and Direct Vehicle Exhaust (DVE) Volume system.

Future vehicle North American emissions standards (e.g., North American Tier 3 Bin 30 or LEVIII SULEV 30) require the exhaust catalyst to be greater than 80% efficient by 20 seconds after the engine has been started in the Federal Test Procedure. Turbocharged engines are especially challenged to deliver fast catalyst light-off since the presence of the turbocharger in the exhaust flow path significantly increases exhaust system heat losses. A solution to delivering cost effective SULEV 30 emissions in turbocharged engines is to achieve fast catalyst light-off by reducing exhaust system heat losses in cold start, without increasing catalyst thermal degradation during high load operation. A CAE methodology to assess the thermal performance of exhaust system hardware options, from the exhaust port to the catalyst brick face is described, which enables compliance with future emissions regulations.

The Flame Ionization Detector (FID) used to measure hydrocarbon content in emission samples uses a hydrogen flame that produces little ionization. Hydrocarbons introduced into this flame produce large numbers of ions with ionization proportional to the number of carbon atoms present. This proportionality can be skewed by variations in oxygen content. Oxygen variation in emission samples, cylinders of air or span/calibration gas, and zero air systems are investigated and their effects on emission results are discussed. The oxygen content of the gas under analysis will affect the hydrocarbon concentration reported by the FID. In the example examined in this paper, the oxygen effect was shown to decrease the FTP (Federal Test Procedure) weighted NMHC (Non-Methane Hydrocarbon) results by as much as 7 % for a BMD (Bag Mini-Diluter) sample and 13% for a CVS (Constant Volume Sampling) sample.

The College of Engineering-Center for Environmental Research and Technology at the University of California, Riverside and Honda Motor Company are conducting a cooperative research program to study the emission characteristics and evaluate the environmental impact of advanced technology vehicles designed to have emission rates at, or below, the California ULEV standard. This program involves a number of technical challenges relating to instrumentation capable of measuring emissions at these low levels and utilizing this instrumentation to gather data under realistic conditions that will allow assessments of the environmental impact of these advanced vehicle technologies. This paper presents results on the performance and suitability of a Fourier Transform Infrared (FTIR) based on-board measurement system developed principally by Honda R&D for this task. This system has been designed to simultaneously measure vehicle exhaust and ambient roadway pollutant concentrations.

This paper examines the issues concerning particulate matter (PM) emissions measurement at the 3 mg/mi level proposed as the future LEV III standard. These issues are general in nature, but are exacerbated at the low levels contemplated for upcoming emissions standards. They are discussed in the context of gasoline direct injection (GDI) engines, where they can have an important impact on the continued development of this technology for improved fuel economy. GDI particulate emissions, just as engine-out diesel PM, contain a high fraction of soot. But the total PM mass is significantly lower than from diesel engines, and there can be significant variations in emissions rate and apparent PM composition between cold-start and running emissions. PM emissions levels depend on sampling method and location. As a result, there can be substantial differences in PM sampled and diluted directly at the exhaust pipe, as opposed to measurements from a dilution tunnel.

Honda has developed a new hybrid system targeting the C and D segments that aims for the latest environmental performance, high fuel economy, and enhanced acceleration feeling in driving. The new engine to be applied to this new hybrid system has been developed with the goal of expanding the high thermal efficiency range, realizing the latest environmental performance, and high quietness. The new engine has adopted the Atkinson cycle and cooled exhaust gas recirculation (EGR) carried over from the previous model [1], and employed an in-cylinder direct fuel injection system with fuel injection pressure of 35 MPa. The combustion chamber and ports have been newly designed to match the fuel system changes. By realizing high-speed combustion, the engine realized a high compression ratio with the mechanical compression ratio of 13.9.

The future of diesel-engine-powered passenger cars and light-duty vehicles in the United States depends on their ability to meet Federal Tier 2 and California LEV2 tailpipe emission standards. The experimental purpose of this work was to examine the potential role of fuels; specifically, to determine the sensitivity of engine-out NOx and particulate matter (PM) to gross changes in fuel formulation. The fuels studied were a market-average California baseline fuel and three advanced low sulfur fuels (<2 ppm). The advanced fuels were a low-sulfur-highly-hydrocracked diesel (LSHC), a neat (100%) Fischer-Tropsch (FT100) and 15% DMM (dimethoxy methane) blended into LSHC (DMM15). The fuels were tested on modern, turbocharged, common-rail, direct-injection diesel engines at DaimlerChrysler, Ford and General Motors. The engines were tested at five speed/load conditions with injection timing set to minimize fuel consumption.