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Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO₃ (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn⁴+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/γ-Al₂O₃ (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO₂).

Currently, two consolidated aftertreatment technologies are available for the reduction of NOx emissions from diesel engines: Urea SCR (Selective Catalytic Reduction) systems and LNT (Lean NOx Trap) systems. Urea SCR technology, which has been widely used for many years at stationary sources, is becoming nowadays an attractive alternative also for light-duty diesel applications. However, SCR systems are much more effective in NOx reduction efficiency at high load operating conditions than light load condition, characterized by lower exhaust gas temperatures.

Glass fiber reinforced plastic of polyamide is applied as one of the materials used for the high strength exterior parts of a motorcycle, such as a rear grab rail or a carrier, to which both strength and good exterior appearance are required. However, Glass Fiber reinforced Polypropylene (PPGF), which is relatively inexpensive material, has a property that the contained glass fibers are prone to be exposed at the surface and, therefore, the requirements for good appearance are hardly met by using PPGF. In this study, Heat and Cool molding method (H&C molding) was employed to realize a cost reduction by using PPGF yet without applying painting process, and the established method was applied to mass production while fulfilling the requirements for a good exterior appearance. In H&C molding, the metal molds are heated up by steam and cooled down by water after molding.

The atomization of molten aluminum when injected during high-pressure die casting is analyzed to determine its effect in enhancing the strength of the product being cast. In the previously reported first step of this study, molten aluminum was injected into open space and its atomization was observed photographically. Now in the second step of the study, a simulation is conducted to determine how the molten aluminum becomes atomized at the injection nozzle (gate) and how this atomized material flows and fills the cavity. A new simulation method is developed based on large-eddy simulation coupled with the volume-of-fluid method. The simulation system is verified by comparing its output with photographs taken in the first step of the study. Simulations are then conducted using an approximation of a real cavity to visualize how it is filled by the atomized molten aluminum.

High-tensile steel plates and lightweight aluminum are being employed as materials in order to achieve weight savings in automotive subframe. Closed-section structures are also in general use today in order to efficiently increase parts stiffness in comparison to open sections. Aluminum hollow-cast subframe have also been brought into practical use. Hollow-cast subframe are manufactured using sand cores in gravity die casting (GDC) or low-pressure die casting (LPDC) processes. Using these manufacturing methods, it is difficult to reduce product thickness, and the limitations of the methods therefore make the achievement of weight reductions a challenge. The research discussed in this paper developed a lightweight, hollow subframe technology employing high-pressure die casting (HPDC), a method well-suited to reducing wall thickness, as the manufacturing method. Hollow-casting using HPDC was developed as a method of forming water jackets for water-cooled automotive engines.

There are a couple of ways to manufacture aluminum cylinder blocks that have a good balance between productivity and abrasion resistance. One of them is the insert-molding of a sleeve made of PMC (Powder Metal Composite) by the HPDC (High Pressure Die Casting) method. However, in this method, cracks are apt to occur on the surface when the PMC sleeve is extruded and that has been a restriction factor against higher extrusion speed. The authors attempted to raise this extrusion temperature by eliminating the Cu additive process from the aluminum alloy powder in order to raise its melting point by approximately 50 °C. This enabled the wall of the extruded sleeve to be thinner and the extrusion speed to be higher compared to those of a conventional production method while avoiding the occurrence of surface cracks.

There are several all-aluminum cylinder blocks. A typical example is a mono-block cylinder of alusil alloy produced by low pressure die casting. This material's resistance to abrasion and seizure, however, is not satisfactory for motorcycle; in addition, long processing time is another disadvantage. To cope with these problems, the authors developed a light and highly productive all-aluminum cylinder block with a cast-in liner through die casting. The liner is made from powder metallurgy composite (PMC) with 3 to 5 % alumina and 0.5 to 3 % of graphite additives. The PMC reconciles abrasion resistance and machinability. The hardness deterioration of the composite due to the heat at die casting is avoided by using heat-resistant rapidly-solidified powders, made from an aluminum-silecon-iron alloy, for the matrix.

In general, welding of high-pressure die casting (DC) parts has been difficult due to gases trapped in the castings. This is a result of the high-speed turbulent flow condition of the DC process. These gases are liberated during welding and produce porosity in the weld joint. The Author had found the range where an enough welding quality was obtained without great drop in castability to the middle of the laminar flow and turbulent flow. This range has been defined as the transition zone. Moreover high strength Al-Mg-Ni alloy was developed by non-heat-treatment. The Transition Flow Filling Method(TFFM) has been developed, that can not only reduce the amount of trapped gases but also is applicable to standard high pressure die casting equipment. With this method, high quality DC parts can be produced that are weldable, strong and have high toughness.

The new die cast (HPDC) wheel alloy has been developed using recycled aluminum to attain considerable reduction of energy at the time of material production to make large contribution to the reduction of CO2 emissions. The material for motorcycle body parts, especially for wheels, requires a sufficient elongation property. However, when recycled aluminum, which contains large amount of impurities, is used as main raw material, the intermetallic compounds crystalize out and the elongation property is deteriorated. Accordingly, we firstly made the investigations on the elements contained in a recycled aluminum and it was clarified that the elongation property was correlated to the shape of crystallized iron-based intermetallic compounds.

SUS301-EH is widely used as a material for exhaust system gaskets, however, at temperatures in excess of 400°C, it can not be used as gas-seal ability of the material declines due to its reduced hardness. The following methods were found to be effective in controlling the softening of stainless steel at high temperatures: (1) The addition of a nitrogen component; (2) Stabilization of the austenite structure; (3) The addition of a molybdenum component. The addition of 0.5% nitrogen to austenitic stainless steel containing molybdenum has enabled the speed of softening at high temperatures to be significantly reduced, due to strain aging by solid nitrogen below 600°C and the combined effects of precipitation hardening and control of growth of recrystallized grains through the precipitation of fine Cr2N on the dislocations and the grain boundary above 600°C.

The technology for a new, high-strength piston material has been developed by using high pressure die casting (HPDC) method, which had a rapid rate of solidification. This method allowed the amount of Ni added to be increased to 5.5 mass%, raising the fatigue strength of the new material at temperatures of 523 K or higher by a factor of 1.5 over that of a conventional material made by gravity die casting (GDC). In addition, application of vacuum to the die cavity and using additional pressure enabled quality exceeding that of conventional GDC pistons. Pistons made from the newly developed material decreased engine friction by 4.4% and increased fuel efficiency by 2.2% in engine bench testing.

Using sand cores, the weld-able, hollow die-cast parts have been developed. For casting, the transition flow filling method is applied to reduce gas containment and to minimize damages to the core. In designing the products, the newly developed core stress prediction system by melt pressure distribution and the newly developed in-product gas containment prediction system have been applied. The hollow die-cast frame made by the new method attains a 30% increase in rigidity and 1kg reduction of weight.

HONDA completed research and development of the Metal V-Belt for CVTs in-house for the purpose of reducing the minimum pitch radius. The newly developed belt is essential to the compactness of a CVT and increases the speed ratio range. Increase of ring stress caused by reducing the minimum pitch radius is treated by improvement of element shape, optimizing clearance between elements and between element and ring and improving materials.(1) In this paper, the optimization of clearance between elements, heat treatment of elements and optimization of ring material are described in detail. Optimum total clearance between elements for a virgin belt is defined by test results during operation using a specially engraved gap sensor and a telemeter system. Tolerance and conditions of heat treatment for elements are optimized concerning fatigue strength of the element nose.

This research is aimed at development of the catalyst for gasoline automobiles which uses only palladium (Pd) among platinum group metals (PGMs). And the conformity emission category aimed at LEV III-SULEV30. For evaluation, the improvement effect was verified for 2013 model year (MY) ACCORD (LEV II-SULEV) as the reference. As compared with Pd-rhodium (Rh) catalyst, a Pd-only catalyst had the low purification performance of nitrogen oxides (NOx), and there was a problem in the drop in dispersion of Pd by sintering, and phosphorus (P) poisoning.

Nd₂Fe₁₄B sintered magnets are used in the drive motors of hybrid, electric and other vehicles. A magnet in which rare earth content is reduced by means of a localized diffusion method has been developed in order to reduce the volume of dysprosium. The distribution of the demagnetization fields in a motor is not uniform, so the necessary coercivity distribution for the magnets was quantified using Computer-Aided Engineering (CAE). Then material specifications of the localized dysprosium diffusion satisfied with this coercivity distribution was determined, and optimal manufacturing conditions including the position of dysprosium diffusion were set. The coercivity distribution in every position of the magnet using localized diffusion method was inspected. As a result, the magnet was satisfied with coercivity distribution demanded by CAE.

This paper describes the development of non-contacting detection type torque sensor that realizes a small lost motion with light weight and low cost. Pedal-equipped electric vehicles are becoming popular in recent years. In those vehicles, torque sensors are usually necessary for measuring the pedaling force to determine the motor torque. We applied an integrated sensing structure and a non-contacting scheme utilizing inverse-magnetostrictive material to minimize the lost motions. As for the sensing material, nickel-iron alloy plating was used to obtain a wide dynamic range. In the tests using the actual structure, the output linearity deterioration occurred because of the strain distribution dispersion produced by the ratchet drive structure. Therefore, the effect of this strain distribution was examined. The inverse-magnetostrictive sensing material of nickel-iron alloy plating has an extremum on its output curve.

The two liter DOHC-VTEC engine developed for the Honda S2000 produces 179kW (240HP, which is 120HP per liter). It is the highest output power among all naturally aspirated two liter engines ever mass-produced. It also achieves an exhaust emission level within National LEV standards. The new engine utilizes a redesigned VTEC cylinder head, in which MIM (metal injection molding) rocker arms are used. The new cylinder block with a ladder frame structure for its lower part, a newly developed camshaft drive chain and gear system and a metal honeycomb catalyst with an air pump start-up system are also utilized.

In this research, a new wire material made using surface-reforming heat treatment was developed in order to enhance the corrosion fatigue resistance of suspension springs. The aim of surface reforming is to improve hydrogen embrittlement characteristics through grain refinement and to improve crack propagation resistance by partial softening of hardness. The grain refinement method used an α'→γ reversed transformation by rapid short-term heating in repeated induction heating and quenching (R-IHQ) to refine the crystal grain size of SAE 9254 steel spring wire to 4 μm or less. In order to simultaneously improve the fatigue crack propagation characteristics, the possibility of reducing the hardness immediately below the spring surface layer was also examined. By applying contour hardening in the second IHQ cycle, a heat affected zone (HAZ) is obtained immediately below the surface.

When the alkali metal-supported catalyst was treated at 830°C, the NOx conversion decreased because the alkali metals in the catalyst layer gradually moved to the cordierite honeycomb layer and reacted with the cordierite elements. This phenomena decreased to be added the basic metal oxide (α) in the catalyst layer. The improved catalyst with α 2 showed higher performance than the conventional catalyst in the model gas test. Moreover, the emission values of NOx, HC, and CO were 50% or less than Japanese domestic regulation values even after 830°C×60h heat treatment in a vehicle test.

A new type of lean NOx catalyst has been developed with improved thermal resistance. This lean NOx catalyst contains precious metals and NO2 adsorbents. The precious metals are used mainly for the oxidation reaction of NO, and the NO2 adsorbents are for the adsorption removal of generated NO2. The thermal resistance of the catalyst was raised by paying attention to the following points. 1) Improvement of thermal resistance for the NO oxidation activity by addition of a different precious metal element. 2) Prevention of thermal degradation of the NO2 adsorbent by addition of a new metal oxide. For item 1, Pd was added to the catalyst which had already included Pt. By having Pd coexist with Pt, the precious metal dispersion was kept high even after heat treatment, so the NO oxidizing ability was improved. For item 2, thermal degradation of NO2 adsorbent was prevented by addition of the new metal oxide (B) to the adsorbent.