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Technical Paper

50,000 Mile Vehicle Road Test of Three-Way and NOx Reduction Catalyst Systems

1978-02-01
780608
The performance of three way and NOx catalysts was evaluated on vehicles utilizing non-feedback fuel control and electronic feedback fuel control. The vehicles accumulated 80,450 km (50,000 miles) using fuels representing the extremes in hydrogen-carbon ratio available for commercial use. Feedback carburetion compared to non-feedback carburetion improved highway fuel economy by about 0.4 km/l (1 mpg) and reduced deterioration of NOx with mileage accumulation. NOx emissions were higher with the low H/C fuel in the three way catalyst system; feedback reduced the fuel effect on NOx in these cars by improving conversion efficiency with the low H/C fuel. Feedback had no measureable effect on HC and CO catalyst efficiency. Hydrocarbon emissions were lower with the low H/C fuel in all cars. Unleaded gasoline octane improver, MMT, at 0.015g Mn/l (0.06 g/gal) increased tailpipe hydrocarbon emissions by 0.05 g/km (0.08 g/mile).
Technical Paper

A Comparison of Four Methods for Determining the Octane Index and K on a Modern Engine with Upstream, Port or Direct Injection

2017-03-28
2017-01-0666
Combustion in modern spark-ignition (SI) engines is increasingly knock-limited with the wide adoption of downsizing and turbocharging technologies. Fuel autoignition conditions are different in these engines compared to the standard Research Octane Number (RON) and Motor Octane Numbers (MON) tests. The Octane Index, OI = RON - K(RON-MON), has been proposed as a means to characterize the actual fuel anti-knock performance in modern engines. The K-factor, by definition equal to 0 and 1 for the RON and MON tests respectively, is intended to characterize the deviation of modern engine operation from these standard octane tests. Accurate knowledge of K is of central importance to the OI model; however, a single method for determining K has not been well accepted in the literature.
Technical Paper

A Comparison of the Effect of E85 vs. Gasoline on Exhaust System Surface Temperatures

2007-04-16
2007-01-1392
With concerns over increasing worldwide demand for gasoline and greenhouse gases, many automotive companies are increasing their product lineup of vehicles to include flex-fuel vehicles that are capable of operating on fuel blends ranging from 100% gasoline up to a blend of 15% gasoline/85% ethanol (E85). For the purpose of this paper, data was obtained that will enable an evaluation relating to the effect the use of E85 fuel has on exhaust system surface temperatures compared to that of regular unleaded gasoline while the vehicle undergoes a typical drive cycle. Three vehicles from three different automotive manufacturers were tested. The surface of the exhaust systems was instrumented with thermocouples at specific locations to monitor temperatures from the manifold to the catalytic converter outlet. The exhaust system surface temperatures were recorded during an operation cycle that included steady vehicle speed operation; cold start and idle and wide open throttle conditions.
Technical Paper

A Modeling Analysis of Fibrous Media for Gasoline Particulate Filters

2017-03-28
2017-01-0967
With an emerging need for gasoline particulate filters (GPFs) to lower particle emissions from gasoline direct injection (GDI) engines, studies are being conducted to optimize GPF designs in order to balance filtration efficiency, backpressure penalty, filter size, cost and other factors. Metal fiber filters could offer additional designs to the GPF portfolio, which is currently dominated by ceramic wall-flow filters. However, knowledge on their performance as GPFs is still limited. In this study, modeling on backpressure and filtration efficiency of fibrous media was carried out to determine the basic design criteria (filtration area, filter thickness and size) for different target efficiencies and backpressures at given gas flow conditions. Filter media with different fiber sizes (8 - 17 μm) and porosities (80% - 95%) were evaluated using modeling to determine the influence of fiber size and porosity.
Journal Article

A New Catalyzed HC Trap Technology that Enhances the Conversion of Gasoline Fuel Cold-Start Emissions

2018-04-03
2018-01-0938
Passive in-line catalyzed hydrocarbon (HC) traps have been used by some manufacturers in the automotive industry to reduce regulated tailpipe (TP) emissions of non-methane organic gas (NMOG) during engine cold-start conditions. However, most NMOG molecules produced during gasoline combustion are only weakly adsorbed via physisorption onto the zeolites typically used in a HC trap. As a consequence, NMOG desorption occurs at low temperatures resulting in the use of very high platinum group metal (PGM) loadings in an effort to combust NMOG before it escapes from a HC trap. In the current study, a 2.0 L direct-injection (DI) Ford Focus running on gasoline fuel was evaluated with full useful life aftertreatment where the underbody converter was either a three-way catalyst (TWC) or a HC trap. A new HC trap technology developed by Ford and Umicore demonstrated reduced TP NMOG emissions of 50% over the TWC-only system without any increase in oxides of oxygen (NOx) emissions.
Technical Paper

A Semi-Empirical Model for Fast Residual Gas Fraction Estimation in Gasoline Engines

2006-10-16
2006-01-3236
Accurate accounting for fresh charge (fuel and air) along with trapped RGF is essential for the subsequent thermodynamic analysis of combustion in gasoline engines as well as for on-line and real-time quantification as relevant to engine calibration and control. Cost and complexity of such techniques renders direct measurement of RGF impractical for running engines. In this paper, an empirically-based approach is proposed for on-line RGF, based on an existing semi-empirical model [1]. The model developed expands the range over which the semi-empirical model is valid and further improves its accuracy. The model was rigorously validated against a well correlated GT-POWER model as well as results from 1D gas exchange model [2]. Overall, using this model, RGF estimation error was within ∼1.5% for a wide range of engine operating conditions. The model will be implemented in Dyno development and calibration at Chrysler Group.
Technical Paper

A Study of Vehicle Equipped with Non-Throttling S.I. Engine with Early Intake Valve Closing Mechanism

1993-03-01
930820
To enable non-throttling operation of gasoline S.I. engine, we have manufactured engines equipped with a newly developed Hydraulic Variable-valve Train (HVT), which can vary its intake-valve closing-timing freely. The air-intake control ability of HVT engine is equivalent to conventional throttling engines. Combustion becomes unstable, however, under non-throttling operation at idling. For the countermeasure, newly designed combustion chamber has been developed. The reduction of pumping loss by the HVT depends on engine speed rather than load, and amounts to about 80 % maximum. A conventional engine-management system is not applicable for non-throttling operation. Therefore, new management system has been developed for load control.
Technical Paper

A Study on Charge Motion Requirements for a Class-Leading GTDI Engine

2017-09-04
2017-24-0065
An integral part of combustion system development for previous NA gasoline engines was the optimization of charge motion towards the best compromise in terms of full load performance, part load stability, emissions and, last but not least, fuel economy. This optimum balance may potentially be different in GTDI engines. While it is generally accepted that an increased charge motion level improves the mixture preparation in direct injection gasoline engines, the tradeoff in terms of performance seems to become less dominant as the boosting systems of modern engines are typically capable enough to compensate the flow losses generated by the more restrictive ports. Nevertheless, the increased boost level does not come free; increased charge motion generates higher pumping- and wall heat losses. Hence it is questionable and engine dependent, whether more charge motion is always better.
Technical Paper

A Study on Shockless Combustion Change Control of Direct Injection Gasoline Engine

2004-10-25
2004-01-2940
A direct injection gasoline engine featuring a center-injection method that incorporates a high-pressure injector at the top center of the combustion chamber, has been developed. The engine is characterized by a significantly improved fuel economy and emissions performance as the result of the application of direct-injection stratified charge, DISC, which is one of the main features of the direct-injection engine. This paper describes a study on a change control method for switching between DISC and homogeneous charge combustion. The two forms of combustion employed in the new direct-injection engine differ in terms of combustion limits in relation to recirculated exhaust gas and air-fuel ratio. This causes the torque difference which is a specific issue in direct injection gasoline engines. The authors attempted to cope with the issue from the viewpoints of misfire prevention and fuel amount restriction in accordance with the torque required.
Technical Paper

A View of Flexible Fuel Vehicle Aldehyde Emissions

1988-08-01
881200
The aldehyde emissions of 1.6L and 5.0L flexible fuel vehicles (FFV) have been measured, with and without a catalyst, on a range of fuels. The “zero mile” catalyzed emission levels of formaldehyde when operating on M85 (85% methanol and 15% gasoline) are in the 5-15 mg/mi range, but as mileage accumulates they tend to be in the 30-50 mg/mi range. The feedgas levels are high and appear to correlate with engine displacement. The formaldehyde and methanol emissions are higher when operating on M100, compared to M85, but the non-oxygenated hydrocarbon emissions are about the same for both fuels, which suggests that the use of M85 may actually provide more air quality benefit than M100. High mileage control of aldehydes to the level of gasoline vehicles does not appear possible with current technology.
Journal Article

Advanced Control System of Variable Compression Ratio (VCR) Engine with Dual Piston Mechanism

2009-04-20
2009-01-1063
A dual piston Variable Compression Ratio (VCR) engine has been newly developed. This compact VCR system uses the inertia force and hydraulic pressure accompanying the reciprocating motion of the piston to raise and lower the outer piston and switches the compression ratio in two stages. For the torque characteristic enhancement and the knocking prevention when the compression ratio is being switched, it is necessary to carry out engine controls based on accurate compression ratio judgment. In order to accurately judge compression ratio switching timing, a control system employing the Hidden Markov Model (HMM) was used to analyze vibration generated during the compression ratio switching. Also, in order to realize smooth torque characteristics, an ignition timing control system that separately controls each cylinder and simultaneously performs knocking control was constructed.
Journal Article

Advancements and Opportunities for On-Board 700 Bar Compressed Hydrogen Tanks in the Progression Towards the Commercialization of Fuel Cell Vehicles

2017-03-28
2017-01-1183
Fuel cell vehicles are entering the automotive market with significant potential benefits to reduce harmful greenhouse emissions, facilitate energy security, and increase vehicle efficiency while providing customer expected driving range and fill times when compared to conventional vehicles. One of the challenges for successful commercialization of fuel cell vehicles is transitioning the on-board fuel system from liquid gasoline to compressed hydrogen gas. Storing high pressurized hydrogen requires a specialized structural pressure vessel, significantly different in function, size, and construction from a gasoline container. In comparison to a gasoline tank at near ambient pressures, OEMs have aligned to a nominal working pressure of 700 bar for hydrogen tanks in order to achieve the customer expected driving range of 300 miles.
Technical Paper

An Analysis on Cycle-by-cycle Variation and Trace-knock using a Turbulent Combustion Model Considering a Flame Propagation Mechanism

2019-12-19
2019-01-2207
Gasoline engines have the trace-knock phenomena induced by the fast combustion which happens a few times during 100 cycles. And that constrains the thermal efficiency improvement due to limiting the ignition timing advance. So the authors have been dedicating a trace-knock simulation so that we could obtain any pieces of information associated with trace-knock characteristics. This simulation consists of a turbulent combustion model, a cycle-by-cycle variation model and a chemical calculation subprogram. In the combustion model, a combustion zone is considered in order to obtain proper turbulent combustion speed through wide range of engine speed. From a cycle-by-cycle variation analysis of an actual gasoline engine, some trace-knock features were detected, and they were involved in the cycle-by-cycle variation model. And a reduced elementary reaction model of gasoline PRF (primary reference fuel) was customized to the knocking prediction, and it was used in the chemical calculation.
Technical Paper

An Experimental Study of the Spray Characteristics of Pressure-Swirl Atomizers for DISI Combustion Systems

2001-05-07
2001-01-1974
This paper presents results from a comprehensive experimental study of high-pressure pressure-swirl gasoline injectors tested under a range of simulated operating conditions. This study encompassed photographic analysis of single spray sequences and simultaneous measurement of axial velocity, radial velocity and diameter at point locations using the phase-doppler technique. The combination of these measurement techniques permitted an insight into the fluid dynamics of the injected spray and its development with time. Five primary stages in the spray-history were identified and numerated with experimental data.
Journal Article

An Overview of the Effects of Ethanol-Gasoline Blends on SI Engine Performance, Fuel Efficiency, and Emissions

2013-04-08
2013-01-1635
This paper provides an overview of the effects of blending ethanol with gasoline for use in spark ignition engines. The overview is written from the perspective of considering a future ethanol-gasoline blend for use in vehicles that have been designed to accommodate such a fuel. Therefore discussion of the effects of ethanol-gasoline blends on older legacy vehicles is not included. As background, highlights of future emissions regulations are discussed. The effects on fuel properties of blending ethanol and gasoline are described. The substantial increase in knock resistance and full load performance associated with the addition of ethanol to gasoline is illustrated with example data. Aspects of fuel efficiency enabled by increased ethanol content are reviewed, including downsizing and downspeeding opportunities, increased compression ratio, fundamental effects associated with ethanol combustion, and reduced enrichment requirement at high speed/high load conditions.
Technical Paper

Analysis for Influence of Inhomogeneity of Air-Fuel Mixture to Super-Knock Caused by Pre-ignition in Supercharged Direct-Injected SI Engine Based on Numerical Calculation

2015-09-01
2015-01-1866
Nowadays, highly super charging is required corresponded to downsizing concept for improving thermal efficiency in direct-injected spark ignition (DISI) engine. However, highly super charging increases the possibility of super-knock caused by pre-ignition. Recently, in many studies, the reason of pre-ignition has been investigated but the reason why pre-ignition leads such strong knocking called super-knock has not been investigated. In DISI engine, it is estimated that there is more inhomogeneity of equivalence ratio and temperature of air-fuel mixture than it in port injection SI engine. In this study, factors which decide self-ignition timing was reviewed and the influence of inhomogeneity of air-fuel mixture to super-knock was investigated based on numerical calculation.
Journal Article

Analysis of Ash in Low Mileage, Rapid Aged, and High Mileage Gasoline Exhaust Particle Filters

2017-03-28
2017-01-0930
To meet future particle mass and particle number standards, gasoline vehicles may require particle control, either by way of an exhaust gas filter and/or engine modifications. Soot levels for gasoline engines are much lower than diesel engines; however, non-combustible material (ash) will be collected that can potentially cause increased backpressure, reduced power, and lower fuel economy. The purpose of this work was to examine the ash loading of gasoline particle filters (GPFs) during rapid aging cycles and at real time low mileages, and compare the filter performances to both fresh and very high mileage filters. Current rapid aging cycles for gasoline exhaust systems are designed to degrade the three-way catalyst washcoat both hydrothermally and chemically to represent full useful life catalysts. The ash generated during rapid aging was low in quantity although similar in quality to real time ash. Filters were also examined after a low mileage break-in of approximately 3000 km.
Journal Article

Analysis of High Mileage Gasoline Exhaust Particle Filters

2016-04-05
2016-01-0941
The purpose of this work was to examine gasoline particle filters (GPFs) at high mileages. Soot levels for gasoline direct injection (GDI) engines are much lower than diesel engines; however, noncombustible material (ash) can cause increased backpressure, reduced power, and lower fuel economy. In this study, a post mortem was completed of two GPFs, one at 130,000 mi and the other at 150,000 mi, from two production 3.5L turbocharged GDI vehicles. The GPFs were ceramic wall-flow filters containing three-way catalytic washcoat and located downstream of conventional three-way catalysts. The oil consumption was measured to be approaching 23,000 mpqt for one vehicle and 30,000 mpqt for the other. The ash contained Ca, P, Zn, S, Fe, and catalytic washcoat. Approximately 50 wt% of the collected ash was non-lubricant derived. The filter capture efficiency of lubricant-derived ash was about 50% and the non-lubricant metal (mostly Fe) deposition rate was 0.9 to 1.2 g per 10,000 mi.
Technical Paper

Basic Understanding of Activated Radical Combustion and Its Two-Stroke Engine Application and Benefits

2000-06-19
2000-01-1836
For a better understanding of the auto-ignition phenomenon in internal combustion engines, consideration is given from the in-cylinder gas temperature aspect. Experimental results demonstrate that the in-cylinder gas temperature at the end of compression, namely, the “auto-ignition temperature” is deeply involved in the onset of auto-ignition. The relation between the gas exchange state and the auto-ignition temperature explains the mechanism of timing controlled auto-ignition, namely, Activated Radical (AR) Combustion. The auto-ignition temperature is maintained constant during the AR combustion state, thanks to the exhaust valve controlling the hot residual gas amount. Finally, the utilization of auto-ignition in gasoline engines is discussed from the methodology aspect.
Journal Article

Benefits of Pd Doped Zeolites for Cold Start HC/NOx Emission Reductions for Gasoline and E85 Fueled Vehicles

2018-04-03
2018-01-0948
In the development of HC traps (HCT) for reducing vehicle cold start hydrocarbon (HC)/nitrogen oxide (NOx) emissions, zeolite-based adsorbent materials were studied as key components for the capture and release of the main gasoline-type HC/NOx species in the vehicle exhaust gas. Typical zeolite materials capture and release certain HC and NOx species at low temperatures (<200°C), which is lower than the light-off temperature of a typical three-way catalyst (TWC) (≥250°C). Therefore, a zeolite alone is not effective in enhancing cold start HC/NOx emission control. We have found that a small amount of Pd (<0.5 wt%) dispersed in the zeolite (i.e., BEA) can significantly increase the conversion efficiency of certain HC/NOx species by increasing their release temperature. Pd was also found to modify the adsorption process from pure physisorption to chemisorption and may have played a role in the transformation of the adsorbed HCs to higher molecular weight species.
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