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In a gasoline engine, the unswept in-cylinder residual gas and introduction of external EGR is one of the important means of controlling engine raw NOx emissions and improving part load fuel economy via reduction of pumping losses. Since the trapped in-cylinder Residual Gas Fraction (RGF, comprised of both internal, and external) significantly affects the combustion process, on-line diagnosis and monitoring of in-cylinder RGF is very important to the understanding of the in-cylinder dilution condition. This is critical during the combustion system development testing and calibration processes. However, on-line measurement of in-cylinder RGF is difficult and requires an expensive exhaust gas analyzer, making it impractical for every application. Other existing methods, based on measured intake and exhaust pressures (steady state or dynamic traces) to calculate gas mass flowrate across the cylinder ports, provide a fast and economical solution to this problem.

A mixed time-scale subgrid large eddy simulation was used to simulate mixture formation, combustion and soot formation under the influence of turbulence during diesel engine combustion. To account for the effects of engine wall heat transfer on combustion, the KIVA code's standard wall model was replaced to accommodate more realistic boundary conditions. This were carried out by implementing the non-isothermal wall model of Angelberger et al. with modifications and incorporating the log law from Pope's method to account for the wall surface roughness. Soot and NOx emissions predicted with the new model are compared to experimental data acquired under various EGR conditions.

The newly developed rotary engine has achieved major progress in high performance, improved fuel economy and clean exhaust gas by innovative action. The engine of the next generation is named RENESIS, which stands for “The RE (Rotary Engine)'s GENESIS” or the rotary engine for the new millennium. The peripheral exhaust port of the previous rotary engine is replaced by a side exhaust port system in the RENESIS. This allows for an increase in the intake port area, thus producing higher power. Exhaust opening timing is retarded to improve thermal efficiency. The side exhaust port also allows reducing the internal EGR, stabilizing the combustion at idling. The improved thermal efficiency and the stabilized idle combustion result in higher fuel economy. In addition, the side exhaust port allows a reduction of the HC mass, realizing reduced exhaust gas emission.

In this study, we determined the detailed reaction mechanism of CO/NO/O2 for automotive three way catalysts. The N2O formation process obtained from measurements of the reaction properties and the formation process of adsorbed NCO species obtained from surface analysis of platinum group metals were added to a previous detailed surface reaction mechanism. The computational accuracy of the developed reaction mechanism was verified by the one-dimensional simulation software BOOST, and it was found to be sufficient for any combination of platinum group metals and gas concentrations.

A newly developed three-way catalyst (TWC) has excellent thermal durability with an ultra low amount of platinum group metals (PGM). The performance of the new catalyst is similar to that of a conventional TWC but with only 1/10 of the typical PGM loading. In the conventional TWC, the PGM particles are simply deposited on the surface of the support material; the particles sinter during thermal aging, resulting in significant thermal deterioration. The new developed catalyst contains small nano-sized PGM particles with a unique microstructure and support materials. With this material, the PGM particles remain at the single nano size after high temperature aging.

Current engine development processes typically involve extensive steady-state and simple transient testing in order to characterize the engine's fuel consumption, emissions, and performance based on several controllable inputs such as throttle, spark advance, and EGR. Steady-state and simple transient testing using idealistic load conditions alone, however, is no longer sufficient to meet powertrain development schedule requirements. Mapping and calibration of an engine under transient operation has become critically important. And, independent engine development utilizing accelerated techniques is becoming more attractive. In order to thoroughly calibrate new engines in accelerated fashion and under realistic transient conditions, more advanced testing is necessary.

The reduced chemical reaction scheme which can take the effect of major fuel components on auto ignition timing into account has been developed. This reaction scheme was based on the reduced reaction mechanism for the primary reference fuels (PRF) proposed by Tsurushima [1] with 33 species and 38 reactions. Some pre-exponential factors were modified by using Particle Swarm Optimization to match the ignition delay time versus reciprocal temperature which was calculated by the detailed scheme with 2,301 species and 11,116 elementary chemical reactions. The result using the present reaction scheme shows good agreements with that using the detailed scheme for the effects of EGR, fuel components, and radical species on the ignition timing under homogeneous charge compression ignition combustion (HCCI) conditions.

Vehicle evaluations and model calculations were conducted on a vacuum-insulated catalytic converter (VICC). This converter uses vacuum and a eutectic PCM (phase-change material) to prolong the temperature cool-down time and hence, may keep the converter above catalyst light-off between starts. Tailpipe emissions from a 1992 Tier 0 5.2L van were evaluated after 3hr, 12hr, and 24hr soak periods. After a 12hr soak the HC emissions were reduced by about 55% over the baseline HC emissions; after a 24hr soak the device did not exhibit any benefit in light-off compared to a conventional converter. Cool-down characteristics of this VICC indicated that the catalyst mid-bed temperature was about 180°C after 24hrs. Model calculations of the temperature warm-up were conducted on a VICC converter. Different warm-up profiles within the converter were predicted depending on the initial temperature of the device.

The new shape ceria-based support material for a lean NOx trap catalyst (LNT) was developed and its catalytic characteristics were investigated. It has a unique shape that each fine particle of raw material is formed into hollow sphere. Samples of platinum loaded powder catalysts were obtained with either the hollow sphere ceria-based material or two kinds of the conventional shape one, and their catalytic activities were evaluated with the synthetic gas. The aged powder catalyst using the hollow sphere ceria-based material had higher CO oxidation performance at low temperature as compared to the conventional shape one with the same composition. The characterization results indicated that the hollow sphere ceria-based material had high thermal stability.

Thermal effects on three-way catalysts and deterioration characteristics were studied. Aging atmosphere (oxidizing or reducing) and temperature contributed to catalyst performance deterioration. Catalysts sharply lost their activities under oxidizing conditions at an aging temperature of 900°C and above. Thermal degradation was found due mainly to the decrease in the surface area of alumina coated on the substrate and the increase in the size of cerium oxide (CeO2) crystal particle, an oxgen storage component (OSC). Also observed was a close correlation between the alumina surface area loss and the volume loss of micro pores with their radius less than 100 Å. Tests demonstrated that the catalyst thermal degradation can be reduced if the alumina micro pore volume loss and the CeO2 crystal particle size increase are restrained.