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Characteristics of mass emission of unburned Oil-Particulate Matter and polycyclic aromatic hydrocarbons from two-stroke scooter were investigated. The tests were carried out under with and without oxidation catalyst and various air-fuel ratio ranging from 12 to 16 at 50:1 of fuel-oil mixing ratio for easy sampling. Unburned Oil-Particulate Matter and 4- to 7-rings polycyclic aromatic hydrocarbons were trapped on filter. These compounds were analyzed by high performance liquid chromatography with fluorescence detector. Mass emission of polycyclic aromatic hydrocarbons and unburned Oil-Particulate Matter tends to decrease as air-fuel ratio which increased up to stoichiometric ratio. The highest conversion ratio of unburned Oil-Particulate Matter on the oxidation catalyst was 64%. Conversion ratio of polycyclic aromatic hydrocarbons increased as rings are smaller.

Diesel Particulate Filter (DPF) is a very effective aftertreatment device to limit particulate emissions from diesel engines. As the amount of soot collected in the DPF increases, the pressure loss increases. Therefore, DPF regeneration needs to be performed. Injected fuel into the exhaust line upstream of the Diesel Oxidation Catalyst (DOC), hydrocarbons are oxidized on the DOC, which increases the exhaust gas temperature at the DPF inlet. It is also necessary that the injected fuel is completely vaporized before entering the DOC, and uniformly mixed with the exhaust gases in order to make the DOC work efficiency. However, ensuring complete evaporation and an optimum mixture distribution in the exhaust line are challenging. Therefore, it is important that the fuel spray feature is grasped to perform DPF regeneration effectively. The purpose of this study is the constructing a simulation model.

A premixed charge compression ignition methanol engine targeting a drastic decrease in NOx emissions and a brake specific energy consumption equivalent to that of a DI diesel engine has been developed (1). The problems of this combustion system are that the brake thermal efficiency decreases, and CO and THC emissions increase due to a deterioration of high load combustion. The purpose of this study is to improve the high load combustion of a premixed charge compression ignition methanol engine using a flash boiling fuel injection technique. The results of this study have shown that the premixed charge compression ignition methanol combustion system using a flash boiling fuel injection technique increases the brake thermal efficiency, decreases CO and THC emissions, while maintaining low NOx emissions in the high load region.

This study employed a diesel particulate generator (DPG), with an installed engine oil injector for soot and ash accumulation in a diesel particulate filter (DPF). Ash was generated by engine oil injection into the diesel burner flame. The amount of soot accumulation per loading varied from 0.5 g/L to 8 g/L while ash accumulation amount per loading was maintained at 0.5 g/L. Initially, ash accumulation distribution in the DPF was visualized using X-ray computed tomography (CT). It was revealed that the form of ash accumulation changed depending on the amount of soot accumulation before active regeneration, i.e., a large amount of soot accumulation resulted in plug ash, whereas a small amount of soot accumulation resulted in wall ash. To clarify ash accumulation mechanisms, soot and ash transport behavior in DPF during active regeneration process was directly observed using a high-speed camera through an optically accessible D-shaped cut DPF covered with a quartz glass plate.

A prototype CNG engine for heavy-duty trucks has been developed. The engine had sufficient output in practical use, and the green-house gas emission rate was below that of the base diesel engine. Furthermore, the NOx emission rate was reduced to 0.16 g/kWh in the JE05 mode as results of having fully adjusted air fuel ratio control. The measured emission characteristics of particles from the prototype CNG engine demonstrated that oil consumption was related to the number of particles. Moreover, when oil consumption is at an appropriate level, the accumulation mode particles are significantly reduced, and the nuclei mode particles are fewer than those of diesel-fueled engines.

Four urea SCR systems were developed and evaluated on a C/D and on the road to investigate their potential for Japanese emission regulations in 2005 and beyond. Test results showed that NOx conversion ratios were 50 to 70% during the Japanese D13 mode cycle, and the ratios under the transient driving cycle were lower than those tested during a steady state. Unregulated emissions, such as benzene, aldehyde and benzo[a]pyrene, existed either at a trace level using the oxidation catalyst, or lower than a base diesel engine, when no oxidation catalyst was used. The health effects of particulate matter emitted from the SCR system were almost the same as those from conventional diesel engines, as evaluated by the Ames test and in vitro micronucleus test. Thermal degradation products, such as cyanuric acid and melamine, were two to four figures lower compared with the toxicological information of Safety Information Resources Inc. (SIRI).

Emission regulations for diesel-powered vehicles have been gradually tightening. Installation of after-treatment devices such as diesel particulate filters (DPF), NOx storage reduction (NSR) catalysts, and so on is indispensable to satisfy rigorous limits of particulate matter (PM) and nitrogen oxides (NOx). Japan Clean Air Program II Oil Working Group (JCAPII Oil WG) has been investigating the effect of engine oil on advanced diesel after-treatment devices. First of all, we researched the impact of oil-derived ash on continuous regeneration-type diesel particulate filter (CR-DPF), and already reported that the less sulfated ash in oil gave rise to lower pressure drop across CR-DPF [1]. In this paper, impact of oil-derived sulfur and phosphorus on NSR catalyst was investigated using a 4L direct injection common-rail diesel engine with turbo-intercooler. This engine equipped with NSR catalyst meets the Japanese new short-term emission regulations.

The objective of this study is to improve tire hydroplaning performance by examining the arrangement of the tread grooves, based on water flow. It is important to smoothly channel the water through the tread grooves to improve performance. For this purpose, flow around the tire contact area was visualized by particle tracing. The velocity and the direction of flow in front of the contact area became clear as a vector map. This vector map indicated that the direction of the flow depends primarily on the lateral position, i.e., the distance from the tread center. Tread grooves parallel to the flow vector were designed based on this result. The visualization of the improved tire demonstrated that water flowed smoothly along the grooves. In addition, a drum test indicated increased cornering force at high speed.

Fuels of wide range of density and viscosity were tested by using a DI diesel engine that conforms to present Japanese regulations. A total of 9 fuels was tested. Six test fuels were commercial automotive diesel fuel available in Japan. In order to expand the density range, test fuels of kerosene, high-density diesel fuel and automotive diesel fuel in Singapore were also included. The density range was 0.796 to 0.856 (g/cm3), and the viscosity range was 1.52 to 5.44 (mm2/s). The test mode was Japanese D13. Also, some fuels were tested by the Japanese transient test mode. Moreover, fuel spray was observed by an optical method to clarify the relationship between viscosity and Sauter mean diameter.

Crosscheck tests of fast electrical mobility spectrometers, Differential Mobility Spectroscopy (DMS) and Engine Exhaust Particle Sizer(EEPS), were conducted to evaluate the accuracy of fine particle measurement. Two kinds of particles were used as test particles for the crosscheck test of instruments: particles emitted from diesel vehicles and diluted in a full dilution tunnel, and particles generated by CAST. In the steady state tests, it was confirmed that the average concentration of each instrument was within the range of ±2σ from the average concentration of all the same type of instruments. In the transient tests, it is verified that the instruments have almost equal sensitivity. For application of the fast electrical mobility spectrometers to evaluation of particle number and size distributions, it is essential to develop a calibration method using reference particle counters and sizers (CPC, SMPS, etc.) and maintenance methods appropriate for each model.

Comparing with the previous Auto/Oil programs, the total plan and current status of the air quality modeling study in JCAP are presented. The total plan of air quality modeling study has the following characteristics: 1) Vehicle emission inventory program is developed by considering the original features of Japan. 2) Not only the urban air quality but also the road sides pollutants dispersion is evaluated. 3) The chemical reaction model for the secondary particulate formations is developed on the basis of the smog chamber experiments. 4) For the cost-effectiveness analysis of vehicle/fuel technologies, the output of the air quality modeling will be combined with the cost data of new vehicle emission reduction technologies As the first step, preliminary modeling studies are conducted to understand the overall tendency of the air quality change toward 2010 in Tokyo urban area.

The Agency of Natural Resources and Energy, Ministry of Economy, Trade and Industry has conducted conformity tests of diesel fuel containing Fatty Acid Methyl Ester (FAME) to amend diesel fuel standards in Japan. The objective of the tests is to examine appropriate specifications of diesel fuel containing FAME for automotive use for existing vehicles in the Japanese market. The conformity testing includes verification of fuel system component compatibility, tail pipe emissions, and characterization of the reliability and durability of the engine system, including the fuel injection system. In designing the conformity tests, the maximum FAME concentration was 5%. Most of the new standards are essentially equivalent to EN14214, but the total acid number (TAN) of specific acids, and oxidation stability of the new standards for diesel fuel containing FAME, are different from EN14214.

This paper proposes a new mixing-controlled, low temperature combustion (LTC) approach for high-speed direct injection (HSDI) diesel engines. The purpose of this approach is to avoid the excessively high pressure-rise rate (PRR) of premixed, kinetics-controlled LTC and to enable the low nitrogen oxides (NOx) combustion to operate over the wide speed and load range of the engine. To address the soot/noise trade-off at high load LTC operating conditions, the pressure modulated multiple-injection coupled with swirl control was applied. This injection strategy enables the injection of high pressure (HP) main spray into the local high temperature region of the already burning low pressure (LP) pilot spray injected from the neighboring injection hole. By employing this injection strategy, the equivalence ratio (φ) distribution of mixture is drastically varied during main combustion processes.

Newly designed laboratory measurement system, which reproduces particle number size distributions of both nuclei and accumulation mode particles in exhaust emissions, was developed. It enables continuous measurement of nano particle emissions in the size range between 5 and 1000 nm. Evaluations of particle number size distributions were conducted for diesel vehicles with a variety of emission aftertreatment devices and for gasoline vehicles with different combustion systems. For diesel vehicles, Diesel Oxidation Catalyst (DOC), urea-Selective Catalytic Reduction (urea-SCR) system and catalyzed Diesel Particulate Filter (DPF) were evaluated. For gasoline vehicles, Lean-burn Direct Injection Spark Ignition (DISI), Stoichiometric DISI and Multi Point Injection (MPI) were evaluated. Japanese latest transient test cycles were used for the evaluation: JE05 mode driving cycle for heavy duty vehicles and JC08 mode driving cycle for light duty vehicles.

A methodology for simulating effect of international variations in fuel compositions on spray combustion is proposed. The methodology is validated with spray combustion experiments with real fuels from three different countries. The compositions of those fuels were analyzed through GC×GC and H-NMR. It was found that ignition delay times, flame region and flame luminosity were significantly affected by the compositional variations. For the simulation, an evaporation surrogate consisting of twenty two species, covering basic molecular types and a wide range of carbon numbers, is developed. Each species in the evaporation surrogate is then virtually converted to a reaction surrogate consisting of n-hexadecane, methylcyclohexane and 1,2,4-trimethyl benzene so that combustion reactions can be calculated with a published kinetic model. The virtual species conversion (VSC) is made so as to take over combustion-related properties of each species of evaporation surrogates.

In recent research, decreasing oil consumption and using a synthetic oil have been shown to be effective methods of reducing smoke emissions. However, the investigation of the constituents of white smoke and its environmental effect on humans have not been undertaken. The purpose of this investigation is to clarify the characteristics and compositions of white smoke and to analyze its environmental effect on humans using Ames test, and to evaluate a control for reduction of emitted matter by steady-state engine tests. Emitted matters(EM) from synthetic oil is less than that of semi-synthetic and mineral oils under the same test conditions. Emission after treatment resulted in the lowest EM when simulating the results of the ISO 6460 test, which results showed a decrease to about 1/10. EM from two-stroke engine mainly consists of unburned engine-oil and more than 95 % of EM is soluble organic fraction (SOF).

Single cylinder engine testing was carried out to clearly understand the test results of multi-cylinder engines reported by the Diesel WG in JCAP (Japan Clean Air Program) (1), (2), (3) and (4). In this tests, engine specifications such as fuel injection pressure, nozzle hole diameter, turbo-charging pressure, EGR rate, and fuel properties such as 1-, 2-, 3-ring aromatics content, n-,i-paraffins content, and T90 were parametrically changed and their influence on the emissions were studied. PM emission generally increased in each engine condition with increased aromatic contents and T90. In particular, multi ring aromatics brought about large increases in PM regardless of the engine conditions. The influence of fuel properties on NOx emission is smaller than the influence on PM emission. Some other fuels that have various side chain structures of 1-ring aromatics, normal paraffins only and various naphthene contents were also investigated.

For the better understanding of nanoparticles observed on the rode side, adding to the emission test on the chassis dynamometer and engine dynamometer test, possible factors for formation of nanoparticles are investigated. As other possible factors, cold starting of transient test cycle, blow-by gas from heavy duty diesel engine without a positive crankcase ventilation, exhaust braking, and plume mixing of vehicle exhausts were investigated. Nuclei mode particles under the transient test cycles formed during fuel cut period, fuel enrichment period and idling period. Concentration of nuclei mode particles during the idling period are depends on exhaust temperature. The higher exhaust temperature courses the lower number concentration but variation range is within twice. Emission rate of nanoparticles from blow-by gas is one thousandth of tail pipe emissions rate and was found to be negligible.

This work investigated the mechanism of oil dilution by post injection to remove accumulated particulate matter on the diesel particulate filter of diesel engines. We developed a model to simulate post injection spray under low ambient gas pressure conditions. The model can predict the quantity of fuel mass adhered on the cylinder wall. The adhered fuel enters oil sump through the piston ring and cause oil dilution. The fuel in diluted oil evaporates during normal engine operations. We focus on the mechanism of fuel evaporation from diluted oil. The effects of engine speed and oil temperature on the evaporation were investigated. The results showed that the fuel evaporation rate increases with increasing engine speed and oil temperature. Furthermore, we developed an empirical model to predict the fuel evaporation rate of diluted oil through regression analysis with measured data.

The engine in the research is a single cylinder DI diesel using the emission reduction techniques such as high boost, high injection pressure and broad range and high quantity of exhaust gas recirculation (EGR). The study especially focuses on the reduction of particulate matter (PM) under the engine operating conditions. In the experiment the authors measured engine performance, exhaust gases and mass of PM by low sulfur fuel such as 3 ppm and low sulfur lubricant oil such as 0.26%. Then the PM components were divided into soluble organic fraction (SOF) and insoluble organic fraction (ISOF) and they were measured at each engine condition. The mass of SOF was measured from the fuel fraction and lubricant oil fraction by gas chromatography. Also each mass of soot fraction and sulfate fraction was measured as components of ISOF. The experiment was conducted at BMEP = 2.0 MPa as full load condition of the engine and changing EGR rate from 0% to 40 %.