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In this study, an experimental investigation was conducted using a direct injection single-cylinder diesel engine equipped with a test common rail fuel injection system to clarify how dimethyl ether (DME) injection characteristics affect the heat release and exhaust emissions. For that purpose the common rail fuel injection system (injection pressure: 15 MPa) and injection nozzle (0.55 × 5-holes, 0.70 × 3-holes, same total holes area) have been used for the test. First, to characterize the effect of DME physical properties on the macroscopic spray behavior: injection quantity, injection rate, penetration, cone angle, volume were measured using high-pressure injection chamber (pressure: 4MPa). In order to clarify effects of the injection process on HC, CO, and NOx emissions, as well as the rate of heat release were investigated by single-cylinder engine test. The effects of the injection rate and swirl ratio on exhaust emissions and heat release were also investigated.