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Knowledge of the tire slip ratio can greatly improve vehicle longitudinal stability and its dynamic performance. Most conventional slip ratio observers were mainly designed based on input of non-driven wheel speed and estimated vehicle speed. However, they are not applicable for electric vehicles (EVs) with four in-wheel motors. Also conventional methods on speed estimation via integration of accelerometer signals can often lead to large offset by long-time integral calculation. Further, model uncertainties, including steady state error and unmodeled dynamics, are considered as additive disturbances, and may affect the stability of the system with estimated state error. This paper proposes a novel slip ratio observer based on input-to-state stability (ISS) method for electric vehicles with four-wheel independent driving motors.