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The Automotive Industry/Government Emissions Research CRADA (AIGER) has been working to develop a new methodology for the direct determination of nonmethane hydrocarbons (DNMHC) in vehicle testing. This new measurement technique avoids the need for subtraction of a separately determined methane value from the total hydrocarbon measurement as is presently required by the Code of Federal Regulations. This paper will cover the historical aspects of the development program, which was initiated in 1993 and concluded in 2002. A fast, gas chromatographic (GC) column technology was selected and developed for the measurement of the nonmethane hydrocarbons directly, without any interference or correction being caused by the co-presence of sample methane. This new methodology chromatographically separates the methane from the nonmethane hydrocarbons, and then measures both the methane and the backflushed, total nonmethane hydrocarbons using standard flame ionization detection (FID).

As the standards for exhaust emissions have become more stringent, the quality control tools used to evaluate the performance of low level samplers and analyzers has become more important. The Vehicle Exhaust Emissions Simulator (VEES) was developed to evaluate the performance of vehicle or engine exhaust emissions sampling and analytical systems. The simulator emulates emissions from low-emitting gasoline vehicles by producing a simulated exhaust stream containing emission constituents (HC, CO, CO2, and NOx) injected via Mass Flow Controllers (MFCs). This paper discusses various applications of the VEES as a quality control tool for ULEV and SULEV testing. A comparison is made between the injected amount of exhaust species by the VEES and the amounts recovered by the different sampling systems. Different root cause scenarios are discussed as to the source of discrepancies between the results on the CVS and BMD for different driving cycles.