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Recent experiments and numerical studies have showed that piston geometry has a significant effect on the homogeneous charge compression ignition (HCCI) process. There are two effects generated by the combustor geometry: the geometry affects the flow/turbulence in the cylinder; the geometry also affects the temperature stratification. The temperature stratification is more directly responsible for the observed alteration of the auto-ignition process. To clarify this issue further we present in this paper a study of two engines with the same geometry but difference ways of cooling. Measurement of the two engines - a metal engine and quartz piston engine, both with the same piston bowl geometry - is carried out. Large eddy simulation (LES) is used to simulate the flow, the temperature field and the auto-ignition process in the two engines. The fuel is ethanol with a relative air/fuel ratio of 3.3.