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Technical Paper

1D Model of a Copper Exchanged Small Pore Zeolite Catalyst Based on Transient SCR Protocol

2013-04-08
2013-01-1578
Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.
Technical Paper

A Comparative Life Cycle Assessment of Magnesium Front End Autoparts: A Revision to 2010-01-0275

2012-12-31
2012-01-2325
The Magnesium Front End Research and Development (MFERD) project under the sponsorship of Canada, China, and USA aims to develop key technologies and a knowledge base for increased use of magnesium in automobiles. The primary goal of this life cycle assessment (LCA) study is to compare the energy and potential environmental impacts of advanced magnesium based front end parts of a North American-built 2007 GM-Cadillac CTS using the current steel structure as a baseline. An aluminium front end is also considered as an alternate light structure scenario. A “cradle-to-grave” LCA is conducted by including primary material production, semi-fabrication production, autoparts manufacturing and assembly, transportation, use phase, and end-of-life processing of autoparts. This LCA study was done in compliance with international standards ISO 14040:2006 [1] and ISO 14044:2006 [2].
Technical Paper

A Comparison of HCCI Ignition Characteristics of Gasoline Fuels Using a Single-Zone Kinetic Model with a Five Component Surrogate Fuel

2008-10-06
2008-01-2399
While gasoline surrogate development has progressed in the areas of more complex surrogate mixtures and in kinetic modeling tools and mechanism development, it is generally recognized that further development is still needed. This paper represents a small step in supporting this development by providing comparisons between experimental engine data and surrogate-based kinetic models. In our case, the HCCI engine data comes from a port-injected, single-cylinder research engine with intake-air heating for combustion phasing control. Timing sweeps were run at constant fuel rate for three market gasolines and five surrogate mixtures. Modeling was done using the CHEMKIN software with a gasoline mechanism set containing 1440 species and 6572 reactions. Five pure compounds were selected for the surrogate blends and include iso-octane, n-heptane, toluene, methylcyclohexane, and 1-hexene.
Technical Paper

A Feasibility Evaluation of a Thermal Plasma Fuel Reformer for Supplemental Hydrogen Addition to Internal Combustion Engines

1999-04-26
1999-01-2239
One scenario for reducing engine out NOx in a spark ignition engine is to introduce small amounts of supplemental hydrogen to the combustion process. The supplemental hydrogen enables a gasoline engine to run lean where NOx emissions are significantly reduced and engine efficiency is increased relative to stoichiometric operation. This paper reports on a mass and energy balance model that has been developed to evaluate the overall system efficiencies of a thermal reformer-heat exchanger system capable of delivering hydrogen to the air intake of a gasoline engine. The mass and energy balance model is utilized to evaluate the conditions where energy losses associated with fuel reformation may be offset by increases in engine efficiencies.
Journal Article

A Gasoline Fueled Pre-Chamber Jet Ignition Combustion System at Unthrottled Conditions

2012-04-16
2012-01-0386
Turbulent Jet Ignition is an advanced spark-initiated pre-chamber combustion system for otherwise standard spark ignition engines. Combustion in the main chamber is initiated by jets of partially combusted (reacting) pre-chamber products which provide a high energy ignition source. The resultant widely distributed ignition sites allow relatively small flame travel distances enabling short combustion durations and high burn rates. Demonstrated benefits include ultra-lean operation (λ≻2) at part load and high-load knock improvement near stoichiometric conditions. Although previous results of this combustion system have been very promising, the main hurdle of this system has been the need for a dual-fuel system, with liquid gasoline used in the main combustion chamber and small fractions of gaseous propane in the pre-chamber.
Technical Paper

A Hybrid 2-Zone/WAVE Engine Combustion Model for Simulating Combustion Instabilities During Dilute Operation

2005-10-24
2005-01-3801
Internal combustion engines are operated under conditions of high exhaust gas recirculation (EGR) to reduce NOx emissions and promote enhanced combustion modes such as HCCI. However, high EGR under certain conditions also promotes nonlinear feedback between cycles, leading to the development of combustion instabilities and cyclic variability. We employ a two-zone phenomenological combustion model to simulate the onset of combustion instabilities under highly dilute conditions and to illustrate the impact of these instabilities on emissions and fuel efficiency. The two-zone in-cylinder combustion model is coupled to a WAVE engine-simulation code through a Simulink interface, allowing rapid simulation of several hundred successive engine cycles with many external engine parametric effects included.
Technical Paper

A Lean Burn Gasoline Fueled Pre-Chamber Jet Ignition Combustion System Achieving High Efficiency and Low NOx at Part Load

2012-04-16
2012-01-1146
Turbulent Jet Ignition is an advanced spark-initiated pre-chamber combustion system for otherwise standard spark ignition engines. Combustion in the main chamber is initiated by jets of partially combusted (reacting) pre-chamber products which provide a high energy ignition source. The resultant widely distributed ignition sites allow relatively small flame travel distances enabling short combustion durations and high burn rates. Demonstrated benefits include ultra lean operation (λ≻2) at part load and high load knock limit extension. Previous jet ignition experimental results have highlighted high thermal efficiencies, high load capability and near-zero engine-out NOx emissions in a standard contemporary engine platform. Although previous results of this system have been very promising, the main hurdle has been the need for a dual fuel system, with liquid gasoline used in the main combustion chamber and small fractions of gaseous propane in the pre-chamber.
Technical Paper

A Life-Cycle-Based Environmental Evaluation: Materials in New Generation Vehicles

2000-03-06
2000-01-0595
This project team conducted a life-cycle-based environmental evaluation of new, lightweight materials (e.g., titanium, magnesium) used in two concept 3XVs -- i.e., automobiles that are three times more fuel efficient than today's automobiles -- that are being designed and developed in support of the Partnership for a New Generation of Vehicles (PNGV) program. The two concept vehicles studied were the DaimlerChrysler ESX2 and the Ford P2000. Data for this research were drawn from a wide range of sources, including: the two automobile manufacturers; automobile industry reports; government and proprietary databases; past life-cycle assessments; interviews with industry experts; and models.
Technical Paper

A Machine Approach for Field Weakening of Permanent-Magnet Motors

2000-04-02
2000-01-1549
The commonly known technology of field weakening for permanent-magnet (PM) motors is achieved by controlling the direct-axis current component through an inverter. Without using mechanical variation of the air gap, a new machine approach for field weakening of PM machines by direct control of air-gap fluxes is introduced. The demagnetization situation due to field weakening is not an issue with this new method. In fact, the PMs are strengthened at field weakening. The field-weakening ratio can reach 10:1 or higher. This technology is particularly useful for the PM generators and electric vehicle drives.
Technical Paper

A Modeling Study of SCR Reaction Kinetics from Reactor Experiments

2013-04-08
2013-01-1576
In order to further characterize and optimize the performance of Selective Catalytic Reduction (SCR) aftertreatment systems used on heavy-duty diesel engines, an accurately calibrated high-fidelity multi-step global kinetic SCR model and a reduced order estimator for on-board diagnostic (OBD) and control are desirable. In this study, a Cu-zeolite SCR catalyst from a 2010 Cummins ISB engine was experimentally studied in a flow reactor using carefully designed protocols. A 2-site SCR model describing mass transfer and the SCR chemical reaction mechanisms is described in the paper. The model was calibrated to the reactor test data sets collected under temperatures from 200 to 425 °C and SCR space velocities of 60000, 90000, and 120000 hr-1. The model parameters were calibrated using an optimization code to minimize the error between measured and simulated NO, NO₂, N₂O, and NH₃ gas concentration time histories.
Technical Paper

A New Combustion System Achieving High Drive Cycle Fuel Economy Improvements in a Modern Vehicle Powertrain

2011-04-12
2011-01-0664
Turbulent Jet Ignition is an advanced spark initiated pre-chamber combustion system for otherwise standard spark ignition engines found in current passenger vehicles. This next generation pre-chamber design simply replaces the spark plug in a conventional spark ignition engine. Turbulent Jet Ignition enables very fast burn rates due to the ignition system producing multiple, widely distributed ignition sites, which consume the main charge rapidly. This high energy ignition results from the partially combusted (reacting) pre-chamber products initiating combustion in the main chamber. The distributed ignition sites enable relatively small flame travel distances enabling short combustion durations and high burn rates. Multiple benefits include extending the knock limit and initiating combustion in very dilute mixtures (excess air and or EGR), with dilution levels being comparable to other low temperature combustion technologies (HCCI), without the complex control drawbacks.
Technical Paper

A New Manufacturing Technology for Induction Machine Copper Rotors

2002-06-03
2002-01-1888
The benefits of energy and operational cost savings from using copper rotors are well recognized. The main barrier to die casting copper rotors is short mold life. This paper introduces a new approach for manufacturing copper-bar rotors. Either copper, aluminum, or their alloys can be used for the end rings. Both solid-core and laminated-core rotors were built. High quality joints of aluminum to copper were produced and evaluated. This technology can also be used for manufacturing aluminum bar rotors with aluminum end rings. Further investigation is needed to study the lifetime reliability of the joint. The improvement of manufacturing fixture through prototype test is also required.
Journal Article

A Normally Aspirated Spark Initiated Combustion System Capable of High Load, High Efficiency and Near Zero NOx Emissions in a Modern Vehicle Powertrain

2010-10-25
2010-01-2196
Turbulent Jet Ignition is an advanced spark-initiated pre-chamber combustion system for an otherwise standard spark ignition engine found in current on-road vehicles. This next-generation pre-chamber design simply replaces the spark plug in a conventional spark ignition engine. Turbulent Jet Ignition enables very fast burn rates due to the ignition system producing multiple, widely distributed ignition sites, which consume the main charge rapidly. This high energy ignition system results from the partially combusted (reacting) prechamber products initiating main chamber combustion. The fast burn rates allow for increased levels of dilution (lean burn and/or EGR) when compared to conventional spark ignition combustion, with dilution levels being comparable to other low temperature combustion technologies (HCCI) without the complex control drawbacks.
Technical Paper

A Novel Capability for Crush Testing Crash Energy Management Structures at Intermediate Rates

2002-06-03
2002-01-1954
The crush performance of lightweight composite automotive structures varies significantly between static and dynamic test conditions. This paper discusses the development of a new dynamic testing facility that can be used to characterize crash performance at high loads and constant speed. Previous research results from the Energy Management Working Group (EMWG) of the Automotive Composites Consortium (ACC) showed that the static crush resistance of composite tubes can be significantly greater than dynamic crush results at speeds greater than 2 m/s. The new testing facility will provide the unique capability to crush structures at high loads in the intermediate velocity range. A novel machine control system was designed and projections of the machine performance indicate its compliance with the desired test tolerances. The test machine will be part of a national user facility at the Oak Ridge National Laboratory (ORNL) and will be available for use in the summer of 2002.
Technical Paper

A Review of Pre-Chamber Initiated Jet Ignition Combustion Systems

2010-10-25
2010-01-2263
This paper reviews progress on turbulent jet ignition systems for otherwise standard spark ignition engines, with focus on small prechamber systems (≺3% of clearance volume) with auxiliary pre-chamber fueling. The review covers a range of systems including early designs such as those by Gussak and Oppenheim and more recent designs proposed by General Motors Corporation, FEV, Bosch and MAHLE Powertrain. A major advantage of jet ignition systems is that they enable very fast burn rates due to the ignition system producing multiple, distributed ignition sites, which consume the main charge rapidly and with minimal combustion variability. The locally distributed ignition sites allow for increased levels of dilution (lean burn/EGR) when compared to conventional spark ignition combustion. Dilution levels are comparable to those reported in recent homogeneous charge compression ignition (HCCI) systems.
Journal Article

A Single Fuel Pre-Chamber Jet Ignition Powertrain Achieving High Load, High Efficiency and Near Zero NOx Emissions

2011-08-30
2011-01-2023
Turbulent Jet Ignition is an advanced spark initiated pre-chamber combustion system for otherwise standard spark ignition engines found in current passenger vehicles. This next generation pre-chamber design simply replaces the spark plug in a conventional spark ignition engine. Turbulent Jet Ignition enables very fast burn rates due to the ignition system producing multiple, widely distributed ignition sites, which consume the main charge rapidly. This high energy ignition results from the partially combusted (reacting) pre-chamber products initiating combustion in the main chamber. The distributed ignition sites enable relatively small flame travel distances enabling short combustion durations and high burn rates. Multiple benefits include extending the knock limit and initiating combustion in very dilute mixtures (excess air and/or EGR), with dilution levels being comparable to other low temperature combustion technologies (HCCI), without the complex control drawbacks.
Technical Paper

A Thermal Conductivity Approach for Measuring Hydrogen in Engine Exhaust

2004-10-25
2004-01-2908
Thermal conductivity detection has long been used in gas chromatography to detect hydrogen and other diatomic gases in a gas sample. Thermal conductivity instruments that are not coupled to gas chromatographs are useful for detecting hydrogen in binary gas mixtures, but suffer from significant cross-interference from other gas species that are separated when the detector is used with a gas chromatograph. This study reports a method for using a commercially-available thermal conductivity instrument to detect and quantify hydrogen in a diesel exhaust stream. The instrument time response of approximately 40 seconds is sufficient for steady-state applications. Cross-interference from relevant gas species are quantified and discussed. Measurement uncertainty associated with the corrections for the various species is estimated and practical implications for use of the instrument and method are discussed.
Journal Article

A Turbulent Jet Ignition Pre-Chamber Combustion System for Large Fuel Economy Improvements in a Modern Vehicle Powertrain

2010-05-05
2010-01-1457
Turbulent Jet Ignition is an advanced pre-chamber initiated combustion system for an otherwise standard spark ignition engine found in current on-road vehicles. This next-generation pre-chamber design overcomes previous packaging obstacles by simply replacing the spark plug in a modern four-valve, pent roof spark ignition engine. Turbulent Jet Ignition enables very fast burn rates due to the ignition system producing multiple, distributed ignition sites, which consume the main charge rapidly and with minimal combustion variability. The fast burn rates allow for increased levels of dilution (lean burn and/or EGR) when compared to conventional spark ignition combustion, with dilution levels being comparable to other low temperature combustion technologies (homogeneous charge compression ignition - HCCI) without the complex control drawbacks.
Technical Paper

A Waste Heat Recovery System for Light Duty Diesel Engines

2010-10-25
2010-01-2205
In order to achieve proposed fuel economy requirements, engines must make better use of the available fuel energy. Regardless of how efficient the engine is, there will still be a significant fraction of the fuel energy that is rejected in the exhaust and coolant streams. One viable technology for recovering this waste heat is an Organic Rankine Cycle. This cycle heats a working fluid using these heat streams and expands the fluid through a turbine to produce shaft power. The present work was the development of such a system applied to a light duty diesel engine. This lab demonstration was designed to maximize the peak brake thermal efficiency of the engine, and the combined system achieved an efficiency of 45%. The design of the system is discussed, as are the experimental performance results. The system potential at typical operating conditions was evaluated to determine the practicality of installing such a system in a vehicle.
Technical Paper

Achieving Diesel-Like Efficiency in a High Stroke-to-Bore Ratio DISI Engine under Stoichiometric Operation

2020-04-14
2020-01-0293
This work explores pathways to achieve diesel-like, high-efficiency combustion with stoichiometric 3-way catalyst compatible spark ignition (SI). A high stroke-to-bore engine design (1.5:1) with cooled exhaust gas recirculation (EGR) and high compression ratio (rc) was used to improve engine efficiency by up to 30% compared with a production turbocharged gasoline direct injection spark ignition engine. To achieve efficiency improvements, engine experiments were coupled with computational fluid dynamics simulations to guide and explain experimental trends between the original engine and the high stroke-to-bore ratio design (1.5:1). The effects of EGR and late intake valve closing (IVC) and fuel characteristics are investigated through their effects on knock mitigation. Direct injection of 91 RON E10 gasoline, 99 RON E0 gasoline, and liquified petroleum gas (i.e., propane/autogas) were evaluated with geometric rc ranging from 13.3:1 to 16.8:1.
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