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Studies have been conducted at Michigan Technological University (MTU) for over twenty years on methods for characterizing and controlling particulate emissions from heavy-duty diesel engines and the resulting effects on regulated and unregulated emissions. During that time, control technologies have developed in response to more stringent EPA standards for diesel emissions. This paper is a review of: 1) modern emission control technologies, 2) emissions sampling and chemical, physical and biological characterization methods and 3) summary results from recent studies conducted at MTU on heavy-duty diesel engines with a trap and an oxidation catalytic converter (OCC) operated on three different fuels. Control technology developments discussed are particulate traps, catalysts, advances in engine design, the application of exhaust gas recirculation (EGR), and modifications of fuel formulations.

Various measurement techniques were employed to quantify sulfuric acid deposition levels and concentration of sulfuric acid in the condensate from the recirculated exhaust gas heat exchanger of a 1995 Cummins M11 heavy-duty diesel engine. Methods employed included a modified version of the sulfur species sampling system developed by Kreso et al. (1)*, rinsing the heat exchanger, and experiments employing a condensate collection device (CCD). The modified sampling system was applied to the inlet and outlet of the heat exchanger in order to quantify the changes in various sulfur compounds. Doped sulfur fuel (3300 to 4000 ppm S) was used to increase the concentrations of the various oxides of sulfur (SOx). These tests were performed at mode 9 of the old EPA 13-mode test cycle (1800 RPM, 932N*m) with 17-20% exhaust gas recirculation (EGR) at two EGR outlet temperatures: 160°C and 103°C.

The effects of a catalyzed particulate filter (CPF) and Exhaust Gas Recirculation (EGR) on heavy-duty diesel engine emissions were studied in this research. EGR is used to reduce the NOx emissions but at the same time it can increase total particulate matter (TPM) emissions. CPF is technology available for retrofitting existing vehicles in the field to reduce the TPM emissions. A conventional low sulfur fuel (371 ppm S) was used in all the engine runs. Steady-state loading and regeneration experiments were performed with CPF I to determine its performance with respect to pressure drop and particulate mass characteristics at different engine operating conditions. From the dilution tunnel emission characterization results for CPF II, at Mode 11 condition (25% load - 311 Nm, 1800 rpm), the TPM, HC and vapor phase emissions (XOC) were decreased by 70%, 62% and 62% respectively downstream of the CPF II.

The effects of exhaust gas recirculation (EGR) on heavy-duty diesel emissions were studied at two EPA steady-state operating conditions, old EPA mode 9* (1800 RPM, 75% Load) and old EPA mode 11 (1800 RPM, 25% Load). Data were collected at the baseline, 10% and 16% EGR rates for both EPA modes. The study was conducted using a 1995 Cummins M11-330E heavy-duty diesel engine and compared to the baseline emissions from the Cummins 1988 and 1991 L10 engines. The baseline gas-, vapor- and particle-phase emissions were measured together with the particle size distributions at all modes of operation. The total particulate matter (TPM) and vapor phase (XOC) samples were analyzed for physical, chemical and biological properties. The results showed that newer engines with electronic engine controls and higher injector pressures produce TPM decreases from the 1988 to 1991 to 1995 engines with the solids decreasing more than the soluble organic fraction (SOF) of TPM.

The goals of this research are to understand the regeneration process in ceramic (Cordierite) monolith traps using a copper fuel additive and to investigate the various conditions that lead to trap regeneration failure. The copper additive lowers the trap regeneration temperature from approximately 500 °C to 375 °C and decreases the time necessary for regeneration. Because of these characteristics, it is important to understand the effect of the additive on regeneration when excessive particulate matter accumulation occurs in the trap. The effects of particulate mass loading on regeneration temperatures and regeneration time were studied for both the controlled (engine operated at full load rated speed) and uncontrolled (trap regeneration initiated at full load rated speed after which the engine was cut to idle) conditions. The trap peak temperatures were higher for the uncontrolled than the controlled regeneration.

The deformation characteristics of sheet metal in the vicinity of the drawbead end are different from those in the continuous main part of the drawbead. The full three-dimensional elastic-plastic finite element method is used to analyze the influence of the drawbead end geometry and the clearance between the drawbead and Its groove on the drawbead restraining effect, deformation patterns and strain paths. It is found that wrinkles and tearing are the main defects resulting from improper design of the drawbead geometry. The present analysis is intended to provide some basic information for generating the design guidelines.

An optical technique for measuring transient combustion chamber surface temperatures in a fired engine has been developed. The spectral region from 3.6 to 4.0 microns was found to be suitable for making optical measurements through the methane-air flame. The experimental apparatus was capable of making simultaneous time-resolved measurements of infrared gas absorption, gas emission and surface radiation during a single engine cycle. The effects of engine operating conditions on gas absorption and gas emission were investigated. Measurements of “simulated” deposits at temperatures ranging from 569 K to 944 K indicated that the technique was accurate within 7 K at the higher temperatures.

The destruction of organic contaminants in waste water for closed systems, such as that of the International Space Station, is crucial due to the need for recycling the waste water. A cocurrent upflow bubble column using oxygen as the gas phase oxidant and packed with catalyst particles consisting of a noble metal on an alumina substrate is being developed for this process. This paper addresses the development of a plug-flow model that will predict the performance of this three phase reactor system in destroying a multicomponent mixture of organic contaminants in water. Mass balances on a series of contaminants and oxygen in both the liquid and gas phases are used to develop this model. These mass balances incorporate the gas-to-liquid and liquid-to-particle mass transfer coefficients, the catalyst effectiveness factor, and intrinsic reaction rate.

This collection is a resource for studying the history of the evolving technologies that have contributed to snowmobiles becoming cleaner and quieter machines. Papers address design for a snowmobile using E10 gasoline (10% ethanol mixed with pump gasoline). Performance technologies that are presented include: • Engine Design: application of the four-stroke engine • Applications to address both engine and track noise • Exhaust After-treatment to reduce emissions The SAE International Clean Snowmobile Challenge (CSC) program is an engineering design competition. The program provides undergraduate and graduate students the opportunity to enhance their engineering design and project management skills by reengineering a snowmobile to reduce emissions and noise. The competition includes internal combustion engine categories that address both gasoline and diesel, as well as the zero emissions category in which range and draw bar performance are measured.

The objective of this research was to evaluate the effects that higher fluid injection pressures and nozzle geometry have on compound fuel injector nozzle performance. Higher pressures are shown to significantly reduce droplet size, increase the discharge coefficient and reduce the overall size of a nozzle spray. It is also shown that the geometry has a significant effect on nozzle performance, and it can be manipulated to give a desired spray shape.

The goal of this research was to determine an empirical method of relating the droplet sizes and the spray patterns to the parameters and the geometries of the compound nozzles. Two different types of compound nozzles were studied, the compound silicon micro machined nozzle and the compound metal disk nozzle. Several different orifice geometries of each nozzle type were examined. The injector components upstream of the compound nozzle of two different types of injectors were also studied. A nondimensional characterization of the droplet sizes and the mass flow rates was proposed. The results of this study show that there exists optimum geometric features that will produce sprays with the minimum steady state and dynamic Sauter mean diameter. The spray of a compound nozzle can be characterized by the atomization efficiency and the discharge coefficient. Nozzle testing results show that many flow characteristics are developed in the compound nozzle.

Dimethyl ether (DME) appears to be an attractive alternative to common fossil fuels in compression ignition engines due to its smokeless combustion and fast mixture formation. However, in order to fully understand the complex combustion process of DME, there is still a remaining need to develop a comprehensive chemical kinetic mechanism that includes both soot and NOx chemistry. In this study, a detailed DME mechanism with 305 species is developed from the basic DME mechanism of Curran et al. (2000) with addition of soot and NOx chemistry from Howard's mechanism et al. (1999), and GRI 3.0 mechanism, respectively. Soot chemistry in Howard mechanism consisting hydrogen abstraction acetylene addition (HACA) and growth of small polycyclic aromatic hydrocarbons (PAH), assesses over a wide range of temperature and is able to predict good to fair the formation of PAH up to coronene.

Aluminum based brake rotors have been a priority research topic in the DOE 1999 Aluminum Industry Roadmap for the Automobile Market. After fourteen years, no satisfactory technology has been developed to solve the problem of aluminum's low working temperatures except the steel clad aluminum (SCA) brake technology. This technology research started at Michigan Technological University (MTU) in 2001 and has matured recently for commercial productions. The SCA brake rotor has a solid body and replaces the traditional convective cooling of a vented rotor with conductive cooling to a connected aluminum wheel. Much lower temperatures result with the aluminum wheel acting as a great heat sink/radiator. The steel cladding further increases the capability of the SCA rotor to withstand higher surface temperatures. During the road tests of SCA rotors on three cars, significant gas mileage improvement was found; primarily attributed to the unique capability of the SCA rotor on pad drag reduction.

This research quantifies the effects of a copper fuel additive on the regulated [oxides of nitrogen (NOx), hydrocarbons (HC) and total particulate matter (TPM)] and unregulated emissions [soluble organic fraction (SOF), vapor phase organics (XOC), polynuclear aromatic hydrocarbons (PAH), nitro-PAH, particle size distributions and mutagenic activity] from a 1988 Cummins LTA10 diesel engine using a low sulfur fuel. The engine was operated at two steady state modes (EPA modes 9 and 11, which are 75 and 25% load at rated speed, respectively) and five additive levels (0, 15, 30, 60 and 100 ppm Cu by mass) with and without a ceramic trap. Measurements of PAH and mutagenic activity were limited to the 0, 30 and 60 ppm Cu levels. Data were also collected to assess the effect of the additive on regeneration temperature and duration. Copper species collected within the trap were identified and exhaust copper concentrations quantified.

Engine friction serves as an important domain for study and research in the field of internal combustion engines. Research shows that friction between the piston and cylinder accounts for almost 20% of the losses in an engine and therefore any effort to minimize friction losses will have an immediate impact on engine efficiency and thus vehicle fuel economy. The two most common methods to experimentally measure engine friction are the floating liner method and the instantaneous indicated mean effective pressure (IMEP) method. This paper provides a detailed review of the IMEP method, presents major findings, and discusses sources of error. Although the instantaneous IMEP method is relatively new compared to the floating liner method, it has been used by many scientists and engineers for calculating piston ring assembly friction with consistent results.

High performance auto parts such as aluminum composite cladding aluminum brake and Ti/Ti3/Al joined exhaust valve with localized Ti+TiC composite coating could be produced using a new manufacturing method - the CastCon process. The aluminum composite cladding aluminum brake consists of an aluminum alloy body with a cladding of SiC and graphite particulate filled aluminum composite on the friction surface of a brake disk or a drum. This structure can ensure an over-all light weight and integral strength and ductility. The SiC particulate in the cladding composite increases abrasion resistance and the graphite particulate provides required lubrication. The cladding can be as thick as desired. There is a flexibility in the manufacturing process for selecting SiC and graphite loading volumes as well as particulate size and shape. This allows the part to be engineered to achieve maximum performance.

This study evaluates iso-butanol as a pathway to introduce higher levels of alternative fuels for recreational marine engine applications compared to ethanol. Butanol, a 4-carbon alcohol, has an energy density closer to gasoline than ethanol. Isobutanol at 16 vol% blend level in gasoline (iB16) exhibits energy content as well as oxygen content identical to E10. Tests with these two blends, as well as indolene as a reference fuel, were conducted on a Mercury 90 HP, 4-stroke outboard engine featuring computer controlled sequential multi-port Electronic Fuel Injection (EFI). The test matrix included full load curves as well as the 5-mode steady-state marine engine test cycle. Analysis of the full load tests suggests that equal full load performance is achieved across the engine speed band regardless of fuel at a 15-20°C increase in exhaust gas temperatures for the alcohol blends compared to indolene.

A numerical analysis was performed to study the variation of the laminar burning speed of gasoline-ethanol blend, pressure, temperature and dilution using the one-dimensional premixed flame code CHEMKIN™. A semi-detailed validated chemical kinetic model (142 species and 672 reactions) for a gasoline surrogate fuel was used. The pure components in the surrogate fuel consist of n-heptane, isooctane and toluene. The ethanol mole fraction was varied from 0 to 85 percent, initial pressure from 4 to 8 bar, initial temperature from 300 to 600K, and the EGR dilution from 0 to 32% to represent the in-cylinder conditions of a spark-ignition engine. The laminar flame speed is found to increase with ethanol concentration and temperature but decrease with pressure and dilution.

A numerical simulation of autoignition of gasoline-ethanol/air mixtures has been performed using the closed homogeneous reactor model in CHEMKIN® to compute the dependence of autoignition time with ethanol concentration, pressure, temperature, dilution, and equivalence ratio. A semi-detailed validated chemical kinetic model with 142 species and 672 reactions for a gasoline surrogate fuel with ethanol has been used. The pure components in the surrogate fuel consisted of n-heptane, isooctane and toluene. The ethanol volume fraction is varied between 0 to 85%, initial pressure is varied between 20 to 60 bar, initial temperature is varied between 800 to 1200K, and the dilution is varied between 0 to 32% at equivalence ratios of 0.5, 1.0 and 1.5 to represent the in-cylinder conditions of a spark-ignition engine. The ignition time is taken to be the point where the rate of change of temperature with respect to time is the largest (temperature inflection point criteria).

One-dimensional simulation methods for unsteady (transient) engine operations have been developed and published in previous studies. These 1-D methods utilize heat release and emissions results obtained from 3-D CFD simulations which are stored in a data library. The goal of this study is to improve the 1-D methodology by optimizing the control strategies. Also, additional independent parameters are introduced to extend the 3-D data library, while, as in the previous studies, the number of interpolation points for each parameter remains small. The data points for the 3-D simulations are selected in the vicinity of the expected trajectories obtained from the independent parameter changes, as predicted by the transient 1-D simulations. By this approach, the number of time-consuming 3-D simulations is limited to a reasonable amount.