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Hydrogen is widely considered a promising fuel for future transportation applications for both, internal combustion engines and fuel cells. Due to their advanced stage of development and immediate availability hydrogen combustion engines could act as a bridging technology towards a wide-spread hydrogen infrastructure. Although fuel cell vehicles are expected to surpass hydrogen combustion engine vehicles in terms of efficiency, the difference in efficiency might not be as significant as widely anticipated [1]. Hydrogen combustion engines have been shown capable of achieving efficiencies of up to 45 % [2]. One of the remaining challenges is the reduction of nitric oxide emissions while achieving peak engine efficiencies. This paper summarizes research work performed on a single-cylinder hydrogen direct injection engine at Argonne National Laboratory.

The U.S. Renewable Fuel Standard (RFS2) requires an increase in the use of advanced biofuels up to 36 billion gallons by 2022. Longer chain alcohols, in addition to cellulosic ethanol and synthetic biofuels, could be used to meet this demand while adhering to the RFS2 corn-based ethanol limitation. Higher carbon number alcohols can be utilized to improve the energy content, knock resistance, and/or petroleum displacement of gasoline-alcohol blends compared to traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part I of this paper focuses on the development of scenarios by which to compare higher alcohol fuel blends to traditional ethanol blends. It also details the implementation of fuel property prediction methods adapted from literature. Possible combinations of eight alcohols mixed with a gasoline blendstock were calculated and the properties of the theoretical fuel blends were predicted.

Higher carbon number alcohols offer an opportunity to meet the Renewable Fuel Standard (RFS2) and improve the energy content, petroleum displacement, and/or knock resistance of gasoline-alcohol blends from traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part II of this paper builds upon the alcohol selection, fuel implementation scenarios, criteria target values, and property prediction methodologies detailed in Part I. For each scenario, optimization schemes include maximizing energy content, knock resistance, or petroleum displacement. Optimum blend composition is very sensitive to energy content, knock resistance, vapor pressure, and oxygen content criteria target values. Iso-propanol is favored in both scenarios' suitable blends because of its high RON value.

Performing acoustic measurements on or near engines, transmissions, as well as in other circumstances where the environment is hazardous and harsh for microphones requires special precautions. Fluids inevitably leak, and the possibility of transducer damage can be very high without proper protection. Properly protecting microphones during testing allows for consistent data quality in these hazardous and difficult environments. While this paper will present the use of a 5 mil Nitrile cover which protects against many fluids within the scope of automotive testing, including water, hydrocarbons, and alcohols, as well as having good heat resistance and high strength, the concepts developed are applicable to other types of microphone protective mechanisms. Acoustic sensitivity was measured and used to calculate the change of the microphone's response after the treatment is applied, as well as after being exposed to various contaminants.

A three phase catalytic mathematical model was developed for analysis and optimization of the volatile reactor assembly (VRA) used on International Space Station (ISS) Water Processor. The Langmuir-Hinshelwood Hougen-Watson (L-H) expression was used to describe the surface reaction rate. Small column experiments were used to determine the L-H rate parameters. The test components used in the experiments were acetic acid, acetone, ethanol, 1-propanol, 2-propanol and propionic acid. These compounds are the most prevalent ones found in the influent to the VRA reactor. The VRA model was able to predict performance of small column data and experimental data from the VRA flight experiment.

Optical and laser diagnostics enable in-depth spray characterization in regards to macroscopic spray characteristics and in-situ fuel mixture quality information, which are needed in understanding the spray injection process and for spray model development, validation and calibration. Use of fuel surrogates in spray researches is beneficial in controlling fuel parameters, developing spray and combustion kinetic models, and performing laser diagnostics with known fluorescence characteristics. This study quantifies and evaluates the macroscopic spray characteristics of a single and multi-component surrogate in comparison to a gasoline with 10% ethanol under gasoline direct injection (GDI) engine conditions. In addition, the effect of fuel tracers on spray evolution and vaporization is also investigated. Both diethyl-methyl-amine/fluorobenzene as a laser-induced exciplex (LIEF) fluorescence tracer pair and 3-pentanone as a laser-induced fluorescence (LIF) tracer are examined.

The favorable physical properties of hydrogen (H2) make it an excellent alternative fuel for internal combustion (IC) engines and hence it is widely regarded as the energy carrier of the future. Hydrogen direct injection provides multiple degrees of freedom for engine optimization and influencing the in-cylinder combustion processes. This paper compares the results in the mixture formation and combustion behavior of a hydrogen direct-injected single-cylinder research engine using two different injector locations as well as various injector nozzle designs. For this study the research engine was equipped with a specially designed cylinder head that allows accommodating a hydrogen injector in a side location between the intake valves as well as in the center location adjacent to the spark plug.

Water injection has been used to reduce the charge temperature and mitigate knocking due to its higher latent heat of vaporization compared to gasoline fuel. When water is injected into the intake manifold or into the cylinder, it evaporates by absorbing heat energy from the surrounding and results in charge cooling. However, the effect of detailed evaporation process on the combustion characteristics under gasoline direct injection relevant conditions still needs to be investigated. Therefore, spray study was firstly conducted using a multi-hole injector by injecting pure water and water-methanol mixture into constant volume combustion chamber (CVCC) at naturally aspirated and boosted engine conditions. The target water-fuel ratio was fixed at 0.5. Mie-scattering and schlieren images of sprays were analyzed to study spray characteristics, and evaluate the amount of water vaporization.

Anti-knock index (AKI) is a metric that can be used to quantify the anti-knock performance of a fuel and is the metric used in the United States. AKI is the average of Research Octane Number (RON) and Motor Octane Number (MON), which are calculated for every fuel on a Cooperative Fuel Research (CFR) engine under controlled conditions according to ASTM test procedures. Fuels with higher AKI have better knock mitigating properties and can be run with a combustion phasing closer to MBT in the knock limited operating region of a gasoline engine. However, fuels with higher AKI tend to be costlier and less environmentally friendly to produce. As an alternative, the anti-knock characteristics of lower AKI fuels can be improved with water injection. In this sense, the water injection increases the ‘effective AKI’ of the fuel.

This is the second part of a study on using port water injection to quantifiably enhance the knock performance of fuels. In the United States, the metric used to quantify the anti-knock performance of fuels is Anti Knock Index (AKI), which is the average of Research Octane Number (RON) and Motor Octane Number (MON). Fuels with higher AKI are expected to have better knock mitigating properties, enabling the engine to run closer to Maximum Brake Torque (MBT) spark timing in the knock limited region. The work done in part I of the study related increased knock tolerance due to water injection to increased fuel AKI, thus establishing an ‘effective AKI’ due to water injection. This paper builds upon the work done in part I of the study by repeating a part of the test matrix with Primary Reference Fuels (PRFs), with iso-octane (PRF100) as the reference fuel and lower PRFs used to match its performance with the help of port water injection.

When fuel at elevated temperatures is injected into an ambient environment at a pressure lower than the saturation pressure of the fuel, the fuel vaporizes in the nozzle and/or immediately upon exiting the nozzle; that is, it undergoes flash boiling. It is characterized by a two-phase flow regime co-located with primary breakup, which significantly affects the spray characteristics. Under flash boiling conditions, the near nozzle spray angle increases, which can lead to shorter penetration because of increased entrainment. In a multi-hole injector this can cause other impacts downstream resulting from the increased plume to plume interactions. To study the effect of injector temperature and injection pressure with real fuels, an experimental investigation of the spray characteristics of a summer grade gasoline fuel with 10% ethanol (E10) was conducted in an optically accessible constant volume spray vessel.

The application of hydrogen (H2) as an internal combustion (IC) engine fuel has been under investigation for several decades. The favorable physical properties of hydrogen make it an excellent alternative fuel for IC engines and hence it is widely regarded as the energy carrier of the future. Direct injection of hydrogen allows optimizing this potential as it provides multiple degrees of freedom to influence the in-cylinder combustion processes and consequently engine efficiency and exhaust emissions. At certain operating conditions the stratification associated with hydrogen direct injection (DI) leads to an efficiency improvement. However, it also results in higher emissions levels. This paper examines the effects of combining an advanced direct injection strategy with water injection for efficiency benefits and emissions reduction of a hydrogen fuelled DI spark ignition (SI) engine.

The characteristics of combustion knock metrics over a number of engine cycles can be an essential reference for knock detection and control in internal combustion engines. In a Spark-Ignition (SI) engine, the stochastic nature of combustion knock has been shown to follow a log-normal distribution. However, this has been derived from experiments done with gasoline only and applicability of log-normal distribution to dual-fuel combustion knock has not been explored. To evaluate the effectiveness and accuracy of log-normal distributed knock model for methane-gasoline blended fuel, a sweep of methane-gasoline blend ratio was conducted at two different engine speeds. Experimental investigation was conducted on a single cylinder prototype SI engine equipped with two fuel systems: a direct injection (DI) system for gasoline and a port fuel injection (PFI) system for methane.

Recently, outboard engine technology has advanced significantly. With these new technologies comes a substantial improvement in emissions compared to traditional carbureted two-stroke engines. Some two-stroke gasoline direct injection (GDI) marine outboard engines are now capable of meeting California Air Resources Board 2008 Ultra-Low emissions standards. With improvement of gaseous emissions, studies are now being conducted to assess particulate matter (PM) emissions from all new technology marine outboard engines which include both four-stroke and two-stroke designs. Methods are currently being developed to determine the best way to measure PM from outboard engines. This study assesses gaseous and PM emissions, mutagenic activity of PM and oil consumption of two different technologies over the useful life of the engines.

This paper aims to provide the experimental and numerical investigation of a single fuel droplet impingement on the different wall conditions to understand the detailed impinging dynamic process. The experimental work was carried out at the room temperature and pressure except for the variation of the impinged wall temperature. A high-speed camera was employed to capture the silhouette of the droplet impinging on wall process against a collimated light. Water, diesel, n-dodecane, and n-heptane were considered as four different droplets and injected from a precision syringe pump with the volume flow rate of 0.2 mL/min at various impact Weber numbers. The impingement outcomes after droplet impacting on the wall include stick, spread, rebound and splash, which depend on the controlling parameters of Weber number, Reynolds number, liquid and surface properties, etc.

The application of hydrogen (H2) as an internal combustion (IC) engine fuel has been under investigation for several decades. The favorable physical properties of hydrogen make it an excellent alternative fuel for fuel cells as well as IC engines and hence it is widely regarded as the energy carrier of the future. The potential of hydrogen as an IC engine fuel can be optimized by direct injection (DI) as it provides multiple degrees of freedom to influence the in-cylinder combustion processes and consequently the engine efficiency and exhaust emissions. This paper studies a single-hole nozzle and examines the effects of injection strategy on engine efficiency, combustion behavior and NOx emissions. The experiments for this study are done on a 0.5 liter single-cylinder research engine which is specifically designed for combustion studies and equipped with a cylinder head that allows side as well as central injector location.

One-dimensional single-zone and two-zone analyses have been exercised to calculate the mass fraction burned in an engine operating on ethanol/gasoline-blended fuels using the cylinder pressure and volume data. The analyses include heat transfer and crevice volume effects on the calculated mass fraction burned. A comparison between the two methods is performed starting from the derivation of conservation of energy and the method to solve the mass fraction burned rates through the results including detailed explanation of the observed differences and trends. The apparent heat release method is used as a point of reference in the comparison process. Both models are solved using the LU matrix factorization and first-order Euler integration.