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Technical Paper

Development of Low-Ash Type Heavy Duty Diesel Engine Oil for After-Treatment Devices

2004-06-08
2004-01-1955
In order to meet the increasingly tough emission regulations on diesel vehicles, automobile manufacturers in Japan are focusing on the development of diesel particulate filters (DPFs), nitrogen-oxide-reducing catalysts so-called deNOx catalysts, and other technology for reducing exhaust gases. In order to reduce catalyst poisoning, diesel fuel with a sulfur content of 50 ppm or lower-one-tenth the previous level-was put on the market in Japan in April 2003. At the same time, guidelines took effect for the new DH-2 and DL-1 standards for diesel engine oils compatible with after-treatment devices; the full regulations are scheduled to come into force in 2005. The newly developed low-ash diesel engine oil described here contains a reduced amount of metallic detergents, thus lowering the sulfated ash content to about two-thirds that of conventional high-ash oil.
Technical Paper

Development of New Hydraulic Fluids Specifications for Construction Machinery

2005-11-01
2005-01-3574
Hydraulic fluid (HF) specifications for mobile construction equipment called JCMAS HK and HKB have been established by the Fuels and Lubricants Committee of Japan Construction Mechanization Association (JCMA). The specifications are designated by two viscosity categories of single grade and multigrade. Each category has ISO viscosity grade (VG) 32 and 46. The JCMAS HK oils are recommended for use in hydraulic systems designed at pressure up to 34.3MPa(5000psi) and to heat hydraulic fluid up to 100 °C. These oils also provide wear control, friction performance, oxidation and rust protection, seal swell control and filterability performance. Two piston pump test procedures were developed to evaluate lubricating performance of these oils under high pressure conditions. The JACMAS HKB oils are classified as environmentally friendly oils due to the additional requirement for biodegradability.
Technical Paper

Effects of Fuel Properties on the Performance of Advanced Diesel NOx Aftertreatment Devices

2006-10-16
2006-01-3443
In the Japan Clean Air Program II (JCAP II) Diesel WG, effects of fuel properties on the performance of two types of diesel NOx emission aftertreatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined. For a Urea-SCR system, the NOx emission reduction performance with and without an oxidation catalyst installed in front of the SCR catalyst at low exhaust gas temperature operation was compared. For an NSR catalyst system, the effect of fuel sulfur on both emissions and fuel economy during 50,000 km driving was examined. Furthermore, effects of other fuel properties such as distillation on exhaust emissions were investigated. The results show that sulfur is the influential factor for both devices. Namely, high NOx emission reduction performance of the Urea-SCR system with the oxidation catalyst at low exhaust gas temperature operation is influenced by sulfur.
Technical Paper

Effects of Sulfur, Aromatics, T50, T90 and MTBE on Mass Exhaust Emissions from Vehicles with Advanced Technology - JCAP Gasoline WG STEP II Report -

2003-05-19
2003-01-1905
An overview of STEP II activity of JCAP gasoline working group is presented. The main evaluation of STEP II was conducted with advanced gasoline-powered vehicle and fuel technologies for reducing exhaust emissions. 4 models of prototype vehicles were prepared for evaluation. 3 of them were SIDIs with lean NOx catalysts and another was MPI with three way catalyst. All test vehicles were designed with the target of 1/6 emission level of the FY 1978 Japanese regulations. Sulfur effects were evaluated by 30000km mileage accumulation tests using 2ppm, 22ppm and 86ppm sulfur gasolines. Exhaust emissions of SIDI vehicles were largely affected by the sulfur content but the degree of effect differed between vehicles. For further reduction of SIDI emissions, investigations about “Package technology” of vehicle and fuel - sulfur durability improvement of lean NOx catalyst and sulfur reduction of fuel - with consideration about “Well to Wheels” CO2 are necessary.
Technical Paper

Evaluation of Diesel Exhaust Emission of Advanced Emission Control Technologies using various Diesel Fuels, and Sulfur Effect on Performance after Mileage Accumulation. -JCAP Diesel WG (fuel) Report for Step II study-

2003-05-19
2003-01-1907
To investigate the future direction of diesel emission control technologies and fuel technologies, exhaust emissions tests of diesel vehicles/engines with advanced after-treatments such as NSR catalyst, CR-DPF, and Urea-SCR or a combination of these, were conducted using various fuels, and fuel sulfur effect on performance of the after-treatments after mileage accumulation was also evaluated in step II study of JCAP Diesel WG. Overall results shows that the after-treatments have significant effects on reducing emission and reducing fuel sulfur have significant effects on function of the after-treatments in term of decrease of sulfate and SOF, and less deterioration of function of after-treatments after mileage accumulation.
Technical Paper

JCMAS New Grease Specifications for Construction Machinery

2006-10-31
2006-01-3504
Since construction machinery manufacturers recommend various brands and types of greases for their machinery, customers would benefit from a standardized grease which can be used in all construction machinery. Furthermore, construction machinery manufacturers have many experiences of field problems caused by commercially available and commonly used EP Lithium greases. Therefore, the Fuels and Lubricants Committee of Japan Construction Mechanization Association (JCMA) has developed a new grease specification called “Japan Construction Mechanization Association Specification (JCMAS) GK,” for construction equipment. The JCMAS GK includes requirements for National Lubrication and Grease Institute (NLGI) No. 1 and No. 2 consistency grades. The JCMAS GK greases have enough lubricating properties for periodical grease fitting of most construction machines, hydraulic excavators, bulldozers and wheel loaders. The JCMAS GK greases are applicable from -20 to +130 degrees Celsius.
Technical Paper

Long Drain/Fuel Efficient Engine Oils Based on the ZDTP Substitute Additive Technologhy

2003-05-19
2003-01-2003
Zinc dialkylphosphate (ZP), a sulfur free analogue of Zinc dialkyldithiophosphate (ZDTP) has been synthesized and tested for engine oil application. The sulfur free engine oil based on ZP showed excellent TBN retention and engine cleanliness in several engine tests which were operated at low and high temperatures. A prototype low phosphorus (0.05%) and low sulfated ash (0.5%) engine oil exhibited even better longer drain performance than a fully synthetic engine oil containing 0.1% P and 1.1% sulfated ash. Thus, zinc dialkylphosphate can be a promising candidate as a ZDTP substitute for future catalyst system compatible engine oil.
Technical Paper

Operational performance of eco-friendly engine oils formulated with the sulfur-free additive ZP

2007-07-23
2007-01-1991
The authors have spent considerable time studying the sulfur-free additive ZP as a means to improve the environmental properties of engine oils. ZP is an alternative compound to ZDDP, which has been a key engine oil additive for over 50 years. The ZP molecule contains oxygen in place of the sulfur found in ZDDP. In our past studies, various engine tests confirmed that ZP-blend engine oils outperform ZDDP-blend oils in terms of long-life and fuel-saving properties. Moreover, by using ZP, levels of sulfur can be reduced without sacrificing the oils' primary performance characteristics, so there less of an adverse effect on emission control systems, and lower levels of vehicle emissions can be achieved. We conducted field tests involving dozens of vehicles to verify the fuel economy retention and long-life performance of ZP oils. We report the results in this paper.
Technical Paper

The Emission Performance of a GTL Diesel Fuel - a Japanese Market Study

2003-05-19
2003-01-1946
Comparative exhaust emission tests were performed on Japanese light- and heavy-duty vehicles fuelled with a Fischer-Tropsch diesel derived from natural gas and two crude oil-derived reference diesels. Both vehicles were tested without and with an oxidation catalyst fitted to the engine. In the case of the light-duty vehicle a current Japanese specification diesel and a future specification low sulphur diesel were used as reference while in the case of the heavy-duty vehicle only the low sulphur diesel was used as reference. The emission tests were performed using the standard Japanese emission test cycle applicable to that vehicle type. In addition certain selected modes from a special test cycle representative of congested traffic patterns encountered in the Tokyo inner city environment were used for both the light- and heavy-duty vehicles. In general, Fischer-Tropsch diesel reduced all the regulated emissions compared to both crude derived diesels.
Technical Paper

The Evaluation of the Fuel-Economy Performance of Low-Viscosity Drive-Train Lubricants and the Development of Oils with Improved Fatigue Life

2004-10-25
2004-01-3029
In recent years, progress has been made in reducing the viscosities of manual transmission fluids (MTFs) and automatic transmission fluids (ATFs). Lower viscosities of MTFs and ATFs are expected to improve the fuel economy of automobiles by reducing the viscous resistance. Examples of low-viscosity ATFs already commercially available include Toyota Auto Fluid WS and ZF Friedrichshafen AG's ZNF 13014. This paper first reports methods for measuring the torque transmission efficiency in manual and automatic transmissions. We explain a simple rig test that we developed using an IAE gear test machine, and we describe oil temperature increase tests and torque measurement tests using actual transmissions and fuel economy tests using actual vehicles. Next, we describe the effects of lower viscosities on the torque transfer efficiency as measured with these measurement methods.
Technical Paper

Wear Mechanisms of Steel Under Boundary Lubrication in Presence of Carbon Black and Graphite Nano-onions Particles

2008-10-06
2008-01-2461
Both carbon blacks and carbon nano-onions nanoparticles have a spheroidal shape and a nested structure. They can be used to simulate the presence of soots in used engine oils. When added to fully formulated fresh engines oils, these two kinds of particles behave very differently. Carbon black particles are highly abrasive causing a lot of wear of steel surfaces and friction increases. At the opposite, the addition of carbon onions in lubricant leads to a reduction of both friction and wear compared to pure base oil. This shows that there is an opportunity to control wear in engines by changing the structure of soots during the combustion process.
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