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A copper alloy powder composed of Cu-14Ni-3Si-2V-2Cr-1.5Fe-1Al-0.5P has been developed for application to laser-clad valve seats. Laser-clad valve seats offer several advantages such as higher engine output and improved fuel economy owing to lower valve head temperature and an increased intake throat diameter compared with conventional press-fit valve inserts made of ferro-based powder metal. Previously, a material having a principal chemical composition of Cu-12Ni-10Co-3Si-2V-2Nb-1.5Fe-1Al was developed to obtain large hard intermetallic compounds. The microstructure of this material is formed by a two-liquid separation reaction, which has been applied to powders of different chemical compositions for laser-clad valve seats of production engines. Although this material shows superior valve seat wear resistance, it has certain drawbacks, including the high cost of the powder, high probability of microcrack formation and low machinability of the laser-clad layer.

Internal combustion engines experience severe valve train wear and the reduction of valve seat and seat insert wear has been a long-standing issue. In this work, worn valve seats and inserts were examined to obtain a fundamental understanding of the wear mechanisms and the results were applied in developing new valve seat insert materials. The new exhaust valve insert material for gasoline engines is a sintered alloy steel containing Co-base hard particles, with lead infiltrated only for inserts used in unleaded gasoline engines. The new intake valve insert material for gasoline engines is a high-Mo sintered steel, obtained through transient liquid phase sintering and with copper precipitated uniformly. This material can be used for both leaded and unleaded gasoline engines. Valve and valve seat insert wear has long been an issue of concern to engine designers and manufacturers.

One important development area for obtaining better fuel economy is to reduce mechanical friction losses in engine components. The valvetrain is a significant source of mechanical friction loss in an automobile engine, especially at low speeds where fuel economy is most important. This paper describes the potential use of diamond-like carbon (DLC) coatings at the cam/follower interface in a bucket-type valvetrain. Using a pin-on-disk tester, a motored valvetrain friction apparatus and a bench test rig, the frictional performance of DLC coatings was tested. Experimental data indicate that under a lubricated condition, DLC coatings produced by a plasma CVD (chemical vapor deposition) technique did not show a sufficient effect on reducing friction (only a 20-25% reduction) contrary to our expectations. DLC coatings prepared by arc-ion plating and containing less hydrogen showed superior frictional performance compared with CVD-DLC coatings under a lubricated condition.