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Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NOx emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NOx reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NOx ratios.

The Magnesium Front End Research and Development (MFERD) project under the sponsorship of Canada, China, and USA aims to develop key technologies and a knowledge base for increased use of magnesium in automobiles. The primary goal of this life cycle assessment (LCA) study is to compare the energy and potential environmental impacts of advanced magnesium based front end parts of a North American-built 2007 GM-Cadillac CTS using the current steel structure as a baseline. An aluminium front end is also considered as an alternate light structure scenario. A “cradle-to-grave” LCA is conducted by including primary material production, semi-fabrication production, autoparts manufacturing and assembly, transportation, use phase, and end-of-life processing of autoparts. This LCA study was done in compliance with international standards ISO 14040:2006 [1] and ISO 14044:2006 [2].

This study investigates occupant containment characteristics of tempered and laminated automotive moveable side glass in rollover collisions. FMVSS 216 test protocols were used to induce roof damage or sheet metal damage around the window opening in Lincoln Navigators equipped with tempered and laminated side glass. Dummy-drop tests were then performed to investigate relative containment. The results demonstrate that, for rollovers in which the window structure is compromised, tempered side glass and laminated side glass perform comparably relative to occupant containment. Also discussed are the general strength characteristics of different types of glass construction, the availability of laminated side glass in recent model U.S. vehicles, and anecdotal data supporting the conclusions of testing.

Studies in an Angular Stretch Bend Test (ASBT) have demonstrated that the failure location moves from the side wall to punch nose area. This occurs as the R/T ratio decreases below a certain limit and applies to most low carbon steels with the exception of Dual Phase (DP) steels. Such behavior in DP steels indicates that bending effects have a severe impact on the formability of DP materials. Therefore, the traditional criterion using the forming limit curve (FLC) is not suitable to assess the formability at punch radius areas for DP steels due in part to its uniqueness of unconventional microstructures. In this paper, a new failure criterion, ‘Bending-modified’ FLC (BFLC), is proposed by extending the traditional FLC using the “Stretch Bendability Index” (SBI) concept for the stretch bendability assessment.

This project team conducted a life-cycle-based environmental evaluation of new, lightweight materials (e.g., titanium, magnesium) used in two concept 3XVs -- i.e., automobiles that are three times more fuel efficient than today's automobiles -- that are being designed and developed in support of the Partnership for a New Generation of Vehicles (PNGV) program. The two concept vehicles studied were the DaimlerChrysler ESX2 and the Ford P2000. Data for this research were drawn from a wide range of sources, including: the two automobile manufacturers; automobile industry reports; government and proprietary databases; past life-cycle assessments; interviews with industry experts; and models.

The benefits of energy and operational cost savings from using copper rotors are well recognized. The main barrier to die casting copper rotors is short mold life. This paper introduces a new approach for manufacturing copper-bar rotors. Either copper, aluminum, or their alloys can be used for the end rings. Both solid-core and laminated-core rotors were built. High quality joints of aluminum to copper were produced and evaluated. This technology can also be used for manufacturing aluminum bar rotors with aluminum end rings. Further investigation is needed to study the lifetime reliability of the joint. The improvement of manufacturing fixture through prototype test is also required.

A simple strategy for building lightweight automobile body-in-whites (BIWs) is developed and discussed herein. Because cost is a critical factor, expensive advanced materials, such as carbon fiber composites and magnesium, must only be used where they will be most effective. Constitutive laws for mass savings under various loading conditions indicate that these materials afford greater opportunity for mass saving when used in bending, buckling or torsion than in tensile, shear or compression. Consequently, it is recommended that these advanced materials be used in BIW components subject to bending and torsion such as rails, sills, “A-B-C” pillars, etc. Furthermore, BIW components primarily subject to tension, compression, or shear, such as floor pans, roofs, shock towers, etc., should be made from lower cost steel. Recommendations for future research that are consistent with this strategy are included.

The HTML (High Temperature Materials Laboratory) is a U.S. Department of Energy User Facility, offering opportunities for in-depth characterization of advanced materials, specializing in high-temperature-capable structural ceramics. Available are electron microscopy for micro-structural and microchemical analysis, equipment for measurement of the thermophysical and mechanical properties of ceramics to elevated temperatures, X-ray and neutron diffraction for structure and residual stress analysis, and high speed grinding machines with capability for measurement of component shape, tolerances, surface finish, and friction and wear properties. This presentation will focus on structural materials characterization, illustrated with examples of work performed on heat engine materials such as silicon nitride, industrial refractories, metal-and ceramic-matrix composites, and structural alloys.

In recent years, light weight components have been an area of significant importance in automotive design. This has led to the replacement of steel and cast iron with aluminum alloys for many automotive components. For instance, Al-Si alloys have successfully replaced nodular and gray cast iron in the production of large automotive components such as engine blocks. However, excessive residual strain along the cylinder bores of these engine blocks may result in cylinder distortion during engine operation. Therefore, in this study, neutron diffraction was used to evaluate residual strain along the aluminum cylinder bridge and the gray cast iron liners of distorted and undistorted engine blocks. The strains were measured in the hoop, radial, and axial orientations. The results suggest that the residual strain along the aluminum cylinder bridge of the distorted engine block was tensile for all three measured components.

Continuous efforts to develop a lightweight alloy suitable for the most demanding applications in automotive industry resulted in a number of advanced aluminum (Al) and magnesium alloys and manufacturing routes. One example of this is the application of 319 Al alloy for production of 3.6L V6 gasoline engine blocks. Aluminum is sand cast around Fe-liner cylinder inserts, prior to undergoing the T7 heat treatment process. One of the critical factors determining the quality of the final product is the type, level, and profile of residual stresses along the Fe liners (or extent of liner distortion) that are always present in a cast component. In this study, neutron diffraction was used to characterize residual stresses along the Al and the Fe liners in the web region of the cast engine block. The strains were measured both in Al and Fe in hoop, radial, and axial orientations. The stresses were subsequently determined using generalized Hooke's law.

Aluminum alloys have been replacing ferrous alloys in automotive applications to reduce the weight of vehicles. The engine block is a striking example of weight reduction, and is made of Al-Si-Cu-Mg (319 type) alloys. The wear resistance in the engine block is enabled by cast iron liners, and these liners introduce tensile residual stress due to a thermo-mechanical mismatch. Typically, an artificial aging treatment effectively reduces residual stress. In this study, neutron diffraction was used to measure the residual stress profiles along the cylinder bridge of a T5 treated 319 aluminum alloy engine block. Results indicated high tensile residual stresses (200-300 MPa) in the hoop and axial orientation at depths of 50-60 mm below the head deck. The high residual stresses were likely due to a combination of minimal stress relief during artificial aging and stress development during post process cooling.

The development of new catalytic materials is still dominated by trial and error methods, even though the experimental and theoretical bases for their characterization have improved dramatically in recent years. Although it has been successful, the empirical development of catalytic materials is time consuming and expensive with no guarantee of success. We have been exploring computationally complex but experimentally simple systems to establish a “catalysis by design” protocol that combines the power of theory and experiment. We hope to translate the fundamental insights directly into a complete catalyst system that is technologically relevant. The essential component of this approach is that the catalysts are iteratively examined by both theoretical and experimental methods.

In September 1993, the Partnership for a New Generation of Vehicles (PNGV) program, initiated a cooperative research and development (R&D) program between the federal government and the United States Council Automotive Research (USCAR) to develop automotive technologies to reduce the nation's dependence on petroleum and reduce emissions of greenhouse gases by improving fuel economy. A key enabler for the attainment of these goals is a significant reduction in vehicle weight. Thus the major focus of the PNGV materials program is the development of materials and technologies that would result in the reduction of vehicle weight by up to 40%. The Automotive Lightweighting Materials (ALM) Program in the Office of Advanced Automotive Technologies (OAAT) of the Department of Energy (DOE), the PNGV Materials Technical Team and the United States Automotive Materials Partnership (USAMP) collaborate to conduct research and development on these materials.

Development of reliable magnesium (Mg) to steel joining methods is one of the critical issues in boarder applications of Mg in automotive body construction. However, due to the large difference of melting temperatures of Mg and steel, fusion welding between two metals is very challenging. Ultrasonic spot welding (USW) has been demonstrated to join Mg to steel without melting and to achieve strong joints. However, galvanic corrosion between Mg and steel is inevitable but not well quantified. In this study, corrosion test of ultrasonic spot welds between 1.6-mm-thick Mg AZ31B-H24 and 0.8-mm-thick galvanized mild steel was conducted. No specific corrosion protection was applied in order to study the worst corrosion behavior. Corrosion test was conducted with an automotive cyclic corrosion test, which includes cyclic exposures of dipping in the salt bath, air drying, then a constant humidity environment. Lap shear strength of the joints decreased linearly with the cycles.

Development of reliable magnesium (Mg) to steel joining methods is one of the critical issues in broader applications of Mg in automotive body construction. Ultrasonic spot welding (USW) has been demonstrated successfully to join Mg to steel and to achieve strong joints. In this study, corrosion test of ultrasonic spot welds between 1.6 mm thick Mg AZ31B-H24 and 0.8 mm thick galvanized mild steel, without and with adhesive, was conducted. Adhesive used was a one-component, heat-cured epoxy material, and was applied between overlapped sheets before USW. Corrosion test was conducted with an automotive cyclic corrosion test, which includes cyclic exposures of dipping in the 0.5% sodium chloride (NaCl) bath, a constant humidity environment, and a drying period. Lap shear strength of the joints decreased with the cycles of corrosion exposure. Good joint strengths were retained at the end of 30-cycle test.

Static and dynamic strength tests were performed on spot welded specimens made of dual-phase (DP) 780 and mild steels (DQSK). Lap-shear (LS) and cross-tension (CT) as well as a new mixed mode specimen were studied using MTS hydraulic universal testing machine for static tests and drop weight tower for dynamic tests. Three weld nugget sizes were made for each steel and CT and LS. DP780 with one weld size was also tested in mixed mode. Load and displacement as functions of time and fracture mode of the spot welds were recorded. Representative data are reported in this paper.

The uniaxial compression test was used to assess the influence of strain amount on the behavior of precipitates and texture of the Al-7%Si-1%Cu-0.5%Mg alloy, modified with micro-additions of V, Zr and Ti. As revealed through metallographic examinations, fracturing and re-orientation of the second-phase particles increased with increasing compression strain. However, the intermetallic particles experienced substantially more frequent cracking than the eutectic silicon. The crystallographic texture was measured and correlated with deformation behavior of the alloy. The weak texture of 11<211> and 111<110> components, detected after casting transformed to a mixture of 1<110>, 112<110> and 111<110> components after room-temperature compression deformation. The intensity of the texture components depended on the strain amount. It is concluded that the texture formation in the studied alloy is controlled by the precipitates formed during solidification of the alloy.

This project investigated the effect of carburizing carbon-potential and thermal history on the bending fatigue performance of carburized SAE 4320 gear steel. Modified-Brugger cantilever bending fatigue specimens were carburized at carbon potentials of 0.60, 0.85, 1.05, and 1.25 wt. pct. carbon, and were either quenched and tempered or quenched, tempered, reheated, quenched, and tempered. The reheat treatment was designed to lower the solute carbon content in the case through the formation of transition carbides and refine the prior austenite grain size. Specimens were fatigue tested in a tension/tension cycle with a minimum to maximum stress ratio of 0.1. The bending fatigue results were correlated with case and core microstructures, hardness profiles, residual stress profiles, retained austenite profiles, and component distortion.

Surfaces of A356 castings were treated by friction stir processing to reduce porosity and to create more uniform distributions of second-phase particles. Dendritic microstructures were eliminated in stir zones. The ultimate tensile strength, ductility, and fatigue life of the cast A356 was increased by friction stir processing. Tensile specimens of cast and friction stir processed metal were also given a T7 heat treatment. Higher tensile strengths and ductilities were also measured for these friction stir processed specimens.

Reported tensile and fatigue properties of die cast AZ91D and AM60B magnesium alloys indicate that those values depend on the size and shape of the test samples and their global porosities. This paper reviews the mechanical properties reported in the open literature for these die cast alloys and indicates that section thickness and global porosity are inadequate for predicting the tensile and fatigue properties of die cast AZ91D and AM60B magnesium alloys.