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Laboratory and vehicle tests were carried out to investigate behaviour and potentiality of NOx-trap catalytic system in Diesel conditions. Three main aspects were studied. The first one deals with the NOx storage capacity of adsorber under laboratory and vehicle conditions, especially regarding the influence of driving conditions. The second one focuses on the regenerability of different materials. At length, special attention is devoted to the sulphur poisoning rate. A representative laboratory test method was built up, to evaluate NOx storage capacity under Diesel conditions. It is shown that NOx adsorption occurs from 100 to 400°C. Low temperature activity (100 to 250°C) is conditioned by low NOx flow emission, mainly due to the use of high EGR rate. Higher temperatures lead to an increase in the intrinsic NOx Storage capacity of the material, but are also accompanied by high NOx concentration and space velocity.