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In a recent study, quantitative measurements were presented of in-cylinder spatial distributions of mixture equivalence ratio in a single-cylinder light-duty optical diesel engine, operated with a non-reactive mixture at conditions similar to an early injection low-temperature combustion mode. In the experiments a planar laser-induced fluorescence (PLIF) methodology was used to obtain local mixture equivalence ratio values based on a diesel fuel surrogate (75% n-heptane, 25% iso-octane), with a small fraction of toluene as fluorescing tracer (0.5% by mass). Significant changes in the mixture's structure and composition at the walls were observed due to increased charge motion at high swirl and injection pressure levels. This suggested a non-negligible impact on wall heat transfer and, ultimately, on efficiency and engine-out emissions.

A free piston, internal combustion (IC) engine, operating at high compression ratio (∼30:1) and low equivalence ratio (ϕ∼0.35), and utilizing homogeneous charge compression ignition combustion, has been proposed by Sandia National Laboratories as a means of significantly improving the IC engine's cycle thermal efficiency and exhaust emissions. A zero-dimensional, thermodynamic model with detailed chemical kinetics, and empirical scavenging, heat transfer, and friction component models has been used to analyze the steady-state operating characteristics of this engine. The cycle simulations using hydrogen as the fuel, have indicated the critical factors affecting the engine's performance, and suggest the limits of improvement possible relative to conventional IC engine technologies.

Chemiluminescence imaging has been applied to investigate the naturally occurring charge stratification in an HCCI engine. This stratification slows the pressure-rise rate (PRR) during combustion, making it critical to the high-load operating limit of these engines. Experiments were conducted in a single-cylinder HCCI engine modified with windows in the combustion chamber for optical access. Using this engine, chemiluminescence images were obtained from three different view angles. These included both single-shot images with intensified CCD cameras and high-speed (20kHz) sequences with an intensified CMOS video camera. The engine was fueled with iso-octane, which has been shown to be a reasonable surrogate for gasoline and exhibits only single-stage ignition at these naturally aspirated conditions. The chemiluminescence images show that the HCCI combustion is not homogeneous but has a strong turbulent structure even when the fuel and air are fully premixed prior to intake.

Combustion phasing is one important issue that must be addressed for HCCI operation. The intake temperature can be adjusted to achieve ignition at the desired crank angle. However, heat-transfer during induction will make the effective intake temperature different from the temperature measured in the runner. Also, depending on the engine speed and port configuration, dynamic flow effects cause various degrees of charge heating. Additionally, residuals from the previous cycle can have significant influence on the charge temperature at the beginning of the compression stroke. Finally, direct injection of fuel will influence the charge temperature since heat is needed for vaporization. This study investigates these effects in a systematic manner with a combination of experiment and cycle simulation using WAVE from Ricardo.

A central challenge for efficient auto-ignition controlled low-temperature gasoline combustion (LTGC) engines has been achieving the combustion phasing needed to reach stable performance over a wide operating regime. The negative valve overlap (NVO) strategy has been explored as a way to improve combustion stability through a combination of charge heating and altered reactivity via a recompression stroke with a pilot fuel injection. The study objective was to analyze the thermal and chemical effects on NVO-period energy recovery. The analysis leveraged experimental gas sampling results obtained from a single-cylinder LTGC engine along with cylinder pressure measurements and custom data reduction methods used to estimate period thermodynamic properties. The engine was fueled by either iso-octane or ethanol, and operated under sweeps of NVO-period oxygen concentration, injection timing, and fueling rate.

This paper studies autoignition characteristics and HCCI engine combustion of ketone fuels, which are important constituents of recently discovered fungi-derived biofuels. Two ketone compounds, 2,4-dimethyl-3-pentanone (DMPN) and cyclopentanone (CPN), are systematically investigated in the Sandia HCCI engine, and the results are compared with conventional gasoline and neat ethanol. It is found that CPN has the lowest autoignition reactivity of all the biofuels and gasoline blends tested in this HCCI engine. The combustion timing of CPN is also the most sensitive to intake-temperature (Tin) variations, and it is almost insensitive to intake-pressure (Pin) variations. These characteristics and the overall HCCI performance of CPN are similar to those of ethanol. In contrast, DMPN shows multi-faceted autoignition characteristics. On the one hand, DMPN has strong temperature-sensitivity, even at boosted Pin, which is similar to the low-reactivity ethanol and CPN.

Previous work has shown that conventional diesel ignition improvers, 2-ethylhexyl nitrate (EHN) and di-tert-butyl peroxide (DTBP), can be used to enhance the autoignition of a regular-grade E10 gasoline in a well premixed low-temperature gasoline combustion (LTGC) engine, hereafter termed an HCCI engine, at naturally aspirated and moderately boosted conditions (up to 180 kPa absolute) with a constant engine speed of 1200 rpm and a 14:1 compression ratio. In the current work the effect of EHN on boosted HCCI combustion is further investigated with a higher compression ratio (16:1) piston and over a range of engine speeds (up to 2400 rpm). The results show that the higher compression ratio and engine speeds can make the combustion of a regular-grade E10 gasoline somewhat less stable. The addition of EHN improves the combustion stability by allowing combustion phasing to be more advanced for the same ringing intensity.

Long chain alcohols possess major advantages over the currently used ethanol as bio-components for gasoline, including higher energy content, better engine compatibility, and less water solubility. The rapid developments in biofuel technology have made it possible to produce C 4 -C 5 alcohols cost effectively. These higher alcohols could significantly expand the biofuel content and potentially substitute ethanol in future gasoline mixtures. This study characterizes some fundamental properties of a C 5 alcohol, isopentanol, as a fuel for HCCI engines. Wide ranges of engine speed, intake temperature, intake pressure, and equivalence ratio are investigated. Results are presented in comparison with gasoline or ethanol data previously reported. For a given combustion phasing, isopentanol requires lower intake temperatures than gasoline or ethanol at all tested speeds, indicating a higher HCCI reactivity.

Well-mixed lean or dilute SI engine operation can provide efficiency improvements relative to that of traditional well-mixed stoichiometric SI operation. However, the realized gains depend on the ability to ensure stable, complete and fast combustion. In this work, the influence of fuel type is examined for gasoline, E30 and E85. Several enabling techniques are compared. For enhanced ignition stability, a multi-pulse (MP) transient plasma ignition system is compared to a conventional high-energy inductive spark ignition system. Combined effects of fuel type and intake-gas preheating are examined. Also, the effects of dilution type (air or N2-simulated EGR) on lean efficiency gains and stability limits are clarified. The largest efficiency improvement is found for lean gasoline operation using intake preheating, showing the equivalent of a 20% fuel-economy gain relative to traditional non-dilute stoichiometric operation.

Well-mixed lean SI engine operation can provide improvements of the fuel economy relative to that of traditional well-mixed stoichiometric SI operation. This work examines the use of two methods for improving the stability of lean operation, namely multi-pulse transient plasma ignition and intake air preheating. These two methods are compared to standard SI operation using a conventional high-energy inductive ignition system without intake air preheating. E85 is the fuel chosen for this study. The multi-pulse transient plasma ignition system utilizes custom electronics to generate 10 kHz bursts of 10 ultra-short (12ns), high-amplitude pulses (200 A). These pulses were applied to a custom spark plug with a semi-open ignition cavity. High-speed imaging reveals that ignition in this cavity generates a turbulent jet-like early flame spread that speeds up the transition from ignition to the main combustion event.

Low-temperature gasoline combustion (LTGC) engines can provide high efficiencies and extremely low NOx and particulate emissions, but controlling the combustion timing remains a challenge. This paper explores the potential of Partial Fuel Stratification (PFS) to provide fast control of CA50 in an LTGC engine. Two different compression ratios are used (CR=16:1 and 14:1) that provide high efficiencies and are compatible with mixed-mode SI-LTGC engines. The fuel used is a research grade E10 gasoline (RON 92, MON 85) representative of a regular-grade market gasoline found in the United States. The fuel was supplied with a gasoline-type direct injector (GDI) mounted centrally in the cylinder. To create the PFS, the GDI injector was pulsed twice each engine cycle. First, an injection early in the intake stroke delivered the majority of the fuel (70 - 80%), establishing the minimum equivalence ratio in the charge.

This paper1 explores some of the important considerations in devising a practical and consistent framework and methodology for working with experiments and experimental data in connection with modeling and prediction. The paper outlines a pragmatic and versatile “real-space” approach within which experimental and modeling uncertainties (correlated and uncorrelated, systematic and random, aleatory and epistemic) are treated to mitigate risk in modeling and prediction. The elements of data conditioning, model conditioning, model validation, hierarchical modeling, and extrapolative prediction under uncertainty are examined. An appreciation can be gained for the constraints and difficulties at play in devising a viable end-to-end methodology. The considerations and options are many, and a large variety of viewpoints and precedents exist in the literature, as surveyed here. Rationale is given for the various choices taken in assembling the novel real-space end-to-end framework.

Isopentanol is an advanced biofuel that can be produced by micro-organisms through genetically engineered metabolic pathways. Compared to the more frequently studied ethanol, isopentanol's molecular structure has a longer carbon chain and includes a methyl branch. Its volumetric energy density is over 30% higher than ethanol, and it is less hygroscopic. Some fundamental combustion properties of isopentanol in an HCCI engine have been characterized in a recent study by Yang and Dec (SAE 2010-01-2164). They found that for typical HCCI operating conditions, isopentanol lacks two-stage ignition properties, yet it has a higher HCCI reactivity than gasoline. The amount of intermediate temperature heat release (ITHR) is an important fuel property, and having sufficient ITHR is critical for HCCI operation without knock at high loads using intake-pressure boosting. Isopentanol shows considerable ITHR, and the amount of ITHR increases with boost, similar to gasoline.

Autoignition enhancing additives have been used for years to enhance the ignition quality of diesel fuel, with 2-ethylhexyl nitrate (EHN) being the most common additive. EHN also enhances the autoignition reactivity of gasoline, which has advantages for some low-temperature combustion techniques, such as Sandia’s Low-Temperature Gasoline Combustion (LTGC) with Additive-Mixing Fuel Injection (AMFI). LTGC-AMFI is a new high-efficiency and low-emissions engine combustion process based on supplying a small, variable amount of EHN into the fuel for better engine operation and control. However, the mechanism by which EHN interacts with the fuel remains unclear. In this work, a chemical-kinetic mechanism for EHN was developed and implemented in a detailed mechanism for gasoline fuels. The combined mechanism was validated against shock-tube experiments with EHN-doped n-heptane and HCCI engine data for EHN-doped regular E10 gasoline. Simulations showed a very good match with experiments.

With the introduction of more fuel cell electric vehicles (FCEVs) on U.S. roadways, especially in California, the need for available hydrogen refueling stations is growing. While funding from the California Energy Commission is helping to solve this problem, solutions need to be developed and implemented to help reduce the time to commission a hydrogen station. The current practice of hydrogen station acceptance can take months because each vehicle manufacturer conducts their own testing and evaluation. This process is not practical or sufficient to support the timely development of a hydrogen fueling station network. To address this issue, as part of the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) Project Sandia National Laboratories and the National Renewable Energy Laboratory along with a team of stakeholders and contractor Powertech Labs has developed the Hydrogen Station Equipment Performance (HyStEP) Device.

We have designed and tested a prototype dish/Stirling hybrid-receiver combustion system. The system consists of a pre-mixed natural-gas burner heating a pin-finned sodium heat pipe. The design emphasizes simplicity, low cost, and ruggedness. Our test was on a 1/6th-scale device, with a nominal firing rate of 18kWt, a power throughput of 13kWt, and a sodium vapor temperature of 750°C. The air/fuel mixture was electrically preheated to 640°C to simulate recuperation. The test rig was instrumented for temperatures, pressures, flow rates, overall leak rate, and exhaust emissions. The data verify our burner and heat-transfer models. Performance and post-test examinations validate our choice of materials and fabrication methods. Based on the 1/6th -scale results, we are designing a full-scale hybrid receiver.

Surrogate fuels that reproduce the characteristics of full-boiling range fuels are key tools to enable numerical simulations of fuel-related processes and ensure reproducibility of experiments by eliminating batch-to-batch variability. Within the PACE initiative, a surrogate fuel for regular-grade E10 (10%vol ethanol) gasoline representative of a U.S. market gasoline, termed PACE-20, was developed and adopted as baseline fuel for the consortium. Although extensive testing demonstrated that PACE-20 replicates the properties and combustion behavior of the full-boiling range gasoline, several concerns arose regarding the purity level required for the species that compose PACE-20. This is particularly important for cyclo-pentane, since commercial-grade cyclo-pentane typically shows 60%–85% purity. In the present work, the effects of the purity level of cyclo-pentane on the properties and combustion characteristics of PACE-20 were studied.

Ethanol blending is one method that can be used to reduce knock in spark ignition engines by decreasing the autoignition reactivity of the fuel and modifying its laminar flame speed. In this paper, the effects of ethanol blending on knock propensity and flame speed of petroleum and low-carbon gasoline fuels is analyzed. To do so, surrogate fuels were formulated for methanol-to-gasoline (MTG) and ethanol-to-gasoline (ETG) based on the fuels’ composition, octane number, and select physical properties; and 0-D and 1-D chemical kinetics simulations were performed to investigate reactivity and laminar flame speed, respectively. Results of MTG and ETG were compared against those of PACE-20, a well-characterized surrogate for regular E10 gasoline. Similarly to PACE-20, blending MTG and ETG with ethanol increases the fuel’s research octane number (RON) and sensitivity.

Low-temperature gasoline combustion (LTGC), based on the compression ignition of a premixed or partially premixed dilute charge, can provide thermal efficiencies (TE) and maximum loads comparable to those of turbo-charged diesel engines, and ultra-low NOx and particulate emissions. Intake boosting is key to achieving high loads with dilute combustion, and it also enhances the fuel's autoignition reactivity, reducing the required intake heating or hot residuals. These effects have the advantages of increasing TE and charge density, allowing greater timing retard with good stability, and making the fuel ϕ- sensitive so that partial fuel stratification (PFS) can be applied for higher loads and further TE improvements. However, at high boost the autoignition reactivity enhancement can become excessive, and substantial amounts of EGR are required to prevent overly advanced combustion.

Unlike other gases, hydrogen can promote embrittlement of structural metals at ambient temperature. The effects of high-pressure hydrogen gas on structural metals vary significantly depending on material, environmental, and mechanical variables as well as the metric used to evaluate performance. In this short review, we provide basic guidance on selection of materials for hydrogen gas service emphasizing the need for performing tests in relevant environments and using appropriate methods. Fracture mechanics and fitness-for-service type design approaches are highly recommended for ensuring robust yet efficient high-pressure designs for hydrogen gas service.