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In this work, the effects of ozone, hydrogen, carbon monoxide, and exhaust gas recirculation (EGR) addition to Haltermann gasoline combustion were investigated. For these additives, laminar and turbulent flame speeds were experimentally determined using spherically propagating premixed flames in a constant volume combustion vessel. Two initial mixture pressures of Po = 1 and 5 bar, two initial mixture temperatures of 358 and 373 K and a range of equivalence ratios (Ф) from 0.5 to 1 were investigated. The additives were added as single, binary and ternary mixtures to Haltermann gasoline over a wide range of concentrations. For the stoichiometric mixture, the addition of 10% H2, 5% CO and 1000 ppm O3 shows remarkable enhancement (80%) in SL0compared to neat Haltermann gasoline. In addition, for this same blend, increasing the mixture initial temperature and pressure results in a significant increase in SL0compared to the neat gasoline.

The regulatory requirements to reduce both greenhouse gases and exhaust gas pollutants from heavy duty engines are driving new perspectives on the interaction between fuels and engines. Fuels that reliefs the burden on engine manufacturers to reach these goals are of particular interest. A low carbon fuel with a higher volatility and heating value than diesel is one such fuel that reduces engine-out emissions and carbon footprint from the entire hydrocarbon lifecycle (well-to-wheel) and improves fuel efficiency, which is a main enabler for gasoline compression ignition (GCI) technology. The present study investigated the potential of GCI technology by evaluating the performance of a low carbon high efficiency, high reactivity gasoline fuel in Doosan’s 6L medium duty diesel engine.

Due to stringent emission standards, the demand for higher efficiency engines has been unprecedentedly high in recent years. Among several existing combustion modes, pre-chamber spark ignition (PCSI) emerges to be a potential candidate for high-efficiency engines. Research on the pre-chamber concept exhibit higher indicated efficiency through lean limit extension while maintaining the combustion stability. In this study, a unique pre-chamber geometry was tested in a single-cylinder heavy-duty engine at low load lean conditions. The geometry features a narrow throat, which was designed to be packaged inside a commercial diesel injector pocket. The pre-chamber was fueled with methane while the main chamber was supplied with an ethanol/air mixture.

As SI engines strive for higher efficiency they are more likely to encounter knock and fuel anti-knock quality, which is currently measured by RON and MON, becomes more important. However, the RON and MON scales are based on primary reference fuels (PRF) - mixtures of iso-octane and n-heptane - whose autoignition chemistry is significantly different from that of practical fuels. Hence RON or MON alone can truly characterize a gasoline for its knock behavior only at their respective test conditions. The same gasoline will match different PRF fuels at different operating conditions. The true anti-knock quality of a fuel is given by the octane index, OI = RON −KS where S = RON − MON, is the sensitivity. K depends on the pressure and temperature evolution in the unburned gas during the engine cycle and hence is different at different operating conditions and is negative in modern engines.

In this study, the authors investigated the effect of fuel properties on the combustion characteristics by employing methane, methanol, ethanol, and primary reference fuels (PRFs) as the main chamber fuel while using methane for the pre-chamber. Global excess air ratios (λ) from 1.6 to lean limit were tested, while 13% of total fuel energy supplied to the engine was delivered via the pre-chamber. The gaseous methane was injected into the pre-chamber at the gas exchange top-dead-center (TDC). Port fuel injection was tested with both open and closed inlet valves. The pre-chamber assembly was designed to fit into the diesel injector pocket of the base engine, which resulted in a narrow throat diameter of 3.3 mm. The combustion stability limit was set at 5% of the coefficient of variation of gross IMEP, and the knock intensity limit was set at 10 bar. GT-Power software was used to estimate the composition of pre-chamber species and was used in heat release analysis of the two chambers.

Gasoline-ethanol-methanol (GEM) blends, with constant stoichiometric air-to-fuel ratio (iso-stoichiometric blending rule) and equivalent to binary gasoline-ethanol blends (E2, E5, E10 and E15 in % vol.), were defined to investigate the effect of methanol and combined mixtures of ethanol and methanol when blended with three FACE (Fuels for Advanced Combustion Engines) Gasolines, I, J and A corresponding to RON 70.2, 73.8 and 83.9, respectively, and their corresponding Primary Reference Fuels (PRFs). A Cooperative Fuel Research (CFR) engine was used under Spark Ignition and Homogeneous Charge Compression Ignited modes. An ignition quality tester was utilized in the Compression Ignition mode. One of the promising properties of GEM blends, which are derived using the iso-stoichiometric blending rule, is that they maintain a constant octane number, which has led to the introduction of methanol as a drop-in fuel to supplement bio-derived ethanol.

The effect of ethanol blended with three FACE (Fuels for Advanced Combustion Engines) gasolines, I, J and A corresponding to RON 70.3, 71.8 and 83.5, respectively, were compared to PRF70 and PRF84 with the same ethanol concentrations, these being 2%, 5%, 10%, 15% and 20% by volume. A Cooperative Fuel Research (CFR) engine was used to understand the blending effect of ethanol with FACE gasolines and PRFs in spark-ignited and homogeneous charge compression ignited mode. Blending octane numbers (BON) were obtained for both the modes. All the fuels were also tested in an ignition quality tester to obtain Blending Derived Cetane numbers (BDCN). It is shown that fuel composition and octane number are important characteristics of all the base fuels that have a significant impact on octane increase with ethanol. The dependency of octane number for the base fuel on the blending octane number depended on the combustion mode operated.

The blending behavior of ethanol in five different hydrocarbon base fuels with octane numbers of approximately 70 and 84 was examined under Spark-Ignited (SI) and Homogeneous Charge Compression Ignited (HCCI) operating conditions. The Blending octane number (BON) was used to characterize the blending behavior on both a volume and molar basis. Previous studies have shown that the blending behavior of ethanol generally follows several well-established rules. In particular, non-linear blending effects are generally observed on a volume basis (i.e. BON > RON or MON of pure ethanol; 108 and 89, respectively), while linear blending effects are generally observed on a molar basis (i.e. BON = RON or MON of pure ethanol). This work firstly demonstrates that the non-linear volumetric blending effects traditionally observed under SI operating conditions are also observed under HCCI operating conditions.

Blending gasoline with oxygenates like ethanol, MTBE or ETBE has a proven potential to increase the thermodynamic efficiency by enhancing knock resistance. The present research focuses on assessing the capability of a 2- and tert-butanol mixture as a possible alternative to state-of-the-art oxygenates. The butanol mixture was blended into a non-oxygenated reference gasoline with a research octane number (RON) of 97. The butanol blending ratios were 15% and 30% by mass. Both the thermodynamic potential and the impact on emissions were investigated. Tests are performed on a highly boosted single-cylinder gasoline engine with high load capability and a direct injecting fuel system using a solenoid-actuated multi-hole injector. The engine is equipped with both intake and exhaust cam phasers. The engine has been chosen for the fuel investigation, as it represents the SI technology with a strongly increasing market share.

Low temperature combustion concepts are studied recently to simultaneously reduce NOX and soot emissions. Optical studies are performed to study gasoline PPC in CI engines to investigate in-cylinder combustion and stratification. It is imperative to perform emission measurements and interpret the results with combustion images. In this work, we attempt to investigate this during the transition from CI to HCCI mode for FACE I gasoline (RON = 70) and its surrogate, PRF70. The experiments are performed in a single cylinder optical engine that runs at a speed of 1200 rpm. Considering the safety of engine, testing was done at lower IMEP (3 bar) and combustion is visualized using a high-speed camera through a window in the bottom of the bowl. From the engine experiments, it is clear that intake air temperature requirement is different at various combustion modes to maintain the same combustion phasing.

Recent work has demonstrated the potential of gasoline-like fuels to reduce NOx and particulate emissions when used in compression ignition engines. In this context, low research octane number (RON) gasoline, a refinery stream derived from the atmospheric crude oil distillation process, has been identified as a highly valuable fuel. In addition, thanks to its higher H/C ratio and energy content compared to diesel, CO2 benefits are also expected when used in such engines. In previous studies, different cetane number (CN) fuels have been evaluated and a CN 35 fuel has been selected. The assessment and the choice of the required engine hardware adapted to this fuel, such as the compression ratio, bowl pattern and nozzle design have been performed on a single cylinder compression-ignition engine.

In this paper blends of diesel and gasoline (dieseline) fuelled Partially Premixed Compression Ignition (PPCI) combustion and the comparison to conventional diesel combustion is investigated. The tests are carried out using a light duty four cylinder Euro IV diesel engine. The engine condition is maintained at 1800 rpm, 52 Nm (equivalent IMEP around 4.3 bar). Different injection timings and different amounts of EGR are used to achieve the PPCI combustion. The results show that compared to the conventional diesel combustion, the smoke and NOx emissions can be reduced by more than 95% simultaneously with dieseline fuelled PPCI combustion. The particle number total concentration can be reduced by 90% as well as the mean diameter (from 54 nm for conventional diesel to 16 nm for G50 fuelled PPCI). The penalty is a slightly increased noise level and lower indicated efficiency, which is decreased from 40% to 38.5%.

Typical automotive emission testing systems usually employ Flame Ionization Detection (FID) analyzers to measure unburned fuel species in the exhaust, but the technique is not suitable for engines operating on alcohol fuels. The FID method is not sensitive to measuring unburned alcohol fuels due to the presence of oxygen bonds in the fuel molecule. Other techniques, such as Fourier Transform Infrared (FTIR), can provide accurate unburned fuel measurements with alcohol fuel. However, these techniques are expensive and are less accessible compared to FID analyzers. In this study, the unburned fuel emissions from the engine exhaust were measured simultaneously with FID and FTIR analyzers, with the engine operating on pure alcohols, which are methanol, ethanol, and n-butanol. While most previous work focuses on stoichiometric air-fuel mixtures, a wide range of lean operating conditions between global-λ 1.6 to 2.8 will be tested in this study.

Light naphtha is the light distillate from crude oil and can be used in compression ignition (CI) engines; its low boiling point and octane rating (RON = 64.5) enable adequate premixing. This study investigates the combustion characteristics of light naphtha (LN) and its multicomponent surrogate under various start of injection (SOI) conditions. LN and a five-component surrogate for LN, comprised of 43% n-pentane, 12% n-heptane, 10% 2-methylhexane, 25% iso-pentane and 10% cyclo-pentane, has been tested in a single cylinder optical diesel engine. The transition in combustion homogeneity from CI combustion to homogenized charge compression ignition (HCCI) combustion was then compared between LN and its surrogate. The engine experimental results showed good agreement in combustion phasing, ignition delay, start of combustion, in-cylinder pressure and rate of heat release between LN and its surrogate.

In the context of stringent future emission standards as well as the need to reduce emissions of CO2 on a global scale, the cost of manufacturing engines is increasing. Naphtha has been shown to have beneficial properties for its use as a fuel in the transportation sector. Well to tank CO2 emissions from the production of Naphtha are lower than any other fuel produced in the refinery due to its lower processing requisites. Moreover, under current technology trends the demand for diesel is expected to increase leading to a possible surplus of light fuels in the future. Recent research has demonstrated that significant fuel consumption reduction is possible based on a direct injection gasoline engine system, when a low quality gasoline stream such as Naphtha is used in compression ignition mode. With this fuel, the engine will be at least as efficient and clean as current diesel engines but will be more cost effective (lower injection pressure, HC/CO after-treatment rather than NOx).

The high-pressure isobaric combustion has been proposed as the most suitable combustion mode for the double compre4ssion expansion engine (DCEE) concept. Previous experimental and simulation studies have demonstrated an improved efficiency compared to the conventional diesel combustion (CDC) engine. In the current study, isobaric combustion was achieved using a single injector with multiple injections. Since this concept involves complex phenomena such as spray to spray interactions, the computational models were extensively validated against the optical engine experiment data, to ensure high-fidelity simulations. The considered optical diagnostic techniques are Mie-scattering, fuel tracer planar laser-induced fluorescence (PLIF), and natural flame luminosity imaging. Overall, a good agreement between the numerical and experimental results was obtained.

Results from a large set of HCCI experiments performed on a single-cylinder research engine fueled with different mixtures of iso-octane and n-heptane are presented and discussed in this paper. The experiments are designed to scrutinize fuel reactivity effects on the operating range of an HCCI engine. The fuel effects on upper and lower operating limits are measured respectively by the maximum pressure rise rate inside the cylinder and the stability of engine operation as determined by cycle-to-cycle variations in IMEP. Another set of experiments that examine the intake air heating effects on HCCI engine performance, exhaust emissions and operating envelopes is also presented. The effects of fuel reactivity and intake air heating on the HCCI ranges are demonstrated by constructing the operating envelopes for the different test fuels and intake temperatures.

The objective of this study was to investigate the effect of aromatic on combustion stratification and particulate emissions for PRF60. Experiments were performed in an optical CI engine at a speed of 1200 rpm for TPRF0 (100% v/v PRF60), TPRF20 (20% v/v toluene + 80% PRF60) and TPRF40 (40% v/v toluene + 60% PRF60). TPRF mixtures were prepared in such a way that the RON of all test blends was same (RON = 60). Single injection strategy with a fuel injection pressure of 800 bar was adopted for all test fuels. Start of injection (SOI) was changed from early to late fuel injection timings, representing various modes of combustion viz HCCI, PPC and CDC. High-speed video of the in-cylinder combustion process was captured and one-dimensional stratification analysis was performed from the intensity of images. Particle size, distribution and concentration were measured and linked with the in-cylinder combustion images.

Pre-chamber spark ignition (PCSI) combustion is an emerging lean-burn combustion mode capable of extending the lean operation limit of an engine. The favorable characteristic of short combustion duration at the lean condition of PCSI results in high efficiencies compared to conventional spark ignition combustion. Since the engine operation is typically lean, PCSI can significantly reduce engine-out NOx emissions while maintaining short combustion durations. In this study, experiments were conducted on a heavy-duty engine at lean conditions at mid to low load. Two major studies were performed. In the first study, the total fuel energy input to the engine was fixed while the intake pressure was varied, resulting in varying the global excess air ratio. In the second study, the intake pressure was fixed while the amount of fuel was changed to alter the global excess air ratio.

Gasoline compression ignition (GCI) engines have been considered an attractive alternative to traditional spark ignition engines. Low octane gasoline fuel has been identified as a viable option for the GCI engine applications due to its longer ignition delay characteristics compared to diesel and in the volatility range of gasoline fuels. In this study, we have investigated the effect of different injection timings at part-load conditions using light naphtha stream in single cylinder engine experiments in the GCI combustion mode with injection pressure of 130 bar. A toluene primary reference fuel (TPRF) was used as a surrogate for the light naphtha in the engine simulations performed here. A physical surrogate based on the evaporation characteristics of the light naphtha has been developed and its properties have been implemented in the engine simulations.