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Carbonaceous deposits can accumulate on various surfaces of the internal combustion engine and affect its performance. The porous nature of these deposits means that they act like a “sponge”, adsorbing fuel components and changing both the composition and the amount of fuel in the combustion chamber. Here we use a previously developed and validated model of engine deposits to predict adsorption of normal heptane, isooctane, toluene and their mixtures in deposits of different origin within a port fuel injected spark ignition engine (Combustion Chamber Deposits, or CCDs, and Intake Valve Deposits, or IVDs) and under different conditions. We explore the influence of molecular structure of adsorbing species, composition of the bulk mixture and temperature on the uptake and selectivity behaviour of the deposits. While deposits generally show high capacity toward all three components, we observe that selectivity behaviour is a more subtle and complex property.

Due to the recent drive to reduce CO₂ emissions, the turbocharged direct injection spark ignition (turbo DISI) gasoline engine has become increasingly popular. In addition, future turbo DISI engines could incorporate a form of charge dilution (e.g., lean operation or external EGR) to further increase fuel efficiency. Thus, the conditions experienced by the fuel before and during combustion are and will continue to be different from those experienced in naturally aspirated SI engines. This work investigates the effects of fuel properties on a modern and prototype turbo DISI engine, with particular focus on the octane appetite: How relevant are RON and MON in predicting a fuel's anti-knock performance in these modern/future engines? It is found that fuels with high RON and low MON values perform the best, suggesting the current MON requirements in fuel specifications could actually be detrimental.