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A 2001 General Motors 4.3 liter V-6 marine engine was baseline emissions tested and then equipped with catalysts. Emission reduction effects of exhaust gas recirculation (EGR) were also explored. Because of a U.S. Coast Guard requirement that inboard engine surface temperatures be kept below 200°F, the engine's exhaust system, including the catalysts, was water-cooled. Engine emissions were measured using the ISO-8178-E4 5-mode steady-state test for recreational marine engines. In baseline configuration, the engine produced 16.6 g HC+NOx/kW-hr, and 111 g CO/kW-hr. In closed-loop control with catalysts, HC+NOx emissions were reduced by 75 percent to 4.1 g/kW-hr, and CO emissions were reduced by 36 percent to 70 g/kW-hr of CO. The catalyzed engine was then installed in a Sea Ray 190 boat, and tested for water reversion on both fresh and salt water using National Marine Manufacturers Association procedures.

The emission and flow restriction characteristics of three different ceramic substrates with varying wall thickness and cell density (400 cpsi/6.5 mil, 600/4.3, and 600/3.5) are compared. These 106mm diameter substrates were catalyzed with similar amounts of washcoat and fabricated into catalytic converters having a total volume of 2.0 liters. A Pd/Rh catalyst technology was applied at a concentration of 6.65 g/l and a ratio of 20/1. Three sets of converters (two of each type) were aged for 100 hours on an engine dynamometer stand. After aging, the FTP performance of these converters were evaluated on an auto-driver FTP stand using a 2.4L, four-cylinder prototype engine and on a 2.4L, four-cylinder prototype vehicle. A third set of unaged converters was used for cold flow restriction measurements and vehicle acceleration tests.

Southwest Research Institute has developed a passive, flow-through, membrane which separates carbon dioxide (CO2) from other exhaust gas species. Stoichiometric exhaust gas for 0% ethanol fuels contain approximately 14% CO2 by concentration. The membrane consists of a ceramic substrate impregnated with lithium zirconate (Li2ZrO3). In the presence of temperatures of 400-600 °C the CO2 reacts with lithium zirconate to form lithium carbonate (Li2CO3). The new compound moves from the inner surface of the membrane via partial pressure gradient to the outer wall of the membrane and desorbs into a low concentration CO2 environment, e.g. atmospheric air with 400 ppm CO2. SwRI has tested the membrane under engine-like conditions, comparable to 2000 rpm 10 bar BMEP operation, on a standalone burner rig (ECTO-lab burner). On the SwRI ECTO-lab burner rig temperature, flow-rate and exhaust gas products can be independently varied.

A 13 L HD diesel engine was converted to run as a flame propagation engine using the HEDGE™ Dual-Fuel concept. This concept consists of pre-mixed gasoline ignited by a small amount of diesel fuel - i.e., a diesel micropilot. Due to the large bore size and relatively high compression ratio for a pre-mixed combustion engine, high levels of cooled EGR were used to suppress knock and reduce the engine-out emissions of the oxides of nitrogen and particulates. Previous work had indicated that the boosting of high dilution engines challenges most modern turbocharging systems, so phase I of the project consisted of extensive simulation efforts to identify an EGR configuration that would allow for high levels of EGR flow along the lug curve while minimizing pumping losses and combustion instabilities from excessive backpressure. A potential solution that provided adequate BTE potential was consisted of dual loop EGR systems to simultaneously flow high pressure and low pressure loop EGR.

More stringent emission legislation has been a driver for changes in the design of Heavy Duty Diesel engines since the 1980s. Optimization of the combustion processes has lead to significant reductions of exhaust emission levels over the years. However, in the year 2002, diesel engines in the USA will have to meet an even more stringent set of emission requirements. Expectations are that this will force most engine builders to incorporate Exhaust Gas Recirculation (EGR). Several studies of the impact of EGR on lubricant degradation have shown increased levels of contamination with soot particles and acidic components. Both of these could lead to changes in lubricant requirements. The industry is developing a new specification for diesel engine lubricants, PC-9, using test procedures incorporating engines with EGR.

Measurement of emissions from small utility engines has usually been accomplished using steady-state raw emissions procedures such as SAE Recommended Practice J1088. While raw exhaust measurements have the advantage of producing modal exhaust gas concentration data for design feedback; they are laborious, may influence both engine performance and the emissions themselves, and have no provision for concurrent particulate measurements. It is time to consider a full-dilution procedure similar in principle to automotive and heavy-duty on-highway emission measurement practice, leading to improvements in many of the areas noted above, and generally to much higher confidence in data obtained. When certification and audit of small engine emissions become a reality, a brief dilute exhaust procedure generating only the necessary data will be a tremendous advantage to both manufacturers and regulatory agencies.

A technique is presented that has been successfully demonstrated to non-intrusively and quickly sample gases typically found in PCV systems. Color Detection Tubes (CDTs) were used with a simple sampling arrangement to monitor CO2, NOx, O2, and H2O(g) at the closure line, crankcase, and PCV line. Measurements were accurate and could be made instantaneously. Short Path Thermal Desorbtion Tubes (SPTDTs) were used at the same engine locations for the characterization of fuel- and oil-derived hydrocarbon (HC) fractions and required only 50 cc samples. High engine loads caused pushover of blowby vapors as indicated by increased concentrations of CO2, NOx, H2O(g), and fuel HCs in the engines' fresh air inlets during WOT operation. Peak concentrations of blowby vapors were measured in the crankcase under no load and part throttle conditions. Oxygen concentrations always opposed the trends of CO2, NOx, and H2O(g).

The US EPA emission standards for 2010 on-highway and 2014 non-road diesel engines are extremely stringent, both in terms of oxides of nitrogen (NOX) and particulate matter (PM). Diesel engines typically operate lean and use at least 40-50 percent more air than what is needed for stoichiometric combustion of the fuel. As a result, significant excess oxygen (O₂) is present in diesel exhaust gas which prevents the application of the mature three-way catalyst (TWC) technology for NOX control used in gasoline engines. The objective of this work was to investigate whether or not the catalyzed DPF had a TWC-type of effect on NOX emissions and if so, why and to what extent when used on a diesel engine operating at reduced A/F ratio conditions.

A menu-driven, PC-based model, ALAMO_ENGINE, has been developed to predict the nitrogen oxides (NOx) reductions in direct-injected, diesel engines due to exhaust gas recirculation (EGR), emulsified fuels, manifold or in-cylinder water injection, fuel injection timing changes, humidity effects, and intake air temperature changes. The approach was to use a diesel engine cycle simulation with detailed gas composition calculations for the intake and exhaust gases (including EGR, water concentration, fuel-type effects, etc.), coupled with a code to calculate stoichiometric, adiabatic flame temperatures and expressions that correlate measured NOx emissions with the flame temperature. Execution times are less than 10 seconds on a 486-66 MHz PC.

Diesel particulate filters (DPF), known as traps in the mid-to late 1970s, were being developed for on-highway diesel applications. However, advanced engine design and in-cylinder engineering enabled diesel engines and vehicles to meet extremely low emission limits, including those of particulate matter (PM) without the need for DPF's or other auxiliary emission control devices. Late in 2000, the US EPA finalized its on-highway heavy-duty diesel emission standards, thus ending speculations regarding its stringency and establishing the lowest limits ever. The new nitric oxides (NOX) and PM limits are seen as technology-forcing. For NOX emissions, the debate rages on among the technical community about the merits of NOX adsorbers and urea selective catalytic reduction. On the other hand, there seems to be little doubt about DPF's as the technical solution for PM.

The Lean NOx Trap (LNT) is a technology that could be used to reduce oxides of nitrogen from heavy-duty diesel engines to meet emissions standards (US 2010 and EURO 4/5/6). This paper describes a case-study for evaluating the feasibility of an LNT. LNTs suffer from sulfur poisoning and thermal aging limitations. Catalyst formulations allow reversal of sulfur poisoning through desulfation procedures. A case study was performed using a 7-liter diesel engine equipped with VGT, common rail fuel injection system, cooled EGR, oxidation catalyst and DPF. The LNT was positioned after the particulate filter. Gaseous raw emissions were measured from engine and various stages of aftertreatment. A Fourier Transform Infrared (FTIR) analyzer was used to characterize Ammonia and SO₂. Temperatures were measured in the substrate. Fast response NOx sensor allowed for continuous monitoring of the NOx in the LNT. A wide-range O₂ sensor was also utilized to measure equivalence ratio.

It is projected that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with 2010 emission standards of 0.20 g/bhp-hr, the National Ambient Air Quality Standards (NAAQS) requirements for ambient ozone will not be met. It is expected that further reductions in NOX emissions from the heavy-duty fleet will be required to achieve compliance with the ambient ozone requirement. To study the feasibility of further reductions, the California Air Resources Board (CARB) funded a research program to demonstrate the potential to reach 0.02 g/bhp-hr NOX emissions. This paper details the work executed to achieve this goal on the heavy-duty Federal Test Procedure (FTP) with a heavy-duty natural gas engine equipped with a three-way catalyst. A Cummins ISX-12G natural gas engine was modified and coupled with an advanced catalyst system.

The diesel engine has long been the most energy efficient powerplant for transportation. Moreover, diesels emit extremely low levels of hydrocarbon and carbon monoxide that do not require post-combustion treatment to comply with current and projected standards. It is admittedly, however, difficult for diesel engines to simultaneously meet projected nitrogen oxides and particulate matter standards. Traditionally, measures aimed at reducing one of these two exhaust species have led to increasing the other. This physical characteristic, which is known as NOx/PM tradeoff, remains the subject of an intense research effort. Despite this challenge, there is significant evidence that heavy-duty highway engine manufacturers can achieve substantial emission reductions. Many development programs carried out over the last five years have yielded remarkable results in laboratory demonstrations.

Increasing fuel costs and the desire for reduced dependence on foreign oil has brought the diesel engine to the forefront of future medium-duty vehicle applications in the United States due to its higher thermal efficiency and superior durability. The main obstacle to the increased use of diesel engines in this platform is the upcoming extremely stringent, Tier 2 emission standard. In order to succeed, diesel vehicles must comply with emissions standards while maintaining their excellent fuel economy. The availability of technologies such as common rail fuel injection systems, low sulfur diesel fuel, NOX adsorber catalysts (NAC), and diesel particle filters (DPFs) allow the development of powertrain systems that have the potential to comply with these future requirements. In meeting the Tier 2 emissions standards, the heavy light-duty trucks (HLDTs) and medium-duty passenger vehicles (MDPVs) will face the greatest technological challenges. In support of this, the U.S.

The 2010 emissions standards for heavy-duty engines have established a limit of oxides of nitrogen (NOX) emissions of 0.20 g/bhp-hr. However, the California Air Resource Board (ARB) projects that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with 2010 emission standards, the National Ambient Air Quality Standards (NAAQS) requirement for ambient particulate matter (PM) and Ozone will not be achieved without further reduction in NOX emissions. The California Air Resources Board (CARB) funded a research program to explore the feasibility of achieving 0.02 g/bhp-hr NOX emissions.

Recent 2010 emissions standards for heavy-duty engines have established a limit of oxides of nitrogen (NOX) emissions of 0.20 g/bhp-hr. However, CARB has projected that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with 2010 emission standards, the National Ambient Air Quality Standards (NAAQS) requirement for ambient particulate matter and Ozone will not be achieved without further reduction in NOX emissions. The California Air Resources Board (ARB) funded a research program to explore the feasibility of achieving 0.02 g/bhp-hr NOX emissions. This paper details engine and aftertreatment NOX management requirements and model based control considerations for achieving Ultra-Low NOX (ULN) levels with a heavy-duty diesel engine. Data are presented for several Advanced Technology aftertreatment solutions and the integration of these solutions with the engine calibration.

The most recent 2010 emissions standards for heavy-duty engines have established a tailpipe limit of oxides of nitrogen (NOX) emissions of 0.20 g/bhp-hr. However, it is projected that even when the entire on-road fleet of heavy-duty vehicles operating in California is compliant with 2010 emission standards, the National Ambient Air Quality Standards (NAAQS) requirement for ambient particulate matter and Ozone will not be achieved without further reduction in NOX emissions. The California Air Resources Board (CARB) funded a research program to explore the feasibility of achieving 0.02 g/bhp-hr NOX emissions.

The post-1998 diesel engine emissions challenge was put forth in July 1995 by the Statement of Principles (SOP) signed by the manufacturers of heavy duty engines, the U.S. Environmental Protection Agency (EPA) and the California Air Resources Board (CARB). Through this SOP, the signatories agreed to reduce the on-highway diesel engine NOx emissions by 50% from the legislated 1998 4.0 g/bhp.hr to 2.0 g/bhp.hr by the year 2004 with no increase over the 1998 particulate matter legislated level set at 0.1 g/bhp.hr. There are provisions in the SOP for the optional grouping of the gaseous hydrocarbons and NOx, limiting them at a combined value of 2.5 g/bhp.hr with a 0.5 g/bhp.hr hydrocarbon limit. In North America, particulate matter emissions standards were first imposed on heavy duty diesel engines in 1988. Since then, the NOx and particulate matter were balanced by taking advantage of the trade-off between the two pollutants inherent in diesel engines.

This paper analyzes the aging of zeolite based hydrocarbon traps to guide development of diagnostic algorithms. Previous research has shown the water adsorption ability of zeolite ages along with the hydrocarbon adsorption ability, and this leads to a possible diagnostic algorithm: the water concentration in the exhaust can be measured and related to aging. In the present research, engine experiments demonstrate that temperature measurements are also related to aging. To examine the relationship between temperature-based and moisture-based diagnostic algorithms, a transient, nonlinear heat and mass transfer model of the exhaust during cold-start is developed. Despite some idealizations, the model replicates the qualitative behavior of the exhaust system. A series of parametric studies reveals the sensitivity of the system response to aging and various noise factors.

Low intake manifold temperature, well below ambient, has many applications in internal combustion engines. In diesel engines, it can reduce NOx to a level of 2.0 g/hp-hr or below, going beyond the 1994 heavy duty diesel engine emissions standards. In gasoline engines, it can allow high compression ratio, turbocharged operation without end gas knock. This will permit ready conversion of some heavy duty diesel engines to gasoline operation at increased power density and lower emissions. In natural gas engines, it will allow base diesel engine to be converted to stoichiometric natural gas operation without increasing thermal loads. A three way catalyst can then be used to reduce emissions.