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A theoretical model for predicting cetane number of primary reference fuels from parameters measurable by proton nuclear magnetic resonance is presented. This modeling technique is expanded to include secondary reference fuels, pure hydrocarbons, and commercial-type fuels. An evaluation of the ignition process indicated that not only hydrogen type distribution measurable by proton NMR, but also relative hydrogen population is important in predicting cetane number. Two mathematical models are developed. One predicts cetane number of saturate fuels and the second predicts cetane number of fuels containing aromatic components. The aromatic fuel model is tested using the ASTM Diesel Check Fuels and shown to predict within the standard error of the model.

An investigation was performed to identify the benefits of cooled exhaust gas recirculation (EGR) when applied to a potential ethanol flexible fuelled vehicle (eFFV) engine. The fuels investigated in this study represented the range a flex-fuel engine may be exposed to in the United States; from 85% ethanol/gasoline blend (E85) to regular gasoline. The test engine was a 2.0-L in-line 4 cylinder that was turbocharged and port fuel injected (PFI). Ethanol blended fuels, including E85, have a higher octane rating and produce lower exhaust temperatures compared to gasoline. EGR has also been shown to decrease engine knock tendency and decrease exhaust temperatures. A natural progression was to take advantage of the superior combustion characteristics of E85 (i.e. increase compression ratio), and then employ EGR to maintain performance with gasoline. When EGR alone could not provide the necessary knock margin, hydrogen (H2) was added to simulate an onboard fuel reformer.

Increased in-cylinder hydrogen levels have been shown to improve burn durations, combustion stability, HC emissions and knock resistance which can directly translate into enhanced engine efficiency. External fuel reformation can also be used to increase the hydrogen yield. During the High-Efficiency, Dilute Gasoline Engine (HEDGE) consortium at Southwest Research Institute (SwRI), the potential of increased hydrogen production in a dedicated-exhaust gas recirculation (D-EGR) engine was evaluated exploiting the water gas shift (WGS) and steam reformation (SR) reactions. It was found that neither approach could produce sustained hydrogen enrichment in a real exhaust environment, even while utilizing a lean-rich switching regeneration strategy. Platinum group metal (PGM) and Ni WGS catalysts were tested with a focus on hydrogen production and catalyst durability.

To develop a methodology for characterizing particulate emissions from diesel engines, one 2-stroke cycle engine and one 4-stroke cycle engine were operated in both individual steady-state modes and according to a variation of the 13-mode diesel emissions measurement procedure. Both engines were operated on three fuels, each used with one of two available diesel fuel additives as well as by itself. The primary particulate sampling technique employed was a dilution tunnel, and secondary evaluation techniques included a diluter-sampler developed under contract to EPA by another organization, a light extinction smokemeter, and a filter-type sampling smokemeter. Gaseous emissions were also measured, providing a running check on engine condition. Particulate mass rates were calculated from gravimetric data; and analysis of particulate included determination of sulfur, carbon, hydrogen, nitrogen, phenols, nitrosamines, trace metals, and organic solubles.

A fire exposure test was conducted on a 72.4 liter composite (Type HGV-4) hydrogen fuel tank at an initial hydrogen pressure of 34.3 MPa (ca 5000 psi). No Pressure Relief Device was installed on the tank to ensure catastrophic failure for analysis. The cylinder ruptured at 35.7 MPa after a 370 kW fire exposure for 6 min 27 seconds. Blast wave pressures measured along a line perpendicular to the cylinder axis were 18% to 25% less the values calculated from ideal blast wave correlations using a blast energy of 13.4 MJ, which is based on the ideal gas internal energy at the 35.7 MPa burst pressure. The resulting hydrogen fireball maximum diameter of 7.7 m is about 19% less than the value predicted from existing correlations using the 1.64 kg hydrogen mass in the tank.

Various fire scenarios involving a hydrogen fuel system were simulated to evaluate their associated safety hazards. Scenarios included finite releases of hydrogen with delayed ignition as well as small hydrogen jet-fire releases. The scenarios tested resulted in minimal damage to the vehicle, minimal hazards to the vehicle's surroundings, and no observable damage or hazards within the passenger compartment.

A vehicle's gasoline fuel tank was removed and replaced with a 5,000-psig, Type-III, aluminum-lined hydrogen cylinder. High-pressure cylinders are typically installed with a thermally-activated pressure relief device (PRD) designed to safely vent the contents of the cylinder in the event of accidental exposure to fire. The objective of this research was to assess the results of a catastrophic failure in the event that a PRD were ineffective. Therefore, no PRD was installed on the vehicle to ensure cylinder failure would occur. The cylinder was pressurized and exposed to a propane bonfire in order to simulate the occurrence of a gasoline pool fire on the underside of the vehicle. Measurements included temperature and carbon monoxide concentration inside the passenger compartment of the vehicle to evaluate tenability. Measurements on the exterior of the vehicle included blast wave pressures. Documentation included standard, infrared, and high-speed video.

Lower explosion limits (LEL) and the chemical compositions of JP-8, Jet A and JP-5 fuel vapors were determined in a sealed combustion vessel equipped with a spark igniter, a gas-sampling probe, and sensors to measure pressure rise and fuel temperature. Ignition was detected by pressure rise in the vessel. Pressure rises up to 60 psig were observed near the flash points of the test fuels. The fuel vapors in the vessel ignited from as much as 11°F below flash-point measurements. Detailed hydrocarbon speciation of the fuel vapors was performed using high-resolution gas chromatography. Over 300 hydrocarbons were detected in the vapors phase. The average molecular weight, hydrogen to carbon ratio, and LEL of the fuel vapors were determined from the concentration measurements. The jet fuel vapors had molecular weights ranging from 114 to 132, hydrogen to carbon ratios of approximately 1.93, and LELs comparable to pure hydrocarbons of similar molecular weight.

The primary focus of this investigation was to determine the hydrogen reformation, efficiency and knock mitigation benefits of methanol-fueled Dedicated EGR (D-EGR®) operation, when compared to other EGR types. A 2.0 L turbocharged port fuel injected engine was operated with internal EGR, high-pressure loop (HPL) EGR and D-EGR configurations. The internal, HPL-EGR, and D-EGR configurations were operated on neat methanol to demonstrate the relative benefit of D-EGR over other EGR types. The D-EGR configuration was also tested on high octane gasoline to highlight the differences to methanol. An additional sub-task of the work was to investigate the combustion response of these configurations. Methanol did not increase its H2 yield for a given D-EGR cylinder equivalence ratio, even though the H:C ratio of methanol is over twice typical gasoline.

This paper describes an on-vehicle demonstration of a hydrogen-heated catalyst (HHC) system for reducing the level of cold-start hydrocarbon emissions from a gasoline-fueled light-duty vehicle. The HHC system incorporated an onboard electrolyzer that generates and stores hydrogen (H2) during routine vehicle operation. Stored hydrogen and supplemental air are injected upstream of a platinum-containing automotive catalyst when the engine is started. Rapid heating of the catalytic converter occurs immediately as a result of catalytic oxidation of hydrogen (H2) with oxygen (O2) on the catalyst surface. Federal Test Procedure (FTP) emission results of the hydrogen-heated catalyst-equipped vehicle demonstrated reductions of hydrocarbons (HC) and carbon monoxide (CO) up to 68 and 62 percent, respectively. This study includes a brief analysis of the emissions and fuel economy effects of a 10-minute period of hydrogen generation during the FTP.

In light of the increasingly stringent efficiency and emissions requirements, several new engine technologies are currently under investigation. One of these new concepts is the Dedicated EGR (D-EGR®) engine. The concept utilizes fuel reforming and high levels of recirculated exhaust gas (EGR) to achieve very high levels of thermal efficiency. While the positive impact of reformate, in particular hydrogen, on gasoline engine performance has been widely documented, the on-board reforming process and / or storage of H2 remains challenging. The Water-Gas-Shift (WGS) reaction is well known and has been used successfully for many years in the industry to produce hydrogen from the reactants water vapor and carbon monoxide. For this study, prototype WGS catalysts were installed in the exhaust tract of the dedicated cylinder of a turbocharged 2.0 L in-line four cylinder MPI engine. The potential of increased H2 production in a D-EGR engine was evaluated through the use of these catalysts.