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In this paper, HCCI combustion characteristics of three typical high octane number fuels, gasoline, ethanol and methanol, are compared in a Ricardo single cylinder port injection engine with compression ratio of 10.5. In order to trap enough high temperature residual gas to heat intake mixture charge for stable HCCI combustion, camshafts of the experimental engine are replaced by a set of special camshafts with low valve lift and short cam duration. The three fuels are injected into the intake port respectively in different mixture volume percentages, which are E0 (100% gasoline), E50 (50% gasoline, 50% ethanol), E100 (100% ethanol), M50 (50% gasoline, 50% methanol) and M100 (100% methanol). This work concentrates on the combustion and emission characteristics and the available HCCI operation range of these fuels. What's more, the detailed comparison of in-cylinder temperature, ignition timing and other parameters has been carried out.