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With ever increasing population growth and increase in per capita income, there is a lot of demand on energy requirements. Also due to depletion in fossil fuels, rocketing fuel prices and CO2 emissions standards, it is imperative to find solutions which are cost-effective and from sustainable energy sources. Being in the sunny tropical belt, India has high solar insolation, and so it should adopt a policy of developing solar power as a dominant component of the renewable energy mix. This paper describes the best possible ways to use solar energy for automotive application. This paper explains various types of photovoltaic (PV) technologies - crystalline and thin film solar cells for automotive use. A medium sized sedan vehicle with mild hybrid technology and roof mounted PV panel has been used for all experiments. The paper describe the benefits and limitations of each PV technology with experimental measurement and payback period analysis.