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SI-CAI hybrid combustion, also known as spark-assisted compression ignition (SACI), is a promising concept to extend the operating range of CAI (Controlled Auto-Ignition) and achieve the smooth transition between spark ignition (SI) and CAI in the gasoline engine. In order to investigate the effect of the thermal boundary condition on the hybrid combustion, the experiments with different coolant temperatures are performed to adjust the chamber wall temperature in a gasoline engine. The experimental results indicate that increasing wall temperature would advance the combustion phasing, enlarge the peak heat release rate and shorten the combustion duration. While the capacity of the wall temperature effect on the hybrid combustion characteristics are more notable in the auto-ignition dominated hybrid combustion.