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Non-equilibrium all-atom MD simulations are used to study the traction properties of hydrocarbon fluids. A fluid layer is confined between two solid Fe plates under the constant normal force of 1.0 GPa. Traction simulations are performed by applying a relative sliding motion to the Fe plates. Shear behaviors of nine hydrocarbon fluids are simulated on a sufficiently large film thickness of 6.7 nm, and succeeded in reproducing the order of the experimental traction coefficients. The dynamic mechanism of the momentum transfer on layers of fluid molecules are analyzed focusing on the intermolecular interactions (density profile, orientation factor, pair-correlation function) and intramolecular interactions (intramolecular interaction energy, conformation change of alicyclic ring). In contrast to the case of n-hexane, which shows low traction due to a fragile chain-like interaction, other mechanisms are obtained in the high traction molecules of cyclohexane, dicyclohexyl and santotrac 50.

Natural gas homogeneous charge compression ignition (HCCI) engines require high compression ratios and intake air heating because of the high auto-ignition temperature of natural gas. In the first study, the natural gas fueled HCCI combustion with internal exhaust gas recirculation (EGR) was achieved without an intake air heater. The effects of the combustion chamber configuration, turbocharging, and external EGR were investigated for expanding the operating range. As a result, it was cleared that the combination of internal / external EGR and turbocharging is effective for expanding the HCCI operational range toward high loads. Meanwhile, the HCCI combustion characteristics at high engine speeds were unstable because of an insufficient reaction time for auto-ignition. Although the engine operation with a richer air-fuel ratio was effective for improving the combustion stability, the combustion noise (CN) was at an unacceptable level.

The catalyst of the crystalline ceramics known as a perovskite-type oxide was designed and controlled at the atomic level in order to create a new function for self-regeneration of precious metals in a usage ambience without auxiliary treatment. We have already reported that a catalyst with Pd supported on the perovskite-type oxide has higher activity than a catalyst with Pd supported on alumina. It was also found that Pd supported on the perovskite catalyst is finely dispersed [1, 2 and 3] The object of this study was to investigate the mechanism of self-regeneration by using hyper-analytical facilities. XAFS analysis, at SPring-8 (8 GeV), revealed that Pd is in six-fold coordinations with oxygen in a perovskite crystal, which indicating that Pd occupies the B site of the unit formula of ABO3 in the perovskite crystal structure under oxidation atmosphere.

If a vehicle is left in a humid environment, the coefficient of friction between the brake pads and discs increases, generating a discomforting noise during braking called brake squeal. It is assumed that this increase in the coefficient of friction in a humid environment is the effect of moisture penetrating between the brake friction surfaces. Therefore, this paper analyzes the factors causing coefficient of friction variation with moisture between the friction surfaces by dynamic observation of these surfaces. The observation was achieved by changing the disc materials from cast iron to borosilicate glass. One side of the glass brake disc was pushed onto the brake pad and the sliding surface was observed from the opposite side by a charge coupled device (CCD) camera. First, a preliminary test was carried out in a dry state using two pad materials with different wear properties to select the appropriate pad for observing the friction surfaces.

The stoichiometric direct injection gasoline engines have higher torque performance than the port injection engines, as the volumetric efficiency can be increased due to the cooling effects of charging air by the fuel evaporation in the cylinder. They need only 3-way catalyst, leading to the cost down. However there exists the injection timing (region) that increased volumetric efficiency does not lead to higher torque. In order to investigate the phenomena, the in-cylinder mixture formation process has been analyzed by the LIF and the CFD techniques. As the results, it has been revealed that the phenomena are caused by the inhomogeneous mixture distribution before the ignition timing.

Methyl esters of saturated/unsaturated higher aliphatic acids (FAMEs) and a FAME of waste cooking oil (WCOME) were heated at 120°C in an air gas flow. The samples were analyzed before and after heating, using six different methods including electrospray ionization mass spectrometry. As a result, the samples after heating were found to contain low molecular weight aliphatic compounds and oligomers of the FAME. Based on the chemical structure of these oxidation products, reaction schemes were proposed for the deterioration of FAMEs. In addition, two unsaturated FAMEs containing 2,6-di-t-butyl-p-cresol (BHT) were similarly heated and analyzed to examine the effect of BHT on the oxidation of these FAME.

The effect of GTL diesel fuel on organic materials used in fuel delivery systems of vehicles was investigated. Specimens made from 16 kinds of organic materials were immersed in GTL diesel fuels synthesized at Refinery-A and Refinery-B (referred to as GTL-A and GTL-B, respectively) and then subjected to tensile testing. The tensile test results revealed that elongation of the nylon sample immersed in GTL-A was extremely small, about 4% of that of untreated nylon. In the light of this finding, the GTL diesel fuels and nylons before and after immersion test were analyzed in detail using about 20 analysis methods to determine the cause for poor elongation. The following points were found. (1) GTL-A consisted of low molecular-weight paraffins. (2) GTL-A had low molecular-weight i-paraffins. (3) The nylon immersed in GTL-A contained low molecular-weight paraffins. (4) The paraffins in the nylon immersed in GTL-A were richer in i-paraffins than the original GTL-A.

Toyota participated in Formula One1 (F1) Racing from 2002 to 2009. As a result of the downturn in the world economy, various engine developments within F1 were restricted in order to reduce the cost of competing in F1. The limit on the maximum number of engines allowed has decreased year by year. Toyota focused on the engine performance deterioration due to the combustion chamber deposits. In 2009, Toyota was successful in reducing around 40% of the deterioration by making combustion chamber cleaner in cooperation with ExxonMobil. This contributed to good result of 2009 F1 season for Toyota, including two second place finishes.

This report describes the implementation of the spark channel short circuit and blow-out submodels, which were described in the previous report, into a spark ignition model. The spark channel which is modeled by a particle series is elongated by moving individual spark particles along local gas flows. The equation of the spark channel resistance developed by Kim et al. is modified in order to describe the behavior of the current and the voltage in high flow velocity conditions and implemented into the electrical circuit model of the electrical inductive system of the spark plug. Input parameters of the circuit model are the following: initial discharge energy, inductance, internal resistance and capacitance of the spark plug, and the spark channel length obtained by the spark channel model. The instantaneous discharge current and the voltage are obtained as outputs of the circuit model.

In diesel engines with a straight intake port and a lipless cavity to restrict in-cylinder flow, an injector with numerous small-diameter orifices with a narrow angle can be used to create a highly homogeneous air-fuel mixture that, during PCCI combustion, dramatically reduces the NOX and soot without the addition of expensive new devices. To further improve this new combustion concept, this research focused on cooling losses, which are generally thought to account for 16 to 35% of the total energy of the fuel, and approaches to reducing fuel consumption were explored. First, to clarify the proportions of convective heat transfer and radiation in the cooling losses, a Rapid Compression Machine (RCM) was used to measure the local heat flux and radiation to the combustion chamber wall. The results showed that though larger amounts of injected fuel increased the proportion of heat losses from radiation, the primary factor in cooling losses is convective heat transfer.

Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.

We have developed a high capacity electromagnetic clutch by means of Si-containing diamond-like carbon (DLC-Si) coating. The durability of the new clutch is enhanced up to 8 times higher than that of the conventional one. Such a superior performance is due to several tribological properties of the DLC-Si film and micro morphology on the clutch surface. In particular, the DLC-Si plays a significant role in maintaining the groove shape of the clutch and giving sufficient friction in fluid, which is required for a drivetrain device. Besides, our deposition process (using direct current plasma-assisted chemical vapor deposition) has afforded homogeneous DLC-Si-coated clutches in large quantities. These techniques have enabled us to reduce the number of clutch discs per coupling and achieve a more compact and higher capacity AWD coupling at a lower cost.

This paper deals with a case where H∞ control is applied to a basic control logic of a rack-assisted Electric Power Steering (EPS) system. In the body, the following three key features are described: Construction of the target controlled model including a vehicle Controller design for the model H∞ controller performance verification In this paper, it has been confirmed that H∞ control is valid as a basic control logic for the EPS system.

In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.

Further improvements in catalyst performance are required to help protect the atmospheric environment. However, from the viewpoint of resource availability, it is also necessary to decrease the amount of precious metals used at the active sites of the catalyst. Therefore, a high-performance three-way catalyst with an advanced coating layer has been developed to lower the amount of precious metal usage. Fuel efficiency improvement technologies such as high compression ratios and a large-volume exhaust gas recirculation (EGR) generally tend to increase the ratio of hydrocarbons (HC) to nitrogen oxides (NOx) in exhaust gas. This research focused on the palladium (Pd) loading depth in the coating layer with the aim of improving the hydrocarbon (HC) conversion activity of the catalyst.

Growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. One of the key technologies is a new OSC material that has low surface area (SA) and high OSC performance. We enhanced the pyrochlore- ceria/zirconia (CZ) which has a very small SA. In order to enhance the heat resistance and promote the OSC reaction, we selected and optimized the additive element. This material showed high OSC performance especially in the temperature range of 400 degrees or less. Another key technology is washcoat structure that has high gas diffusivity by making connected pore in the washcoat (New pore forming technology).

In order to reduce the energy consumption of the automotive air conditioning system, adsorption heat pump (AHP) system is one of the key technologies. We have been developing compact AHP system utilizing the exhaust heat from the engine coolant system (80-100 °C), which can meet the requirements in the automotive application. However, AHP systems have not been practically used in automotive applications because of its low volumetric power density of the adsorber. The volumetric power density of the adsorber is proportional to sorption rate, packing density and latent heat. In general, the sorption rate is determined by mass transfer resistance in primary particle of an adsorbent and heat and mass transfer resistance in packed bed. In order to improve the volumetric power density of the adsorber, it is necessary to increase the production of the sorption rate and the packing density.

According to the principle of pH measurement, an on-board type engine oil deterioration sensor has been developed. The developed sensor is composed of a Pb and oxidized stainless steel electrodes. The sensor signal shows a good linear relationship to the quasi-pH value of the oil. Especially in the region where the oil deterioration proceeds, the remaining basic additives in the oil is easily estimated from the sensor signal.

A concept of dual-fuel, Premixed Compression Ignition (PCI) combustion controlled by two fuels with different ignitability has been developed to achieve drastically low NOx and smoke emissions. In this system, isooctane, which was used to represent high-octane gasoline, was supplied from an intake port and diesel fuel was injected directly into an engine cylinder at early timing as ignition trigger. It was found that the ignition timing of this PCI combustion can be controlled by changing the ratio of amounts of injected two fuels and combustion proceeds very mildly by making spatial stratifications of ignitability in the cylinder even without EGR, as preventing the whole mixture from igniting simultaneously. The operable range of load, where NOx and smoke were less than 10ppm and 0.1 FSN, respectively, was extended up to 1.2MPa of IMEP using an intake air boosting system together with dual fueling.

The effect of the chemical reactivity of diesel fuel on PM formation was investigated using a flow reactor and a shock tube. Reaction products from the flow-reactor pyrolysis of the three diesel fuels used for the engine tests in Part 1(1) (“Base”, “Improved” and Swedish “Class-1”) were analyzed by gas chromatography. At 850C, Swedish “Class-1” fuel was found to produce the most PM precursors such as benzene and toluene among the three fuels, even though it contains very low amounts of aromatics. The chemical analyses described in Part 1 revealed that “Class-1” contains a large amount of branched and cyclic structures in the saturated hydrocarbon portion of the fuel. These results suggest that the presence of such branched and ring structures can increase exhaust PM emissions.