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Two-line excitation LIF (Laser-Induced Fluorescence) technique for 2-dimensional temperature measurements in an engine cylinder before ignition is presented. From the fundamental examinations, the combination of toluene tracer with a pair of excitation lines of 248nm and 266nm has been selected because of the high LIF intensity ratio and closer excitation wavelengths. In-cylinder thermometry is conducted using a visualized single cylinder spark ignition engine both in PFI (port-fuel-injection) and DI (direct-injection) operation. The accuracy of this technique is determined through the homogeneous PFI experiment. Temperature and fuel distribution in unburned mixture are measured simultaneously in DI operation. It exists a strong correlation between equivalence ratio and temperature inside the mixture. Temperature in the fuel rich region is lower than in the fuel lean region.

The catalyst of the crystalline ceramics known as a perovskite-type oxide was designed and controlled at the atomic level in order to create a new function for self-regeneration of precious metals in a usage ambience without auxiliary treatment. We have already reported that a catalyst with Pd supported on the perovskite-type oxide has higher activity than a catalyst with Pd supported on alumina. It was also found that Pd supported on the perovskite catalyst is finely dispersed [1, 2 and 3] The object of this study was to investigate the mechanism of self-regeneration by using hyper-analytical facilities. XAFS analysis, at SPring-8 (8 GeV), revealed that Pd is in six-fold coordinations with oxygen in a perovskite crystal, which indicating that Pd occupies the B site of the unit formula of ABO3 in the perovskite crystal structure under oxidation atmosphere.

The stoichiometric direct injection gasoline engines have higher torque performance than the port injection engines, as the volumetric efficiency can be increased due to the cooling effects of charging air by the fuel evaporation in the cylinder. They need only 3-way catalyst, leading to the cost down. However there exists the injection timing (region) that increased volumetric efficiency does not lead to higher torque. In order to investigate the phenomena, the in-cylinder mixture formation process has been analyzed by the LIF and the CFD techniques. As the results, it has been revealed that the phenomena are caused by the inhomogeneous mixture distribution before the ignition timing.

A study of diesel fuel as a lubricant for diesel engines was conducted with the aim of dramatically reducing engine friction and eliminating the need to change the lubricating oil. A prototype single-cylinder engine modified for diesel fuel lubrication was made, and it was confirmed that firing operation is possible. Piston friction during the firing operation was reduced by modifying the shape of the cylinder liner surface to improve the retention of the lubricating oil. The study produced valid findings concerning engine lubrication, not only with diesel fuel, but also with ultra-low viscosity oil.

Countries and regions around the world are tightening emissions regulations in reaction to the increasing awareness of environmental conservation. At the same time, growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. This catalyst incorporates rhodium (Rh) clusters with a particle size of several nanometers, and stabilized CeO2-ZrO2 solid-solution (CZ) with a pyrochlore crystal structure as a high-volume oxygen storage capacity (OSC) material with a slow O2 storage rate.

In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.

Growing concerns about the depletion of raw materials as vehicle ownership continues to increase is prompting automakers to look for ways of decreasing the use of platinum-group metals (PGMs) in the exhaust systems. This research has developed a new catalyst with strong robustness against fluctuations in the exhaust gas and excellent nitrogen oxide (NOx) conversion performance. One of the key technologies is a new OSC material that has low surface area (SA) and high OSC performance. We enhanced the pyrochlore- ceria/zirconia (CZ) which has a very small SA. In order to enhance the heat resistance and promote the OSC reaction, we selected and optimized the additive element. This material showed high OSC performance especially in the temperature range of 400 degrees or less. Another key technology is washcoat structure that has high gas diffusivity by making connected pore in the washcoat (New pore forming technology).

According to the principle of pH measurement, an on-board type engine oil deterioration sensor has been developed. The developed sensor is composed of a Pb and oxidized stainless steel electrodes. The sensor signal shows a good linear relationship to the quasi-pH value of the oil. Especially in the region where the oil deterioration proceeds, the remaining basic additives in the oil is easily estimated from the sensor signal.

A concept of dual-fuel, Premixed Compression Ignition (PCI) combustion controlled by two fuels with different ignitability has been developed to achieve drastically low NOx and smoke emissions. In this system, isooctane, which was used to represent high-octane gasoline, was supplied from an intake port and diesel fuel was injected directly into an engine cylinder at early timing as ignition trigger. It was found that the ignition timing of this PCI combustion can be controlled by changing the ratio of amounts of injected two fuels and combustion proceeds very mildly by making spatial stratifications of ignitability in the cylinder even without EGR, as preventing the whole mixture from igniting simultaneously. The operable range of load, where NOx and smoke were less than 10ppm and 0.1 FSN, respectively, was extended up to 1.2MPa of IMEP using an intake air boosting system together with dual fueling.

Fretting fatigue mechanism of rapidly solidified powder aluminum alloy has been studied by model tests and analysis using fracture mechanics. The factors which influences upon fretting scar formation and fatigue crack propagation were the main concerns in the present work. In order to investigate the mechanism of fretting scar formation in detail, fretting wear tests in which small amplitude oscillatory movement occurred in the contact region were carried out. Test results showed that the size of fretting scar increased with increasing tangential force coefficient. Characteristics of fretting fatigue crack propagation were analyzed using fracture mechanics. The fatigue limits under fretting conditions were estimated by connecting the applied stress intensity factor range calculated from applied cyclic stress and tangential force, with the threshold stress intensity factor range of small crack.

The properties of diesel fuels were investigated in terms of particulate emissions to clarify the specification of such a diesel fuel for minimizing particulate emissions. Diesel fuels were analyzed using thin layer chromatography (TLC), and gas chromatography/mass spectrometry (GC/MS). These analysis revealed the entire composition of hydrocarbons in diesel fuels according to molecular formula. The entire composition of hydrocarbons in diesel fuels could be expressd on a three-dimensional graph: the X-axis as carbon number, the Y-axis as H/C ratio and the Z-axis as the amount of hydrocarbons of identical molecular formula. By using the graph, the properties reported so far were investigated. Also, simplified images of the fuel sprayed into a cylinder and its flame were derived from the observational results previously reported.

Diamond-like carbon (DLC) films are of significant interest for the automobile field, because they possess the potential to improve friction properties under various sliding conditions. Among the various DLC films, the authors focus on silicon-containing DLC (DLC-Si) films, which exhibit extremely low friction coefficient under dry sliding conditions in an ambient air atmosphere. The aim of this study is to examine the influence of silicon content in DLC-Si films on the friction property of the films, and to clarify the low friction mechanism of the films. The friction test was conducted under dry sliding conditions. It was found that the films have an exceedingly low friction coefficient (about 0.05) ranging in silicon content from 4 at% to 17 at%. In order to examine the low friction mechanism of the films, surface analyses were done on the wear surface of DLC-Si films slid against bearing steel.

In the case of engine bearings, pressure in a cylinder is necessary for the analysis of lubrication. In this study, a cycle simulation of gasoline engines has been developed to predict the pressure in the cylinder under the wide range of engine operation. In the cycle simulation, intake and exhaust processes are included and combustion process is calculated with flame propagation based on burning velocity. Here, the equation of ignition delay and the equation of burning velocity were determined with experimental results of a gasoline engine over wide A/F ratio. The pressure in the cylinder over the engine cycle is introduced into an elastohydrodynamic lubrication analysis of a con-rod bearing to calculate the load on the bearing in addition to the inertia force. Orbital movement, minimum film thickness, and power loss in the bearing were estimated over the wide range of engine operation.

The laser-induced exciplex fluorescence (LIEF) technique, currently used to observe mixture formation in a diesel engine, has been applied to a spark ignition (SI) engine and a new equivalence ratio calibration technique has been developed in order that two-dimensional measurements of the equivalence ratio may be made in an operating engine. Spectrally separated fluorescent images of liquid and vapor phase fuel distributions were obtained by adding new exciplex-forming dopants to the gasoline fuel. Dual light sheets from an excimer laser were introduced into one of the cylinders of a 4-valve lean-burn engine, and 2-D images of the mixture formation were recorded at pre-set crank angles during the induction and compression strokes by an image-intensified camera equipped with the appropriate filter.

In order to improve corrosion resistance and thermal efficiency of the air conditioner evaporator, a coating which provides hydrophilicity was formed over the chromate coating. In addition, there has been greater demand for air with fewer smells. This report describes the cause of “dusty odor” and a method to reduce it. The dusty odor is caused by a little corrosion of the substrate aluminum. Hydrophilic coating film dissolves little by little in condensed water, and substrate aluminum is exposed. A method to prevent the odor was developed by forming a coating giving hydrophilicity and durability to the evaporator surface.

NOx reduction activity in an oxidizing exhaust gas was significantly improved by discharging non-thermal plasma and catalysts (plasma assisted catalysis). We investigated effective catalyst for plasma assisted catalysis in view of hydrocarbon-selective catalytic reduction(HC-SCR). Plasma assist was effective for γ-alumina and alkali or alkaline earth metals loaded zeolite and γ-alumina showed the highest NOx conversion among these catalysts. On the other hand, Plasma assist was not effective for Cu-ZSM-5 and Pt loaded catalyst. The NOx conversion for the plasma assisted γ-alumina decreased by formation of a deposit on the catalyst below 400°C. It is shown that indium loading on γ-alumina improved the NOx reduction activity and suppressed the degradation of the NOx reduction activity at 300°C with plasma assist.

Three-dimensional numerical analysis of fuel liquid and mixture behavior in a port-injection gasoline engine is assessed by comparing calculations with measurements. The fuel mass distributed in the intake port and cylinder is measured using an engine with hydraulic valve and gas sampling system. The experimental results show that about half of the fuel mass per injection enters the cylinder, and the rest stays in the port. The difference of the mass fraction of injected fuel directly entering the cylinder is small between the cases of single pulse injection and serial injection. Therefore, three-dimensional calculation presupposing single pulse injection has difficulty in predicting the in-cylinder mixture formation process, although it can analyze the amount of fuel wetting the port wall. The calculations are performed for a port-injection engine, and the differences of fuel behavior with respect to swirl control valve opening and wall temperature are discussed.

A multi-component fuel vaporization model is developed for numerical analysis of specific fuel component behaviors in port-fuel-injection(PFI) gasoline engines. In order to specify the differences of in-cylinder fuel distribution among its components, three-dimensional calculations of intake flow, spray and vapor motion of each component are performed with respect to engine wall temperature and the distillation characteristics of the fuel. Simultaneous measurements of in-cylinder behaviors of different volatility components in the fuel are also carried out using a laser-induced fluorescence (LIF) technique to validate the calculation results. In both measurements and calculations, the same fuels are used, which are composed of seven or eight components to simulate the distillation characteristics of two kinds of gasoline. The in-cylinder vapor amount of high and low volatility components is compared between the calculations and the experiments.

A method of real time oil concentration measurment has been developed utilizing the effect of ultraviolet light absorption by lubricating oil in the liquid refrigerant line of an automotive air conditioning system. The light wavelengths from 200nm to 370nm are selected based on the ultraviolet light absorption sensitivity of the oils and refrigerants (CFC12,HFC134a). The effects of temperature,pressure and contaminantion on the absorbance of light are investigated in order to determine how these parameters affect the concentration measurement. The density changes of refrigerants are then compensated in the calculation for the oil concentration. The uncertainties of the overall concentration measurement are less than ±0.1 weight percent at 1 weight percent concentration. A transient oil circulation of the automotive air conditioner is measured by using this method.

The schlieren visualization of in-cylinder processes from the side of an engine cylinder is useful to understand the phenomena which change along the cylinder axis. A transparent collimating cylinder, TCC, permits schlieren observation inside the cylinder through its transparent wall. In this study, a single cylinder visualization engine with the TCC was applied to a direct-injection gasoline engine. A fuel spray, mixture formation and combustion were observed with a simultaneous measurement of in-cylinder pressure. The shape of the fuel spray and subsequent mixture formation process are drastically changed with the injection timing. The images of luminous flame were also taken with the schlieren images during the combustion period. Stable combustion, misfire and abnormal combustion are discussed with the comparison between the observed results and in-cylinder pressure analysis.