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A multi-dimensional numerical method for predicting the warm-up characteristic of automobile catalytic converter systems was developed to effectively design catalytic converter systems which achieve low tail pipe emissions with satisfactory packagebility. The features of the method are; (1) consideration of the governing phenomena such as gas flow, heat transfer, and chemical reactions (2) capability of predicting warm-up characteristic for not only the catalytic converters but also the system as a whole during emission test modes such as the USA LA-4 mode. The description of the method is presented. The experimental verifications of the method were conducted to assure the accuracy of it. The effect of design parameters such as electrically heated catalyst (EHC), high loading of noble metal and thin honeycomb wall on warm-up characteristic of the catalyst are analyzed in the paper.

In SI engines with port injection system, fuel behavior both in the intake port and in the cylinder has significant influence on the transient A/F characteristics and HC emissions [1]. Therefore, to improve the engine performance, it is very important to understand fuel behavior in the intake port and in the cylinder [2, 3]. This paper describes the following three unique methods to analyze fuel behavior in port injected SI engines and some test results. (1) Observation of fuel behavior in the intake port, using a transparent intake air tube and a strobe synchronized TV-photographic system. (2) Observation of fuel behavior in the cylinder, using a glass cylinder and fluorescent fuel. (3) Measurement of fuel wall wetting in the intake port and in the cylinder, using the engine with electronically controlled hydraulically driven in-take/exhaust valves.

A newly-developed time resolved exhaust gas analysis system was utilized in this study. The hydrocarbon compositions upstream and downstream of the catalytic converter were investigated during cold start and warm up of the Federal Test Procedure(FTP), with three fuels of different aromatic contents. Although engine-out hydrocarbon emissions had high concentrations right after cold start, the specific reactivity was low. This can be explained by the selective adsorption of the high boiling point components which had a high Maximum Incremental Reactivity (MIR) in the intake manifold and engine-oil films. Thereafter, the high boiling point components were desorbed rapidly and consequently specific reactivity increased. Hydrocarbon adsorption of high boiling point components and hydrocarbon conversion of low boiling point components occurred simultaneously on the catalyst during warm up.