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In order to meet increasingly stringent fuel consumption and emission regulations, more attentions are paid to improve engine efficiency. A large amount of energy-saving technologies have been applied in automotive field especially in gasoline engines. It is well known that lean burn and ultra-high compression ratio technologies are two basic and important methods to increase efficiency. In this paper, a rapid compression machine was employed to study combustion process of lean iso-octane mixture at ultra-high compression ratios (16 to 19:1). Regardless of flammability of the mixture, spark was triggered at the timing right after the end of compression, then, the flame propagation and/or auto-ignition can be recorded using high-speed photography simultaneously. The effects of equivalence ratio (φ), compression ratio (ε), dilution ratio, and effective temperature (Teff) on the combustion process was investigated.