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Fuel film deposits on combustion chamber walls are understood to be the main source of particle emissions in GDI engines under homogenous charge operation. More precisely, the liquid film that remains on the injector tip after the end of injection is a fuel rich zone that undergoes pyrolysis reactions leading to the formation of poly-aromatic hydrocarbons (PAH) known to be the precursors of soot. The physical phenomena accompanying the fuel film deposit, evaporation, and the chemical reactions associated to the injector film are not yet fully understood and require high fidelity CFD simulations and controlled experimental campaigns in optically accessible engines. To this end, a simplified model based on physical principles is developed in this work, which couples an analytical model for liquid film formation and evaporation on the injector tip with a stochastic particle dynamics model for particle formation.

The 4th Workshop of the Engine Combustion Network (ECN) was held September 5-6, 2015 in Kyoto, Japan. This manuscript presents a summary of the progress in experiments and modeling among ECN contributors leading to a better understanding of soot formation under the ECN “Spray A” configuration and some parametric variants. Relevant published and unpublished work from prior ECN workshops is reviewed. Experiments measuring soot particle size and morphology, soot volume fraction (fv), and transient soot mass have been conducted at various international institutions providing target data for improvements to computational models. Multiple modeling contributions using both the Reynolds Averaged Navier-Stokes (RANS) Equations approach and the Large-Eddy Simulation (LES) approach have been submitted. Among these, various chemical mechanisms, soot models, and turbulence-chemistry interaction (TCI) methodologies have been considered.

Compared to the gasoline engine, the diesel engine has the advantage of being more efficient and hence achieving a reduction of CO₂ levels. Unfortunately, particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines are high. To overcome these drawbacks, several new combustion concepts have been developed, including the PCCI (Premixed Charge Compression Ignition) combustion mode. This strategy allows a simultaneous reduction of NOx and soot emissions through the reduction of local combustion temperatures and the enhancement of the fuel/air mixing. In spite of PCCI benefits, the concept is characterized by its high combustion noise levels. Currently, a promising way to improve the PCCI disadvantages is being investigated. It is related with the use of low cetane fuels such as gasoline and diesel-gasoline blends.

A commercially available fuel, E85, a blend of ~85% ethanol and ~15% gasoline, can be a viable substitute for fossil fuels in internal combustion engines in order to achieve a reduction of the greenhouse gas (GHG) emissions. Ethanol is traditionally made of biomass, which makes it a part of the food-feed-fuel competition. New processes that reuse waste products from other industries have recently been developed, making ethanol a renewable and sustainable second-generation fuel. So far, work on E85 has focused on spark ignition (SI) concepts due to high octane rating of this fuel. There is very little research on its application in CI engines. Alcohols are known for low soot particle emissions, which gives them an advantage in the NOx-soot trade-off of the compression ignition (CI) concept.

The Engine Combustion Network (ECN) is a coordinate effort from research partners from all over the world which aims at creating a large experimental database to validate CFD calculations. Two injectors from ECN, namely Spray C and D, have been compared in a constant pressure flow vessel, which enables a field of view of more than 100 mm. Both nozzles have been designed with similar flow metrics, with Spray D having a convergent hole shape and Spray C a cylindrical one, the latter being therefore more prone to cavitation. Although the focus of the study is on reacting conditions, some inert cases have also been measured. High speed schlieren imaging, OH* chemiluminescence visualization and head-on broadband luminosity have been used as combustion diagnostics to evaluate ignition delay, lift off length and reacting tip penetration. Parametric variations include ambient temperature, oxygen content and injection pressure variations.

Visualization of single-hole nozzles into quiescent ambient has been used extensively in the literature to characterize spray mixing and combustion. However in-cylinder flow may have some meaningful impact on the spray evolution. In the present work, visualization of direct diesel injection spray under both non-reacting and reacting operating conditions was conducted in an optically accessible two-stroke engine equipped with a single-hole injector. Two different high-speed imaging techniques, Schlieren and UV-Light Absorption, were applied here to quantify vapor penetration for non-reacting spray. Meanwhile, Mie-scattering was used to measure the liquid length. As for reacting conditions, Schlieren and OH* chemiluminescence were simultaneously applied to obtain the spray tip penetration and flame lift-off length under the same TDC density and temperature. Additionally, PIV was used to characterize in-cylinder flow motion.

In order to face the new challenges, spark ignition engines are evolving by following some strategies and technologies. Among them, alternative combustion processes based on the dilution of the homogeneous mixture, either with fresh air or with Exhaust Gas Recirculation (EGR), are being explored. In a higher or lower extent, these changes modify in-cylinder thermodynamic conditions during the engine operation (pressure, temperature and gas composition) thus conditioning the spark ignition system requirements that will have to evolve to become more reliable and powerful. In this framework, an experimental study on the effect of the key in-cylinder conditions on the ignition system performance has been carried out in a single-cylinder spark-ignition (SI) research engine. The study includes EGR, lambda and energizing time sweeps to assess the behavior of the engine in different operating conditions.

Plug-in Hybrid Electric Vehicles (PHEVs) can be considered as the most promising technology to achieve the European CO2 targets together with a moderate infrastructure modification. However, the real benefits, in terms of CO2 emissions, depend on a great extent on the energy source (fuel and electricity mix), user responsibility, and vehicle design. Moreover, the electrification of the powertrain does not reduce other emissions as NOx and particulate matter (mainly soot). In the last years, low temperature combustion (LTC) modes as the reactivity controlled compression ignition (RCCI) have shown to achieve ultra-low NOx and soot emissions simultaneously due to the use of two fuels with different reactivity together with high exhaust gas recirculation (EGR) rates. Therefore, the aim of this work is to assess, through numerical simulations fed with experimental results, the effects of different energy sources on the performance and emissions of a series RCCI PHEV.

In recent decades, the importance of emerging alternative fuels has increased significantly as a solution to the problems of global warming and air pollution from energy production. In this context, ammonia (NH3) is seen as a potential option and energy vector that may be able to overcome the technical challenges associated with the use of other carbon-free fuels such as hydrogen (H2) in internal combustion engines (ICE). In this research, a numerical methodology for evaluating the impact of using ammonia as a fuel for spark-ignition ICEs has been developed. A combination of a single-cylinder and multi-cylinder numerical experiments has been performed to identify the main challenges and determine correct engine configuration. In addition, the performance of the engine has been evaluated through standard homologation driving cycles, contrasting it with other alternative propulsion configurations.

Recent studies have shown that the use of highly premixed dual fuel combustion reduces pollutant emissions and fuel consumption in CI engines. The most common strategy for dual fueling is to use two injection systems. Port fuel injection for low reactivity fuel and direct injection for high reactivity fuel. This strategy implies some severe shortcomings for its real implementation in passenger cars such as the use of two fuel tanks. In this sense, the use of a single injection system for dual fueling could solve this drawback trying to maintain pollutant and efficiency benefits. Nonetheless, when single injection system is used, the spray characteristics become an essential issue. In this work the fundamental characteristics of dual-fuel sprays with a single injection system under non-evaporating engine-like conditions are presented.

Fleet electrification has been demonstrated as a feasible solution to decarbonize the heavy-duty transportation sector. The combination of hybridization and advanced combustion concepts may provide further advantages by also introducing reductions on criteria pollutants such as nitrogen oxides and soot. In this scenario, the interplay among the different energy paths must be understood and quantified to extract the full potential of the powertrain. One of the key devices in such powertrains is the battery, which involves different aspects regarding operation, safety, and degradation. Despite this complexity, most of the models still rely on resistance-capacity models to describe the battery operation. These models may lead to unpractical results since the current flow is governed by limiters rather than physical laws. Additionally, phenomena related with battery degradation, which decreases the nominal capacity and enhances the heat generation are also not considered in this approach.

This work contributes to the understanding of physical mechanisms that control flashback, or more appropriately combustion recession, in diesel sprays. A large dataset, comprising many fuels, injection pressures, ambient temperatures, ambient oxygen concentrations, ambient densities, and nozzle diameters is used to explore experimental trends for the behavior of combustion recession. Then, a reduced-order model, capable of modeling non-reacting and reacting conditions, is used to help interpret the experimental trends. Finally, the reduced-order model is used to predict how a controlled ramp-down rate-of-injection can enhance the likelihood of combustion recession for conditions that would not normally exhibit combustion recession. In general, fuel, ambient conditions, and the end-of-injection transient determine the success or failure of combustion recession.

A comparison of the flame structure for two different fuels, dodecane and oxymethylene dimethyl ether (OMEX), has been performed under condition of Spray A of the Engine Combustion Network (ECN). The experiments were carried out in a constant pressure vessel with wide optical access, at high pressure and temperature and controlled oxygen concentration. The flame structure analysis has been performed by measuring the formaldehyde and OH radical distributions using planar Laser-Induced Fluorescence (PLIF) techniques. To complement the analysis, this information was combined with that obtained with high-speed imaging of OH* chemiluminescence radiation in the UV. Formaldehyde molecules are excited with the 355-nm radiation from the third harmonic of a Nd:YAG laser, whilst OH is excited with a wavelength of 281.00-nm from a dye laser.

The dense spray region in the near-field of diesel fuel injection remains an enigma. This region is difficult to interrogate with light in the visible range and difficult to model due to the rapid interaction between liquid and gas. In particular, modeling strategies that rely on Lagrangian particle tracking of droplets have struggled in this area. To better represent the strong interaction between phases, Eulerian modeling has proven particularly useful. Models built on the concept of surface area density are advantageous where primary and secondary atomization have not yet produced droplets, but rather form more complicated liquid structures. Surface area density, a more general concept than Lagrangian droplets, naturally represents liquid structures, no matter how complex. These surface area density models, however, have not been directly experimentally validated in the past due to the inability of optical methods to elucidate such a quantity.

The increasingly stringent emissions regulations together with the demand of highly efficient vehicles from the customers, lead to rapid developments of distinct powertrain solutions, especially when the electrification is present in a certain degree. The combination of electric machines with conventional powertrains diversifies the powertrain architectures and brings the opportunity to save energy in greater extents. On the other hand, alternative combustion modes as reactivity controlled compression ignition (RCCI) have shown to provide simultaneous ultra-low NOx and soot emissions with similar or better thermal efficiency than conventional diesel combustion (CDC). In addition, it is necessary to introduce more renewable fuels as ethanol to reduce the total CO2 emitted to the atmosphere, also called well-to-wheel (WTW) emission, in the transport sector.

The need to control global warming by regulating automotive emission levels has led to a lot of changes in the policies of different countries globally, specifically the United States (US) and the European Union (EU). More recently, the governments have been strongly pushing the integration of Electric Vehicles (EVs) in the market to replace the conventional Internal Combustion Engine (ICE) vehicles for CO₂ emissions reduction, with the enforcement of 50% EV sales by 2030 in the US and complete 100% by 2035 in the EU for passenger cars. However, these policies are misleading by considering EVs as zero emission vehicles, as there is no such technology yet available that has zero emissions during its lifecycle. During the manufacturing phase, any vehicle produced gives out emissions, with EVs emitting even higher than the conventional ICE vehicles with their battery manufacturing.

Reactivity controlled compression ignition (RCCI) combustion has demonstrated to be able to avoid the NOx-soot trade-off appearing during conventional diesel combustion (CDC), with similar or better thermal efficiency than CDC under a wide variety of engine platforms. However, a major challenge of this concept comes from the high hydrocarbon (HC) and carbon monoxide (CO) emission levels, which are orders of magnitude higher than CDC and similar to those of port fuel injected (PFI) gasoline engines. The higher HC and CO emissions combined with the lower exhaust temperatures during RCCI operation present a challenge for current exhaust aftertreatment technologies. RCCI has been successfully implemented on different compression ignition engine platforms with only minor modifications on the combustion system to include a PFI for feeding the engine with the low reactivity fuel.

Methanol is currently being evaluated as a promising alternative fuel for internal combustion engines, due to being attainable by carbon neutral or negative pathways (renewable energy and carbon capture technology). The low ignitability of methanol has made it attractive mostly as a fuel for spark ignition engines, however the low sooting properties of the fuel could potentially reduce the NOx-soot tradeoff present in compression ignition engines. In this work, using a 4-cylinder engine with compression ratio modified from 16:1 to 19:1, methanol combustion is evaluated under five operating conditions in terms of fuel consumption, criteria pollutants, CO2 emissions and engine efficiency in addition to the qualitative assessment of the combustion stability. It was found that combustion is stable at medium to high loads, with medium load NOx emissions levels at least 30% lower than the original diesel engine and comparable emissions at maximum load conditions.

Ever decreasing permitted emission levels and the necessity of more efficient engines demand a better understanding of in-cylinder phenomena. In swirl-supported compression ignition (CI) engines, mean in-cylinder flow structures formed during the intake stroke deeply influence mixture preparation prior to combustion, heat transfer and pollutant oxidation all of which could potentially improve engine performance. Therefore, the ability to characterize these mean flow structures is relevant for achieving performance improvements. CI mean flow structure is mainly described by a precessing vortex. The location of the vortex center is key for the characterization of the flow structure. Consequently, this work aims at evaluating algorithms that allow for the location of the vortex center both, in ensemble-averaged velocity fields and in instantaneous velocity fields.

De-fossilization is an increasingly important trend in the energy sector. In the transport sector the de-fossilization efforts have been centered in promoting the electrification of vehicles, nonetheless other pathways, like the use of carbon neutral or carbon-offsetting fuels under current vehicle fleets, are also worth considering. Low-carbon fuels (LCF) can be synthetized from sources that can take advantage of the carbon already present in the atmosphere (either by technologies like direct carbon capture or biological processes like photosynthesis in biofuels) and use energy from renewable sources for the necessary industrial processes. Although, LCFs can be compared to fossil fuels as energy sources for internal combustion engines, their composition is not the same and their properties can modify the engine combustion and emissions.