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In order to reduce both polluting emissions and fuel costs, many countries allow mixing ethanol to gasoline either in fixed percentages or in variable percentages. The resulting fuel is labeled E10 or E22, where the number specifies the ethanol percentage. This operation significantly changes way the stoichiometric value, which is the air-to-fuel mass ratio theoretically needed to completely burn the mixture. Ethanol concentration must be correctly estimated by the Engine Management System to optimally control exhaust emissions, fuel economy and engine performance. In fact, correct fuel quality recognition allows estimating the actual stoichiometric value, thus allowing the catalyst system to operate at maximum efficiency in any engine working point. Moreover, also other essential engine control functions should be adapted in real time by taking into account the quality of the fuel that is being used.