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Alternative and oxygenated fuels are nowadays being studied in order to increase engine efficiency and reduce exhaust emissions and also to limit the automotive industry's economical dependency from crude oil. These fuels are considered more ecological compared to hydrocarbons because they are obtained using renewable sources. Fuels like anhydrous/hydrous ethanol, methanol or alcohol/gasoline blends which are injected in liquid form must vaporize quickly, especially in direct injection engines, therefore their volatility is a very important factor and strongly depends on thermodynamic conditions and chemical properties. When a multi-component fuel blend is injected into a low pressure environment below its saturation pressure, a rapid boiling of the most volatile component triggers a thermodynamic atomization mechanism. These kinds of sprays show smaller droplets and lower penetration compared to mechanical break up.