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With the rapid growth of biodiesel production, it is prudent to research ways to improve its operation and performance in an engine, especially concerning fuel economy and exhaust emissions. This requires a thorough understanding of both the biodiesel production and engine operating processes. Completion of a published study of the impact of biodiesel fuel properties on engine operation indicated that it is difficult to draw conclusions about the exact causes of increased NOx emissions with respect to biodiesel properties without the capability of measuring engine cylinder pressures. As improvements were made to the authors' laboratory, a system to monitor and record pressure inside a diesel engine during operation was constructed to test dissimilar fuels. In the current work, three different fuels were tested in order to investigate combustion phasing, emissions, and fuel consumption as a function of fuel properties such as density, viscosity, Cetane Number, and energy content.

In-cylinder engine modeling is a necessary aspect of combustion research. In particular, simulating heat release connects variable combustion behavior to fuel properties through the 1st Law of Thermodynamics. One extension of such models is to evaluate changes to in-cylinder behavior using the Second Law of Thermodynamics in order to identify the peak period of availability for work extraction. Thus, Second Law models are a useful tool to augment research into alternative fuel usage and optimization. These models also help identify internal irreversibilities that are separate from heat transfer and exhaust gas losses. This study utilizes a multi-zone 1st and 2nd Law Heat Release model to characterize the changes in combustion behavior of a number of neat fuels used in a single-cylinder compression ignition (CI) engine.

As climate change drives the exploration into new and alternative fuels, biodiesel has emerged as a promising alternative to traditional diesel fuel. To further increase the viability of biodiesel, a unique system at the University of Kansas utilizes glycerin, the primary byproduct of biodiesel production, for power generation. This system converts glycerin into a hydrogen-rich gas (syngas) that is sent to an engine-generator system in one continuous flow process. The current setup allows for running the engine-generator system on pure propane, reformed propane, or reformed glycerin, with each fuel serving a unique purpose. This paper discusses upgrades in pure propane operation that serves the intent of preheating the engine prior to syngas operation and establishing the baseline energy requirement for fueling the system.

Alternative fuels based on biomass have typically been specified in ways which substantially limit allowable compositions. These specifications are unlike those for petroleum based fuels which include mixtures comprised of hundreds of different compounds. Such narrow biofuel specifications are clearly disadvantageous by restricting any flexibility of using different biofuels to minimize costs and offset price fluctuations. This paper focuses on critical performance criteria for diesel fuels and provides experimental data on several, non-conventional biofuels. Experimental data includes the physical properties and ignition delay times of new, lower cost sugar formulations. The objective of this work is to develop specifications on volumetric heating value, viscosity, and ignition properties as well as other properties for compression ignition biofuels. Proposed fuel specifications would not include compositions, thereby allowing a variety of feedstocks to be used.

Utilizing a higher compression ratio in a Compression Ignition (CI) engine grants an obvious advantage of improved thermal efficiency. However, the resulting combustion temperatures promote dissociation ensuing in increased nitrogen oxide (NOx) emissions. Unfortunately, due to the inherent properties of CI combustion, it is difficult to achieve simultaneous reduction of NOx and particulate matter (PM) through conventional combustion methods. Taking a different route though accomplishing Homogeneous Charge Compression Ignition (HCCI) in CI engines will largely eliminate NOx and PM; however, combustion can result in a significant increase in hydrocarbon (HC) and carbon monoxide (CO) emissions due to the low volatility of diesel fuel. Hence, this work attempts another avenue of Low Temperature Combustion (LTC) by employing Pre-mixed Charge Compression Ignition (PCI) combustion on a comparatively higher compression ratio (21.2) single cylinder CI engine.

The Partnership for a New Generation Vehicle (PNGV) is in the midst of narrowing technology options for our new generation of automobiles, and one technology which has appeal to the major auto-makers is the use of advanced compression-ignition engines. Ford has announced that the Synergy 2010 concept car (new version of Ford Taurus) would have a 20 1 compression-ratio, compression-ignition engine with preferred fuels including gasoline, diesel, and methanol. At these conditions, cetane improvers are necessary for the optimal performance of methanol and gasoline. In general, cetane improver technology has an important role in PNGV fuels, cleaner burning diesel, and current premium diesel markets. This paper reviews published data on cetane improvers including nitrates, peroxides, amines, and soluble metal-based catalysis. In addition, methods relating cetane numbers, blending cetane numbers, and ignition delay times are reviewed.

The use of Compressed Natural Gas (CNG) has demonstrated the potential to decrease Particulate Matter (PM) and nitrogen oxide (NOx) emissions simultaneously when used in a dual-fuel application with diesel fuel functioning as the ignition source. However, some authors do find that NOx emissions can increase. One postulation is that the conflicting results in the literature may be due to the difference in composition of natural gas around the world. Therefore, in order to investigate if CNG composition influences combustion performance and emissions, four unique mixtures of CNG were tested (i.e., 87% to 96% methane) while minimizing the combined difference of the density, heating value, and constant pressure specific heat of each mixture. This was accomplished at moderate energy substitution ratios (up to 40%) in a single cylinder engine operating at various loads.

Selective Catalytic Reduction (SCR) catalysts used in Lean NOx Trap (LNT) - SCR exhaust aftertreatment systems typically encounter alternating oxidizing and reducing environments. Reducing conditions occur when diesel fuel is injected upstream of a reformer catalyst, generating high concentrations of hydrogen (H₂), carbon monoxide (CO), and hydrocarbons to deNOx the LNT. In this study, the functionality of an iron (Fe) zeolite SCR catalyst is explored with a bench top reactor during steady-state and cyclic transient SCR operation. Experiments to characterize the effect of an LNT deNOx event on SCR operation show that adding H₂ or CO only slightly changes SCR behavior with the primary contribution being an enhancement of nitrogen dioxide (NO₂) decomposition into nitric oxide (NO). Exposure of the catalyst to C₃H₆ (a surrogate for an actual exhaust HC mixture) leads to a significant decrease in NOx reduction capabilities of the catalyst.