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Technical Paper

Clean and Cost-effective Dry Boundary Lubricants for Aluminum Forming

1998-02-23
980453
Preliminary research in our laboratory has demonstrated that boric acid is an effective lubricant with an unusual capacity to reduce the sliding friction (providing friction coefficients as low as 0.02) and wear of metallic and ceramic materials. More recent studies have revealed that water or methanol solutions of boric acid can be used to prepare strongly bonded layers of boric acid on aluminum surfaces. It appears that boric acid molecules have a strong tendency to bond chemically to the naturally oxidized surfaces of aluminum and its alloys and to make these surfaces very slippery. Recent metal-formability tests indicated that the boric acid films applied to aluminum surfaces worked quite well, improving draw scale performance by 58 to 75%.
Technical Paper

Development in Lost Foam Casting of Magnesium

2003-03-03
2003-01-0821
Preliminary work was conducted in the casting of magnesium using the lost foam casting process. The lost foam or expendable pattern casting (EPC) process is capable of making extremely complicated part shapes at acceptable soundness levels and with low manufacturing costs. Standard test shapes were used to determine the ability of the magnesium to fill the mold and to assess the types of defects encountered. This paper will briefly explain how this project evolved including the developmental strategies formed, the products selected, the casting trials performed, and the casting results.
Technical Paper

Diffusive Sampling of US Navy Submarine Atmospheres

2002-07-15
2002-01-2297
The atmospheres of US Navy Submarines are unique closed environments in which sailors both live and work for extended periods. Although this atmosphere is continuously monitored with a real-time, mass spectrometer-based Central Atmosphere Monitoring System (CAMS), the ability to measure trace constituents is limited. The identity, concentrations and distributions of trace constituents have been studied more exhaustively, in some cases for as long as the duration of a patrol, using conventional active air sampling methods such as passivated stainless steel canisters and solid sorbent tubes. The results from these studies indicate that trace constituents are generally present at concentrations well below levels that would present health concerns. However, these studies also show that there is a fairly wide variation in such levels over time, operational conditions, submarine and class of submarine.
Journal Article

Durability Study of a High Pressure Common Rail Fuel Injection System Using Lubricity Additive Dosed Gasoline-Like Fuel - Additional Cycle Runtime and Teardown Analysis

2019-04-02
2019-01-0263
This study is a continuation of previous work assessing the robustness of a Cummins XPI common rail injection system operating with gasoline-like fuel. All the hardware from the original study was retained except for the high pressure pump head and check valves which were replaced due to cavitation damage. An additional 400 hour NATO cycle was run on the refurbished fuel system to achieve a total exposure time of 800 hours and detect any other significant failure modes. As in the initial investigation, fuel system parameters including pressures, temperatures and flow rates were logged on a test bench to monitor performance over time. Fuel and lubricant samples were taken every 50 hours to assess fuel consistency, metallic wear, and interaction between fuel and oil. High fidelity driving torque and flow measurements were made to compare overall system performance when operating with both diesel and light distillate fuel.
Technical Paper

Engine Friction and Wear Performances with Polyalkylene Glycol Engine Oils

2016-10-17
2016-01-2271
The application of polyalkylene glycol (PAG) as a base stock for engine oil formulation has been explored for substantial fuel economy gain over traditional formulations with mineral oils. Various PAG chemistries were explored depending on feed stock material used for manufacturing. All formulations except one have the same additive package. The friction performance of these oils was evaluated in a motored single cylinder engine with current production engine hardware in the temperature range 40°C-120°C and in the speed range of 500 RPM-2500 RPM. PAG formulations showed up to 50% friction reduction over GF-5 SAE 5W-20 oil depending on temperature, speed, and oil chemistry. Friction evaluation in a motored I-4 engine showed up to 11% friction reduction in the temperature range 40°C-100°C over GF-5 oil. The paper will share results on ASTM Sequence VID fuel economy, Sequence IVA wear, and Sequence VG sludge and varnish tests. Chassis roll fuel economy data will also be shared.
Journal Article

Lignin-Derived Carbon Fiber as a Co-Product of Refining Cellulosic Biomass

2014-01-15
2013-01-9092
Lignin by-products from biorefineries has the potential to provide a low-cost alternative to petroleum-based precursors to manufacture carbon fiber, which can be combined with a binding matrix to produce a structural material with much greater specific strength and specific stiffness than conventional materials such as steel and aluminum. The market for carbon fiber is universally projected to grow exponentially to fill the needs of clean energy technologies such as wind turbines and to improve the fuel economies in vehicles through lightweighting. In addition to cellulosic biofuel production, lignin-based carbon fiber production coupled with biorefineries may provide $2,400 to $3,600 added value dry Mg−1 of biomass for vehicle applications. Compared to producing ethanol alone, the addition of lignin-derived carbon fiber could increase biorefinery gross revenue by 30% to 300%.
Technical Paper

Low-Friction Coatings for Air Bearings in Fuel Cell Air Compressors

2000-04-02
2000-01-1536
In an effort to reduce fuel consumption and emissions, hybrid vehicles incorporating fuel cell systems are being developed by automotive manufacturers, their suppliers, federal agencies (specifically, the U.S. Department of Energy) and national laboratories. The fuel cell system will require an air management subsystem that includes a compressor/expander. Certain components in the compressor will require innovative lubrication technology in order to reduce parasitic energy losses and improve their reliability and durability. One such component is the air bearing for air turbocompressors designed and fabricated by Meruit, Inc. Argonne National Laboratory recently developed a carbon-based coating with low friction and wear attributes; this near-frictionless-carbon (NFC) coating is a potential candidate for use in turbocompressor air bearings. We presents here an evaluation of the Argonne coating for air compressor thrust bearings.
Technical Paper

Modeling of Failure Modes Induced by Plastic Strain Localization in Dual Phase Steels

2008-04-14
2008-01-1114
Microstructure level inhomogeneities between the harder martensite phase and the softer ferrite phase render the dual phase (DP) steels more complicated failure mechanisms and associated failure modes compared to the conventionally used low alloy homogenous steels. This paper examines the failure mode DP780 steel under different loading conditions using finite element analyses on the microstructure levels. Micro-mechanics analyses based on the actual microstructures of DP steel are performed. The two-dimensional microstructure of DP steel was recorded by scanning electron microscopy (SEM). The plastic work hardening properties of the ferrite phase was determined by the synchrotron-based high-energy X-ray diffraction technique. The work hardening properties of the martensite phase were calibrated and determined based on the uniaxial tensile test results. Under different loading conditions, different failure modes are predicted in the form of plastic strain localization.
Technical Paper

Near-Frictionless Carbon Coatings for Use in Fuel Injectors and Pump Systems Operating with Low-Sulfur Diesel Fuels

2000-03-06
2000-01-0518
While sulfur in diesel fuels helps reduce friction and prevents wear and galling in fuel pump and injector systems, it also creates environmental pollution in the form of hazardous particulates and SO2 emissions. The environmental concern is the driving force behind industry's efforts to come up with new alternative approaches to this problem. One such approach is to replace sulfur in diesel fuels with other chemicals that would maintain the antifriction and antiwear properties provided by sulfur in diesel fuels while at the same time reducing particulate emissions. A second alternative might be to surface-treat fuel injection parts (i.e., nitriding, carburizing, or coating the surfaces) to reduce or eliminate failures associated with the use of low-sulfur diesel fuels. Our research explores the potential usefulness of a near-frictionless carbon (NFC) film developed at Argonne National Laboratory in alleviating the aforementioned problems.
Journal Article

Recent Developments in X-ray Diagnostics for Cavitation

2015-04-14
2015-01-0918
Cavitation plays an important role in fuel injection systems. It alters the nozzle's internal flow structure and discharge coefficient, and also contributes to injector wear. Quantitatively measuring and mapping the cavitation vapor distribution in a fuel injector is difficult, as cavitation occurs on very short time and length scales. Optical measurements of transparent model nozzles can indicate the morphology of large-scale cavitation, but are generally limited by the substantial amount of scattering that occurs between vapor and liquid phases. These limitations can be overcome with x-ray diagnostics, as x-rays refract, scatter and absorb much more weakly from phase interfaces. Here, we present an overview of some recent developments in quantitative x-ray diagnostics for cavitating flows. Measurements were conducted at the Advanced Photon Source at Argonne National Laboratory, using a submerged plastic test nozzle.
Technical Paper

Separation Techniques for Auto Shredder Residue

1991-02-01
910854
Disposal of automobile shredder residue (ASR), remaining from the reclamation of steel from junked automobiles, promises to be an increasing environmental and economic concern. Argonne National Laboratory (ANL) is investigating alternative technology for recovering value from ASR while also, it is hoped, lessening landfill disposal concerns. Of the ASR total, some 20% by weight consists of plastics. Preliminary work at ANL is being directed toward developing a protocol, both mechanical and chemical (solvent dissolution), to separate and recover polyurethane foam and the major thermoplastic fraction from ASR. Feasibility has been demonstrated in laboratory-size equipment.
Technical Paper

Ultrafast X-Ray Phase-Enhanced Microimaging for Visualizing Fuel Injection Process

2005-09-11
2005-24-093
Propagation-based and phase-enhanced x-ray imaging was developed as a unique metrology technique to visualize the internal structure of high-pressure fuel injection nozzles. We have visualized the microstructures inside 200-μm fuel injection nozzles in a 3-mm-thick steel housing using this novel technique. Furthermore, this new x-ray-based metrology technique has been used to directly study the highly transient needle motion in the nozzles in situ and in real-time, which is virtually impossible by any other means. The needle motion has been shown to have the most direct effect on the fuel jet structure and spray formation immediately outside of the nozzle. In addition, the spray cone-angle has been perfectly correlated with the numerically simulated fuel flow inside the nozzle due to the transient nature of the needle during the injection.
Journal Article

X-ray Imaging of Cavitation in Diesel Injectors

2014-04-01
2014-01-1404
Cavitation plays a significant role in high pressure diesel injectors. However, cavitation is difficult to measure under realistic conditions. X-ray phase contrast imaging has been used in the past to study the internal geometry of fuel injectors and the structure of diesel sprays. In this paper we extend the technique to make in-situ measurements of cavitation inside unmodified diesel injectors at pressures of up to 1200 bar through the steel nozzle wall. A cerium contrast agent was added to a diesel surrogate, and the changes in x-ray intensity caused by changes in the fluid density due to cavitation were measured. Without the need to modify the injector for optical access, realistic injection and ambient pressures can be obtained and the effects of realistic nozzle geometries can be investigated. A range of single and multi-hole injectors were studied, both sharp-edged and hydro-ground. Cavitation was observed to increase with higher rail pressures.
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