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The Selective Catalytic Reduction (SCR) system installed on the exhaust line is currently widely used on Diesel heavy-duty trucks and it is considered a promising technique for light and medium duty trucks, large passenger cars and off-highway vehicles, to fulfill future emission legislation. Some vehicles of these last categories, equipped with SCR, have been already put on the market, not only in the US, where the emission legislation on Diesel vehicles is more restrictive, but also in Europe, demonstrating to be already compliant with the upcoming Euro 6. Moreover, new and more stringent emission regulations and homologation cycles are being proposed all over the world, with a consequent rapidly increasing interest for this technology. As a matter of fact, a physical model of the Diesel Exhaust Fluid (DEF) supply system is very useful, not only during the product development phase, but also for the implementation of the on-board real-time controller.

While the Diesel Particulate Filter (DPF) is actually a quasi-standard equipment in the European Diesel passenger cars market, an interesting solution to fulfill NOx emission limits for the next EU 6 legislation is the application of a Selective Catalytic Reduction (SCR) system on the exhaust line, to drastically reduce NOx emissions. In this context, one of the main issues is the performance of the SCR system during cold start and warm up phases of the engine. The exhaust temperature is too low to allow thermal activation of the reactor and, consequently, to promote high conversion efficiency and significant NOx concentration reduction. This is increasingly evident the smaller the engine displacement, because of its lower exhaust system temperature (reduced gross power while producing the same net power, i.e., higher efficiency).