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Fuels are formulated by a variety of different components characterized by chemical and physical properties spanning a wide range of values. Changing the ratio between the mixture component molar fractions, it is possible to fulfill different requirements. One of the main properties that can be strongly affected by mixture composition is the volatility that represents the fuel tendency to vaporize. For example, changing the mixture ratio between alcohols and hydrocarbons, it is possible to vary the mixture saturation pressure, therefore the fuel vaporization ratio during the injection process. This paper presents a 1D numerical model to simulate the superheated injection process of a gasoline-ethanol mixture through real nozzle geometries. In order to test the influence of the mixture properties on flash atomization and flash evaporation, the simulation is repeated for different mixtures characterized by different gasoline-ethanol ratio.

In order to reduce both polluting emissions and fuel costs, many countries allow mixing ethanol to gasoline either in fixed percentages or in variable percentages. The resulting fuel is labeled E10 or E22, where the number specifies the ethanol percentage. This operation significantly changes way the stoichiometric value, which is the air-to-fuel mass ratio theoretically needed to completely burn the mixture. Ethanol concentration must be correctly estimated by the Engine Management System to optimally control exhaust emissions, fuel economy and engine performance. In fact, correct fuel quality recognition allows estimating the actual stoichiometric value, thus allowing the catalyst system to operate at maximum efficiency in any engine working point. Moreover, also other essential engine control functions should be adapted in real time by taking into account the quality of the fuel that is being used.

Alternative and oxygenated fuels are nowadays being studied in order to increase engine efficiency and reduce exhaust emissions and also to limit the automotive industry's economical dependency from crude oil. These fuels are considered more ecological compared to hydrocarbons because they are obtained using renewable sources. Fuels like anhydrous/hydrous ethanol, methanol or alcohol/gasoline blends which are injected in liquid form must vaporize quickly, especially in direct injection engines, therefore their volatility is a very important factor and strongly depends on thermodynamic conditions and chemical properties. When a multi-component fuel blend is injected into a low pressure environment below its saturation pressure, a rapid boiling of the most volatile component triggers a thermodynamic atomization mechanism. These kinds of sprays show smaller droplets and lower penetration compared to mechanical break up.