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This paper deals with the experimental and numerical investigation of a 2.0 litre single cylinder Heavy Duty Diesel Engine fuelled by natural gas and diesel oil in Dual Fuel mode. Due to the gaseous nature of the main fuel and to the high compression ratio of the diesel engine, reduced emissions can be obtained. An experimental study has been carried out at three different load level (25%, 50% and 75% of full engine load). Basing on experimental data, the authors recreated a 45° mesh sector of the engine cylinder and performed CFD simulations for the cases at 50% and 75% load levels. Numerical simulations were carried out on the 3D code Ansys FORTE. The aim of this work is to study combustion phenomena and, in particular, the interaction between natural gas and diesel oil, respectively represented by methane and n-dodecane. A reduced kinetic scheme for methane auto-ignition was implemented while for n-dodecane two set of reactions were utilised.