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A Mg-5.0wt.%Al-2.0wt.%Ca alloy (AC52) was cast at different cooling rates varying from 0.5 to 65 °C/s. The dendrites was characterized by determining the secondary dendrite arm spacing (SDAS) and the volume fraction of secondary eutectic phases with the linear intercept and point counting methods, respectively. The SDAS decreases significantly with increasing cooling rates, while the volume fraction of the eutectic phase increases from 10.8 ± 1.44 vol.% at 0.5 °C/s to 20.4 ± 1.52 vol.% at 20 °C/s. However, a further increase in cooling rate beyond 20 °C/s has limited influence on the volume fraction of eutectic phases. A large number of dispersed eutectic phases were observed in the primary α-Mg of the alloys cast at low cooling rates. Although, at the microscale, there were no dispersed eutectic phases in alloys cast at a high cooling rate of 30 °C/s, nanoscale eutectic phases were found by TEM observation.

Sliding wear of magnesium (Mg) engine cylinder bore surfaces and corrosion of Mg engine coolant channels are the two unsolved critical issues that automakers have to deal with in development of magnesium-intensive engines. In this paper, Plasma Electrolytic Oxidation (PEO) process was used to produce oxide coatings on AJ62 Mg alloy to provide wear and corrosion protection. In order to optimize the PEO process, orthogonal experiments were conducted to investigate the effect of PEO process parameters on the wear properties of PEO coatings. The PEO coatings showed a much better wear resistance, as well as a smaller friction coefficient, than the AJ62 substrate. The galvanic corrosion property of AJ62 Mg coupled with stainless steel and aluminum (Al) was investigated via immersion corrosion test in an engine coolant. Applying PEO coating on Mg can effectively prevent the galvanic corrosion attack to Mg.