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The fuel film thickness resulting from diesel fuel spray impingement was measured in a chamber at conditions representative of early injection timings used for low temperature diesel combustion. The adhered fuel volume and the radial distribution of the film thickness are presented. Fuel was injected normal to the impingement surface at ambient temperatures of 353 K, 426 K and 500 K, with densities of 10 kg/m3 and 25 kg/m3. Two injectors, with nozzle diameters of 100 μm and 120 μm, were investigated. The results show that the fuel film volume was strongly affected by the ambient temperature, but was minimally affected by the ambient density. The peak fuel film thickness and the film radius were found to increase with decreased temperature. The fuel film was found to be circular in shape, with an inner region of nearly constant thickness. The major difference observed with temperature was a decrease in the radial extent of the film.