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A procedure has been developed to build system level predictive models that incorporate physical laws as well as information derived from experimental data. In particular a soot model was developed, trained and tested using experimental data. It was seen that the model could fit available experimental data given sufficient training time. Future accuracy on data points not encountered during training was estimated and seen to be good. The approach relies on the physical phenomena predicted by an existing system level phenomenological soot model coupled with ‘weights’ which use experimental data to adjust the predicted physical sub-model parameters to fit the data. This approach has developed from attempts at incorporating physical phenomena into neural networks for predicting emissions. Model training uses neural network training concepts.

An engine cycle simulation code with detailed chemical kinetics has been developed to study Homogeneous Charge Compression Ignition (HCCI) combustion with hydrogen as the fuel. In order to attain adequate combustion duration, resulting from the self-accelerating nature of the chemical reaction, fuel and temperature inhomogeneities have been brought to the calculation by considering the combustion chamber to have various temperature and fuel distributions. Calculations have been done under various conditions including both perfectly homogeneous and inhomogeneous cases, changing the degree of inhomogeneity. The results show that intake gas temperature is more dominant on ignition timing of HCCI than equivalence ratio and that there is a possibility to control HCCI by introducing appropriate temperature inhomogeneity to in-cylinder mixture.

Three distinct types of diesel particulate matter (PM) are generated in selected engine operating conditions of a single-cylinder heavy-duty diesel engine. The three types of PM are trapped using typical Cordierite diesel particulate filters (DPF) with different washcoat formulations and a commercial Silicon-Carbide DPF. Two systems, an external electric furnace and an in-situ burner, were used for regeneration. Furnace regeneration experiments allow the collected PM to be classified into two categories depending on oxidation mechanism: PM that is affected by the catalyst and PM that is oxidized by a purely thermal mechanism. The two PM categories prove to contribute differently to pressure drop and transient filtration efficiency during in-situ regeneration.

An experimental study was performed to investigate diesel particulate filter (DPF) performance during filtration with the use of real-time measurement equipment. Three operating conditions of a single-cylinder 2.3-liter D.I. heavy-duty diesel engine were selected to generate distinct types of diesel particulate matter (PM) in terms of chemical composition, concentration, and size distribution. Four substrates, with a range of geometric and physical parameters, were studied to observe the effect on filtration characteristics. Real-time filtration performance indicators such as pressure drop and filtration efficiency were investigated using real-time PM size distribution and a mass analyzer. Types of filtration efficiency included: mass-based, number-based, and fractional (based on particle diameter). In addition, time integrated measurements were taken with a Rupprecht & Patashnick Tapered Element Oscillating Microbalance (TEOM), Teflon and quartz filters.

An investigation of several diesel injector nozzles that produced different engine emissions performance was performed. The nozzle styles used were two VCO type nozzles that were manufactured using two different techniques, and two mini-sac nozzles that provided comparison. Fired experiments were conducted on a Detroit Diesel Series 50 engine. Optical access was obtained by substituting a sapphire window for one exhaust valve. Under high speed, high load, retarded injection timing conditions, it was discovered that each nozzle produced different specific soot and NOx emissions. High-speed film images were obtained. It was discovered that the temperature and KL factor results from the 2-color optical pyrometry showed significant differences between the nozzles. The authors propose the possibility that differences in air entrainment, caused by potential differences in CD due to surface finish, may contribute to the variance in emissions performance.

An experimental study was performed to investigate the effect of fuel composition on combustion, gaseous emissions, and detailed chemical composition and size distributions of diesel particulate matter (PM) in a modern heavy-duty diesel engine with the use of the enhanced full-dilution tunnel system of the Engine Research Center (ERC) of the UW-Madison. Detailed description of this system can be found in our previous reports [1,2]. The experiments were carried out on a single-cylinder 2.3-liter D.I. diesel engine equipped with an electronically controlled unit injection system. The operating conditions of the engine followed the California Air Resources Board (CARB) 8-mode test cycle. The fuels used in the current study include baseline No. 2 diesel (Fuel A: sulfur content = 352 ppm), ultra low sulfur diesel (Fuel B: sulfur content = 14 ppm), and Fisher-Tropsch (F-T) diesel (sulfur content = 0 ppm).

An experimental study was carried out to investigate the effects of fuel injection timing on detailed chemical composition and size distributions of diesel particulate matter (PM) and regulated gaseous emissions in a modern heavy-duty D.I. diesel engine. These measurements were made for two different diesel fuels: No. 2 diesel (Fuel A) and ultra low sulfur diesel (Fuel B). A single-cylinder 2.3-liter D.I. diesel engine equipped with an electronically controlled unit injection system was used in the experiments. PM measurements were made with an enhanced full-dilution tunnel system at the Engine Research Center (ERC) of the University of Wisconsin-Madison (UW-Madison) [1, 2]. The engine was run under 2 selected modes (25% and 75% loads at 1200 rpm) of the California Air Resources Board (CARB) 8-mode test cycle.

Oxygen enhancement in a direct injection (DI) diesel engine was studied to investigate the potential for particulate matter and NOx emissions control. The local oxygen concentration within the fuel plume was modified by oxygen enrichment of the intake air and by oxygenating the base fuel with 20% methyl t-butyl ether (MTBE). The study collected overall engine performance and engine-out emissions data as well as in-cylinder two-color measurements at 25% and 75% loads over a range of injection timings. The study found oxygen enhancement, whether it be from intake air enrichment or via oxygenated fuels, reduces particulate matter, the effectiveness depending on the local concentration of oxygen in the fuel plume. Since NOx emissions depend strongly on the temperature and oxygen concentration throughout the bulk cylinder gas, the global thermal and dilution effects from oxygen enrichment were greater than that from operation on oxygenated fuel.

An investigation of the effect of microflow machining on the spray characteristics of diesel injectors was undertaken. A collection of four VCO injector tips were tested prior to and after an abrasive flow process using a high viscosity media. The injector nozzles were tested on a spray fixture. Rate of injection measurements and high-speed digital images were used for the quantification of the air entrainment rate. Comparisons of the spray characteristics and A/F ratios were made for conditions of before and after the abrasive flow process. Results showed a significant decrease in the injection-to-injection variability and improvement of the spray symmetry. A link between the quantity of air entrained and potential differences in spray plume internal chemical composition and temperature is proposed via equilibrium calculations.

A single cylinder, Cummins NH, direct-injection, diesel engine has been operated in order to evaluate the effects of aromatic content and aromatic structure on diesel engine particulates. Results from three fuels are shown. The first fuel, a low sulfur Chevron diesel fuel was used as a base fuel for comparison. The other fuels consisted of the base fuel and 10% by volume of 1-2-3-4 tetrahydronaphthalene (tetralin) a single-ring aromatic and naphthalene, a double-ring aromatic. The fuels were chosen to vary aromatic content and structure while minimizing differences in boiling points and cetane number. Measurements included exhaust particulates using a mini-dilution tunnel, exhaust emissions including THC, CO2, NO/NOx, O2, injection timing, two-color radiation, soluble organic fraction, and cylinder pressure. Particulate measurements were found to be sensitive to temperature and flow conditions in the mini-dilution tunnel and exhaust system.