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High-speed video of combustion processes and cylinder pressure traces were obtained from a single-cylinder optical-accessible engine with a production four-valve cylinder head to study the mixture formation and flame propagation characteristics at near-stoichiometric start condition. Laser-sheet Mie-scattering images were collected for liquid droplet distributions inside the cylinder to correlate the mixture formation process with the combustion results. A dual-stream (DS) injector and a quad-stream (QS) injector were used to study the spray dispersion effect on engine starting, under different injection timings, throttle valve positions, engine speeds, and intake temperatures. It was found that most of the fuel under open-valve injection (OVI) conditions entered the cylinder as droplet mist. A significant part of the fuel droplets hit the far end of the cylinder wall at the exhaust-valve side.