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A comprehensive biodiesel combustion model is presented for use in multi-dimensional engine simulations. The model incorporates realistic physical properties in a vaporization model developed for multi-component fuel sprays and applies an improved mechanism for biodiesel combustion chemistry. Previously, a detailed mechanism for methyl decanoate and methyl-9-decenoate was reduced from 3299 species to 85 species to represent the components of biodiesel fuel. In this work, a second reduction was performed to further reduce the mechanism to 69 species. Steady and unsteady spray simulations confirmed that the model adequately reproduced liquid penetration observed in biodiesel spray experiments. Additionally, the new model was able to capture expected fuel composition effects with low-volatility components and fuel blend sprays penetrating further.

Striving for sustainable transportation solutions, hydrogen is often identified as a promising energy carrier and internal combustion engines are seen as a cost effective consumer of hydrogen to facilitate the development of a large-scale hydrogen infrastructure. Driven by efficiency and emissions targets defined by the U.S. Department of Energy, a research team at Argonne National Laboratory has worked on optimizing a spark-ignited direct injection engine for hydrogen. Using direct injection improves volumetric efficiency and provides the opportunity to properly stratify the fuel-air mixture in-cylinder. Collaborative 3D-CFD and experimental efforts have focused on optimizing the mixture stratification and have demonstrated the potential for high engine efficiency with low NOx emissions. Performance of the hydrogen engine is evaluated in this paper over a speed range from 1000 to 3000 RPM and a load range from 1.7 to 14.3 bar BMEP.

Use of ethanol as gasoline replacement can contribute to the reduction of nitrogen oxide (NOx) and carbon oxide (CO) emissions. Depending on ethanol production, significant reduction of greenhouse-gas emissions is possible. Concentration of certain species, such as unburned ethanol and acetaldehyde in the engine-out emissions are known to rise when ratio of ethanol to gasoline increases in the fuel. This research explores on hydrous ethanol fueled port-fuel injection (PFI) spark ignition (SI) engine emissions that contribute to photochemical formation of ozone, or so-called ozone precursors and the precursor of peroxyacetyl nitrates (PANs). The results are compared to engine operation on gasoline. Concentration obtained by FTIR gas analyzer, and mass-specific emissions of formaldehyde (HCHO), acetaldehyde (MeCHO) and methane (CH4) under two engine speed, four load and two spark advance settings are analyzed and presented.

With an intention to improve the performance of reciprocating engines used for distributed generation US-Dept. of Energy has launched ARES program. Under this program, the performance targets for these natural gas-fuelled stationary engines are ≻ 50% efficiency and NOx emissions ≺ 0.1 g/bhp-hr by 2013. This paper presents two technologies developed under this program. Lean-burn operation is very popular with engine manufacturers as it offers simultaneous low-NOx emissions and high engine efficiencies, while not requiring the use of any aftertreatment devices. Though engines operating on lean-burn operation are capable of better performance, they are currently limited by the inability to sustain reliable ignition under lean conditions. Addressing such an issue, research has evaluated the use of laser ignition as an alternative to the conventional Capacitance Discharge Ignition (CDI).

The current paper describes a methodology for combustion bowl assessment for diesel engines. The methodology is based on the application of Computational Fluid Dynamics (CFD) following a Design of Experiments (DoE) procedure. In this work the 3D CFD simulation was performed by the commercial CFD code AVL-FIRE for different combustion bowls from intake valve closing (IVC) to exhaust valve opening (EVO). The initial conditions (at IVC) and boundary conditions were obtained from 1D simulation. Since the work was concentrated on the spray injection, mixing, combustion as well as bowl aerodynamics only a sector mesh was employed for the calculations. A DoE procedure was also used for this simulation work in order to minimize the number of simulation runs and at the same time maintaining the accuracy required assessing the influences of different bowl geometry, spray and intake air motion parameters.

The U.S. Renewable Fuel Standard (RFS2) requires an increase in the use of advanced biofuels up to 36 billion gallons by 2022. Longer chain alcohols, in addition to cellulosic ethanol and synthetic biofuels, could be used to meet this demand while adhering to the RFS2 corn-based ethanol limitation. Higher carbon number alcohols can be utilized to improve the energy content, knock resistance, and/or petroleum displacement of gasoline-alcohol blends compared to traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part I of this paper focuses on the development of scenarios by which to compare higher alcohol fuel blends to traditional ethanol blends. It also details the implementation of fuel property prediction methods adapted from literature. Possible combinations of eight alcohols mixed with a gasoline blendstock were calculated and the properties of the theoretical fuel blends were predicted.

Higher carbon number alcohols offer an opportunity to meet the Renewable Fuel Standard (RFS2) and improve the energy content, petroleum displacement, and/or knock resistance of gasoline-alcohol blends from traditional ethanol blends such as E10 while maintaining desired and regulated fuel properties. Part II of this paper builds upon the alcohol selection, fuel implementation scenarios, criteria target values, and property prediction methodologies detailed in Part I. For each scenario, optimization schemes include maximizing energy content, knock resistance, or petroleum displacement. Optimum blend composition is very sensitive to energy content, knock resistance, vapor pressure, and oxygen content criteria target values. Iso-propanol is favored in both scenarios' suitable blends because of its high RON value.

The CFR F1 engine is the standard testing apparatus used for rating the research octane number (RON) of gasoline fuels. Unlike the motor octane number (MON) method, where the intake port temperature after the carburetor is controlled by an electric heater, the mixture temperature can vary during the RON test due to the heat of vaporization (HoV) of the fuel. Ethanol is receiving increasing attention as a high octane and high HoV fuel component. This work presents an analysis of the combustion characteristics during the RON rating of ethanol fuel blends according to the standard ASTM D2699 method, highlighting the effects of ethanol concentration and base fuel composition. All fuels were blended to a constant RON of 98. Ethanol levels varied from 0 to 50 vol% and the base fuels were surrogate blends composed of primary reference fuels (PRF), toluene standardization fuels (TSF), and a four component gasoline surrogate.

SunDiesel fuel is a biomass-to-liquid (BTL) fuel that may have certain attributes different from conventional diesel. In this investigation, 100% SunDiesel was tested both in a Mercedes A-Class (MY1999) diesel vehicle and a single-cylinder heavy-duty compression-ignition direct-injection engine. The SunDiesel's emissions and fuel consumption were significantly better than conventional diesel fuel, especially in nitrogen oxides (NOx) reduction. In the vehicle U.S. Environmental Protection Agency (EPA), Federal Test Procedure 75 (FTP-75), and New European Drive Cycle (NEDC) tests, the carbon dioxide emissions on a mile basis (g/mile) from SunDiesel fuel were almost 10% lower than the conventional diesel fuel. Similarly, in the single-cylinder engine steady-state tests, the reductions in brake specific NOx, carbon monoxide (CO), and particulate matter (PM) are equally significant. Combustion analysis, though not conclusive, indicates that there are differences deserving further research.

The Center for Transportation Research (CTR) Vehicle Systems team modified a Nissan CK-2 Continuously Variable Transmission (CVT) for a diesel hybrid powertrain application. Mechanical and electrical modifications were made to the CVT, both internal and external to the transmission. The goal of this experiment was to investigate and demonstrate the potential of CVT for diesel engines hybrid electric vehicles (HEVs) in fuel economy and emissions. The test set-up consisted of a diesel engine coupled to an electric motor driving a Continuously Variable Transmission (CVT). This hybrid drive is connected to a dynamometer and a DC electrical power source creating a vehicle context by combining advanced computer models and emulation techniques. The experiment focuses on the impact particular transmission control strategies have on measured fuel economy and emissions specifically, nitrogen oxides (NOx) and particulate matter (PM).

The correlations between the physical properties and autoignition parameters of several alternate fuels have been examined. The fuels are DF-2 and its blends with petroleum derived fuels, coal derived fuels, shale derived fuels, high aromatic naphtha sun-flower oils, methanol and ethanol. A total of eighteen existing correlations are discussed. An emphasis is made on the suitability of each of the correlations for the development of electronic controls for diesel engines when run on alternate fuels. A new correlation has been developed between the cetane number of the fuels and its kinematic viscosity and specific gravity.

Detailed properties of particulate matter (PM) emissions from a gasoline direct injection (GDI) engine were analyzed in terms of size, morphology, and nanostructures, as gasoline and its ethanol blend E20 were used as a fuel. PM emissions were sampled from a 0.55L single-cylinder GDI engine by means of a scanning mobility particle sizer (SMPS) for size measurements and a self-designed thermophoretic sampling device for the subsequent analyses of size, morphology and nanostructures using a transmission electron microscope (TEM). The particle sizes were evaluated with variations of air-fuel equivalence ratio and fuel injection timing. The most important result from the SMPS measurements was that the number of nucleation-mode nanoparticles (particularly those smaller than 10 - 15 nm) increased significantly as the fuel injection timing was advanced to the end-of-injection angle of 310° bTDC.

Low temperature combustion through in-cylinder blending of fuels with different reactivity offers the potential to improve engine efficiency while yielding low engine-out NOx and soot emissions. A Navistar MaxxForce 13 heavy-duty compression ignition engine was modified to run with two separate fuel systems, aiming to utilize fuel reactivity to demonstrate a technical path towards high engine efficiency. The dual-fuel engine has a geometric compression ratio of 14 and uses sequential, multi-port-injection of a low reactivity fuel in combination with in-cylinder direct injection of diesel. Through control of in-cylinder charge reactivity and reactivity stratification, the engine combustion process can be tailored towards high efficiency and low engine-out emissions. Engine testing was conducted at 1200 rpm over a load sweep.

A multiple-injection combustion strategy has been developed for heated gasoline direct injection compression ignition (HGCI). Gasoline was injected into a 0.4L single cylinder engine at a fuel pressure of 300bar. Fuel temperature was increased from 25degC to a temperature of 280degC by means of electric injector heater. This approach has the potential of improving fuel efficiency, reducing harmful CO and UHC as well as particulate emissions, and reducing pressure rise rates. Moreover, the approach has the potential of reducing fuel system cost compared to high pressure (>500bar) gasoline direct injection fuel systems available in the market for GDI SI engines that are used to reduce particulate matter. In this study, a multiple injection strategy was developed using electric heating of the fuel prior to direct fuel injection at engine speed of 1500rpm and load of 12.3bar IMEP.

A novel, electronically controlled, common rail fuel injection system has been designed and developed by the authors under a contract from the National Renewable Energy Laboratory (NREL). This system was specifically designed for direct injection of liquid dimethyl ether (DME) to achieve ultra-low emissions of NOx & particulate matter from conventional diesel engines. However, the system's basic characteristics also make it suitable for direct injection of ethanol & methanol in compression-ignition engines, and direct injection of liquid propane and gasoline in spark-ignition engines.

The objective of this paper is to present the results of diesel exhaust aftertreatment testing and analysis done under the FreedomCAR program. Nitrogen Oxides (NOx) adsorber technology was selected based on a previous investigation of various NOx aftertreatment technologies including non-thermal plasma, NOx adsorber and active lean NOx. Particulate Matter (PM) emissions were addressed by developing a catalyzed particulate filter. After various iterations of the catalyst formulation, the aftertreatment components were integrated and optimized for a light duty vehicle application. This compact exhaust aftertreatment system is dual leg and consists of a sulfur trap, NOx adsorbers, and catalyzed particulate filters (CPF). During regeneration, supplementary ARCO ECD low-sulfur diesel fuel is injected upstream of the adsorber and CPF in the exhaust. Steady state and transient emission test results with and without the exhaust aftertreatment system (EAS) are presented.

The superior fuel economy of direct injection internal combustion engines (diesel and gasoline) is related to use of a high compression ratio to auto-ignite the fuel and the overall lean combustible mixture. Two of the major problems in diesel engine emissions are the NOx and soot emissions, which are caused by the heterogeneity of the charge and the properties of the diesel fuel. Conventional Direct Injection Spark Ignition Gasoline engines don't have these problems because of the fuel properties particularly its volatility. However, its efficiency and specific power output are limited by the knock, knock produced preignition and the sporadic preignition phenomenon. The Gasoline Direct Injection Compression Ignition (GDICI) engine combines the superior features of the two engines by increasing the compression ratio and use of gasoline as a fuel.

The potential exists to displace a portion of the petroleum diesel demand with butanol and positively impact engine-out particulate matter. As a preliminary investigation, 20% and 40% by volume blends of butanol with ultra low sulfur diesel fuel were operated in a 1999 Mercedes Benz C220 turbo diesel vehicle (Euro III compliant). Cold and hot start urban as well as highway drive cycle tests were performed for the two blends of butanol and compared to diesel fuel. In addition, 35 MPH and 55 MPH steady-state tests were conducted under varying road loads for the two fuel blends. Exhaust gas emissions, fuel consumption, and intake and exhaust temperatures were acquired for each test condition. Filter smoke numbers were also acquired during the steady-state tests. The results showed that for the urban drive cycle, both total hydrocarbon (THC) and carbon monoxide (CO) emissions increased as larger quantities of butanol were added to the diesel fuel.

The performance of the Common Rail diesel injection system (CRS) is investigated experimentally in a single cylinder engine and a test rig to determine the cycle-to-cycle variation in the injection pressure and its effects on the needle opening and rate of fuel delivery. The engine used is a single cylinder, simulated-turbocharged diesel engine. Data for the different injection and performance parameters are collected under steady state conditions for 35 consecutive cycles. Furthermore, a mathematical model has been developed to calculate the instantaneous fuel delivery rate at various injection pressures. The experimental results supported with the model computations indicated the presence of cycle-to-cycle variations in the fuel injection pressure and needle lift. The variations in the peak-cylinder gas pressure, rate of heat release, cylinder gas temperature and IMEP are correlated with the variation in the injection rate.

The effects of different blends of Soybean Methyl Ester (biodiesel) and ultra low sulfur diesel (ULSD) fuel: B-00 (ULSD), B-20, B-40, B-60, B-80 and B-100 (biodiesel); on autoignition, combustion, performance, and engine out emissions of different species including particulate matter (PM) in the exhaust, were investigated in a single-cylinder, high speed direct injection (HSDI) diesel engine equipped with a common rail injection system. The engine was operated at 1500 rpm under simulated turbocharged conditions at 5 bar IMEP load with varied injection pressures at a medium swirl of 3.77 w ithout EGR. Analysis of test results was done to determine the role of biodiesel percentage in the fuel blend on the basic thermodynamic and combustion processes under fuel injection pressures ranging from 600 bar to 1200 bar.