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Several mechanisms are discussed to understand the formation of both regulated and unregulated emissions in a high speed, direct injection, single cylinder diesel engine using low sulphur diesel fuel. Experiments were conducted over a wide range of injection pressures, EGR rates, injection timings and swirl ratios. The regulated emissions were measured by the standard emission equipment. Unregulated emissions such as aldehydes and ketones were measured by high pressure liquid chromatography and hydrocarbon speciation by gas chromatography. Particulate mass was measured with a Tapered Element Oscillating Microbalance (TEOM). Analysis was made of the sources of different emission species and their relationship with the combustion process under the different operating conditions. Special attention is given to the low temperature combustion (LTC) regime which is known to reduce both NOx and soot. However the HC, CO and unregulated emissions increased at a higher rate.

Engine-out HC emissions were investigated during cold and hot starts. The tests were conducted at room temperature, on a new Chrysler 2.4-L, 4-cylinder, 16-valve, DOHC, multipoint-port-fuel-injection gasoline engine. Real time engine-out HC emissions were measured using Cambustion Fast Response Flame Ionization Detector (FRFID). Sources of unburned hydrocarbon emissions were discussed in details. Unburned hydrocarbons emitted during the cold-start were much higher than the hot-start. Cylinder-to-cylinder variation was investigated. A fuel inventory program was used to characterize total injected fuel, burned fuel, unburned HC, and fuel unaccounted for (mainly accumulated fuel in the engine system and CO). A fuel interrupt test was run to examine the possibility of burning the leftover fuel after the fuel shut-off. The contribution of the cold and hot start modes in engine-out HC emissions was determined.

I The effect of Cetane Number (CN) of the fuel and the addition of cetane improvers on the cold starting and white smoke emissions of a diesel engine was investigated. Tests were conducted on a single-cylinder, four-stroke-cycle, air-cooled, direct-injection, stand-alone diesel engine in a cold room at ambient temperatures ranging from 25 °C to - 5 °C. Five fuels were used. The base fuel has a CN of 49.2. The CN of the base fuel was lowered to 38.7 and 30.8 by adding different amounts of aromatic hydrocarbons. Iso-octyl nitrate is added to the high aromatic fuels in order to increase their CN to 48.6 and 38.9 respectively. Comparisons are made between the five fuels to determine the effect of CN and the additive on cylinder peak pressure, heat release rate, cold start-ability, combustion instability, hydrocarbon emissions and solid and liquid particulates.

The emissions trade-off and combustion characteristics of a high speed, small-bore, direct injection, single cylinder, diesel engine are investigated at three different load conditions. The experiments covered a wide range of parameters including the injection pressure, exhaust gas recirculation (EGR) rate and swirl ratio (Sw). The effects of each parameter on the ignition delay (ID), apparent rate of energy release (ARER), NOx, Bosch smoke unit (BSU), CO and hydrocarbons are investigated. The results show that the NOx emission dropped continuously with the increase in EGR (up to 55%), but with increasing smoke emission in a classical trade-off relationship. The increase in injection pressure generally reduced smoke with NOx penalty; however, the NOx penalty decreased at higher EGR. There also appears to be an increase in the cool flame intensity at the high EGR rates. Applying swirl at high EGR rate and high injection pressure conditions further reduced smoke emissions.

Several mechanisms are discussed to understand the particulate matter (PM) characterization in a high speed, direct injection, single cylinder diesel engine using low sulfur diesel fuel. This includes their formation, size distribution and number density. Experiments were conducted over a wide range of injection pressures, EGR rates, injection timings and swirl ratios, therefore covering both conventional and low temperature combustion regimes. A micro dilution tunnel was used to immediately dilute a small part of the exhaust gases by hot air. A Scanning Mobility Particle Sizer (SMPS) was used to measure the particulate size distribution and number density. Particulate mass was measured with a Tapered Element Oscillating Microbalance (TEOM). Analysis was made of the root cause of PM characterization and their relationship with the combustion process under different operating conditions.