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Several mechanisms are discussed to understand the formation of both regulated and unregulated emissions in a high speed, direct injection, single cylinder diesel engine using low sulphur diesel fuel. Experiments were conducted over a wide range of injection pressures, EGR rates, injection timings and swirl ratios. The regulated emissions were measured by the standard emission equipment. Unregulated emissions such as aldehydes and ketones were measured by high pressure liquid chromatography and hydrocarbon speciation by gas chromatography. Particulate mass was measured with a Tapered Element Oscillating Microbalance (TEOM). Analysis was made of the sources of different emission species and their relationship with the combustion process under the different operating conditions. Special attention is given to the low temperature combustion (LTC) regime which is known to reduce both NOx and soot. However the HC, CO and unregulated emissions increased at a higher rate.

I The effect of Cetane Number (CN) of the fuel and the addition of cetane improvers on the cold starting and white smoke emissions of a diesel engine was investigated. Tests were conducted on a single-cylinder, four-stroke-cycle, air-cooled, direct-injection, stand-alone diesel engine in a cold room at ambient temperatures ranging from 25 °C to - 5 °C. Five fuels were used. The base fuel has a CN of 49.2. The CN of the base fuel was lowered to 38.7 and 30.8 by adding different amounts of aromatic hydrocarbons. Iso-octyl nitrate is added to the high aromatic fuels in order to increase their CN to 48.6 and 38.9 respectively. Comparisons are made between the five fuels to determine the effect of CN and the additive on cylinder peak pressure, heat release rate, cold start-ability, combustion instability, hydrocarbon emissions and solid and liquid particulates.

Several mechanisms are discussed to understand the particulate matter (PM) characterization in a high speed, direct injection, single cylinder diesel engine using low sulfur diesel fuel. This includes their formation, size distribution and number density. Experiments were conducted over a wide range of injection pressures, EGR rates, injection timings and swirl ratios, therefore covering both conventional and low temperature combustion regimes. A micro dilution tunnel was used to immediately dilute a small part of the exhaust gases by hot air. A Scanning Mobility Particle Sizer (SMPS) was used to measure the particulate size distribution and number density. Particulate mass was measured with a Tapered Element Oscillating Microbalance (TEOM). Analysis was made of the root cause of PM characterization and their relationship with the combustion process under different operating conditions.