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Acetone-Butanol-Ethanol (ABE), an intermediate product in the ABE fermentation process for producing bio-butanol, is considered a promising alternative fuel because it not only preserves the advantages of oxygenated fuel which typically emit less pollutants compared to conventional diesel, but also lowers the cost of fuel recovery for each individual component during the fermentation. With the development of advanced ABE fermentation technology, the volumetric percentage of acetone, butanol and ethanol in the bio-solvents can be precisely controlled. In this respect, it is desirable to estimate the performance of different ABE blends to determine the best blend and optimize the production process accordingly. ABE fuels with different component ratio, (A: B: E: 6:3:1; 3:6:1; 0:10:0, vol. %), were blended with diesel and tested in a constant volume chamber.

Use of ethanol as gasoline replacement can contribute to the reduction of nitrogen oxide (NOx) and carbon oxide (CO) emissions. Depending on ethanol production, significant reduction of greenhouse-gas emissions is possible. Concentration of certain species, such as unburned ethanol and acetaldehyde in the engine-out emissions are known to rise when ratio of ethanol to gasoline increases in the fuel. This research explores on hydrous ethanol fueled port-fuel injection (PFI) spark ignition (SI) engine emissions that contribute to photochemical formation of ozone, or so-called ozone precursors and the precursor of peroxyacetyl nitrates (PANs). The results are compared to engine operation on gasoline. Concentration obtained by FTIR gas analyzer, and mass-specific emissions of formaldehyde (HCHO), acetaldehyde (MeCHO) and methane (CH4) under two engine speed, four load and two spark advance settings are analyzed and presented.

Polyoxymethylene dimethyl ethers (PODEn) have high cetane number, high oxygen content and high volatility, therefore can be added to gasoline to optimize the performance and soot emission of Gasoline Compression Ignition (GCI) combustion. High speed imaging was used to investigate the spray and combustion process of gasoline/PODEn blends (PODEn volume fraction 0%-30%) under various ambient conditions and injection strategies in a constant volume vessel. Results showed that with an increase of PODEn proportion from 10% to 30%, liquid-phase penetration of the spray increased slightly, ignition delay decreased from 3.8 ms to 2.0 ms and flame lift off length decreased 29.4%, causing a significant increase of the flame luminance. For blends with 20% PODEn, when ambient temperature decreased from 893 K to 823 K, the ignition delay increased 1.3 ms and the flame luminance got lower.

Recent research has shown that butanol, instead of ethanol, has the potential of introducing a more suitable blend in diesel engines. This is because butanol has properties similar to current transportation fuels in comparison to ethanol. However, the main downside is the high cost of the butanol production process. Acetone-butanol-ethanol (ABE) is an intermediate product of the fermentation process of butanol production. By eliminating the separation and purification processes, using ABE directly in diesel blends has the potential of greatly decreasing the overall cost for fuel production. This could lead to a vast commercial use of ABE-diesel blends on the market. Much research has been done in the past five years concerning spray and combustion processes of both neat ABE and ABE-diesel mixtures. Additionally, different compositions of ABE mixtures had been characterized with a similar experimental approach.

Wide Distillation Fuel (WDF), with a distillation range from Initial Boiling Point of gasoline to Final Boiling Point of diesel, can be easily gained directly by blending diesel with gasoline. However, the reduced auto-ignitability of WDF could lead to higher HC emissions. Polyoxymethylene Dimethyl Ethers (PODE), with good volatility and oxygen content of up to 49%, have great potential to improve combustion and emission characteristics, especially for soot reduction. Experiments were carried out in a light-duty four-cylinder diesel engine fueled with neat diesel, gasoline/diesel blends (GD), GD/PODE blends (GDP) and the combustion and emission characteristics were carefully examined. Results showed that GDP had the lowest PM emission and diesel had the poorest one among the three fuels. Due to the addition of gasoline and the relatively poor ignitability, GD had lower combustion efficiency and higher Soluble Organic Fraction (SOF) emissions than diesel.

An air-cooled, four-stroke, 125 cc electronic gasoline fuel injection SI engine for motorcycles is altered to burn ethanol fuel. The effects of nozzle orifice size, fuel injection duration, spark timing and the excess air/ fuel ratio on engine power output, fuel and energy consumptions and engine exhaust emission levels are studied on an engine test bed. The results show that the maximum engine power output is increased by 5.4% and the maximum torque output is increased by 1.9% with the ethanol fuel in comparison with the baseline. At full load and 7000 r/min, HC emission is decreased by 38% and CO emission is decreased 46% on average over the whole engine speed range. However, NOx levels are increased to meet the maximum power output. The experiments of the spark timing show that the levels of HC and NOx emission are decreased markedly by the delay of spark timing.

The correlations between the physical properties and autoignition parameters of several alternate fuels have been examined. The fuels are DF-2 and its blends with petroleum derived fuels, coal derived fuels, shale derived fuels, high aromatic naphtha sun-flower oils, methanol and ethanol. A total of eighteen existing correlations are discussed. An emphasis is made on the suitability of each of the correlations for the development of electronic controls for diesel engines when run on alternate fuels. A new correlation has been developed between the cetane number of the fuels and its kinematic viscosity and specific gravity.

Biodiesel has been widely accepted as an alternative for fossil-derived diesel fuel for use in compression ignition (CI) engines. Poor oxidative stability and cold flow properties restrict the use of biodiesel beyond current B20 blend levels (20% biodiesel in 80% ULSD) for vehicle applications. Maintaining the properties of B20 as specified by ASTM D7476-08 is important because, once out of spec, B20 may cause injector coke formation, fuel filter plugging, increased exhaust emissions, and overall loss of engine performance. While the properties of fresh B20 may be within the specifications, under engine operating and longer storage conditions B20 could deteriorate. In a diesel engine, the fuel that goes to the injector and does not enter the cylinder is recycled back to the fuel tank. The re-circulated fuel returns to the fuel tank at an elevate temperature, which can cause thermal oxidation.

Polyoxymethylene Dimethyl Ether (PODEn) is a promising green additive to diesel fuel, owing to the unique chemical structure (CH3O[CH2O]nCH3, n≥2) and high cetane number. Together with the general wide-distillation fuel (WDF), which has an attractive potential to reduce the cost of production of vehicle fuel, the oxygenated WDF with PODEn can help achieve a high efficiency and low emissions of soot, NOx, HC, and CO simultaneously. In this paper, the first detailed reaction mechanism (225 species, 1082 reactions) which can describe the ignition characteristics of PODE1 and PODE3 at low temperature was developed.

The focus of this study is to determine the effect of using B-20 (a blend of 20% soybean methyl ester biodiesel and 80% ultra low sulfur diesel fuel) on the combustion process, performance and exhaust emissions in a High Speed Direct Injection (HSDI) diesel engine equipped with a common rail injection system. The engine was operated under simulated turbocharged conditions with 3-bar indicated mean effective pressure and 1500 rpm engine speed. The experiments covered a wide range of injection pressures and EGR rates. The rate of heat release trace has been analyzed in details to determine the effect of the properties of biodiesel on auto ignition and combustion processes and their impact on engine out emissions. The results and the conclusions are supported by a statistical analysis of data that provides a quantitative significance of the effects of the two fuels on engine out emissions.

The effects of different blends of Soybean Methyl Ester (biodiesel) and ultra low sulfur diesel (ULSD) fuel: B-00 (ULSD), B-20, B-40, B-60, B-80 and B-100 (biodiesel); on autoignition, combustion, performance, and engine out emissions of different species including particulate matter (PM) in the exhaust, were investigated in a single-cylinder, high speed direct injection (HSDI) diesel engine equipped with a common rail injection system. The engine was operated at 1500 rpm under simulated turbocharged conditions at 5 bar IMEP load with varied injection pressures at a medium swirl of 3.77 w ithout EGR. Analysis of test results was done to determine the role of biodiesel percentage in the fuel blend on the basic thermodynamic and combustion processes under fuel injection pressures ranging from 600 bar to 1200 bar.

The ethanol has potential to be a renewable alternative fuel for internal combustion engines and contributes to lower global CO2 emission. In this study, vegetable methyl ester is added in the ethanol-diesel fuel to prevent separation of the ethanol from diesel, thus the ethanol blend ratio can be set up to 30% in volume. This work pays more attention on its spray, effects of the ethanol percentage on the detailed PM components. To investigate the spray behavior of ethanol, diesel and their blends, experiments in a constant volume chamber were carried out combining numerical simulation. Properties of the ethanol-diesel blended fuels were obtained through some measurements and empirical calculations. The breakup sub-model, Wave-KH model considering the blend fuel properties were adopted in an engine simulation code KIVA-3V. The simulation had a good agreement with experiments.

In this study, an experimental investigation was conducted using a direct injection single-cylinder diesel engine equipped with a test common rail fuel injection system to clarify how dimethyl ether (DME) injection characteristics affect the heat release and exhaust emissions. For that purpose the common rail fuel injection system (injection pressure: 15 MPa) and injection nozzle (0.55 × 5-holes, 0.70 × 3-holes, same total holes area) have been used for the test. First, to characterize the effect of DME physical properties on the macroscopic spray behavior: injection quantity, injection rate, penetration, cone angle, volume were measured using high-pressure injection chamber (pressure: 4MPa). In order to clarify effects of the injection process on HC, CO, and NOx emissions, as well as the rate of heat release were investigated by single-cylinder engine test. The effects of the injection rate and swirl ratio on exhaust emissions and heat release were also investigated.

Octane number (ON) and octane sensitivity (S), the fuel anti-knock indices, are critical for the design of advanced jet ignition engines. In this study, ten fuels with different research octane number (RON) and varying S were formulated based on ethanol reference fuels (ERFs) to investigate the effect of S on combustion of jet ignition engine. To fully understand S effects, the combustion characteristics under EGR dilution and lean burn were further investigated. The results indicated that increasing S resulted in higher reactivity with shorter ignition delay and combustion duration. The increase of reactivity led to heavier knocking intensity. The competition between the flame speed and the reactivity of the mixture determined the auto-ignition fraction of mixture and the knocking onset crank angle as S varied. Medium S (S=3) was helpful to improve the combustion speed, reduce the auto-ignition fraction of mixture and retard the knocking onset crank angle.

Fuel quality has a significant influence on the combustion engine operation. In recent years the increasing concerns about environmental protection, energy saving, energy security and the requirements of protecting fuel injection and aftertreatment systems have been major driving forces for the Chinese fuel specification evolution. The major property changes in the evolution of Chinese national gasoline and diesel standards are introduced and the reasons behind these changes are analyzed in this paper. The gasoline fuel development from State I to State VI-B involved a decrease of sulfur, manganese, olefins, aromatics and benzene content. The diesel fuel quality improvement from State I to State VI included achieving low sulfur fuels and a cetane number (CN) increase. Provincial fuel standards, stricter than corresponding national standards, were implemented in economically developed areas in the past.

Ammonia and methanol are both future fuels with carbon-neutral potential. Ammonia has a high octane number, a slow flame speed, and a narrow ignition limit, while methanol has a fast flame speed with complementary combustion characteristics but is more likely to lead to pre-ignition and knock. In this paper, the combustion and emission characteristics of ammonia-methanol solution in a high compression ratio spark ignition engine are investigated. The experimental results show that the peak in-cylinder pressure and peak heat release rate of the engine when using ammonia-methanol solution are lower and the combustion phase is retarded compared with using methanol at the same spark timing conditions. Using ammonia-methanol solution in the engine resulted in a more ideal combustion phase than that of gasoline, leading to an increase in indicated thermal efficiency of more than 0.6% and a wider range of efficient operating conditions.

The increasing interest and requirement for improved electronic engine control during the last few decades, has led to the implementation of several different sensor technologies. The process of utilizing the spark plug as a combustion probe to monitor the different combustion related parameters such as knock, misfire, Ignition timing, and air-fuel ratio have been the subject of research for some time now. The air-fuel ratio is one of the most important engine operating parameters that has an impact on the combustion process, engine-out emissions, fuel economy, indicated mean effective pressure and exhaust gas composition and temperature. Furthermore, air-fuel ratio affects the ion produced during flame kernel initiation and post flame propagation. In this paper, an investigation is made to determine the effect of air-fuel ratio on ion current, using gasoline and methane under different spark plug designs and engine operating conditions.

As diesel emission regulations continue to increase, the use of exhaust aftertreatment systems containing, for example the diesel oxidation catalyst (DOC) and diesel particulate filter (DPF) will become necessary in order to meet these stringent emission requirements. The addition of a DOC and DPF in conjunction with utilizing biodiesel fuels requires extensive research to study the implications that biodiesel blends have on emissions as well as to examine the effect on aftertreatment devices. The proceeding work discusses results from a 2006 VM Motori four-cylinder 2.8L direct injection diesel engine coupled with a diesel oxidation catalyst and catalyzed diesel particulate filter. Tests were done using ultra low sulfur diesel fuel blended with 20% choice white grease biodiesel fuel to evaluate the effects of biodiesel emission products on the performance and effectiveness of the aftertreatment devices and the effect of low temperature combustion modes.

The combustion characteristics and soot emissions of three types of fuels were studied in a high pressure and temperature vessel. In order to achieve better volatility, proper cetane number and high oxygen content, the newly designed WDEP fuel was proposed and investigated. It is composed of wide distillation fuel (WD), PODE3-6 mixture (PODEn) and ethanol. For comparison, the test on WD and the mixture of PODEn-ethanol (EP) are also conducted. OH* chemiluminescence during the combustion was measured and instantaneous PLII was also applied to reveal the soot distribution. Abel transformation was adopted to calculate the total soot of axisymmetric flame. The results show that WDEP has similar ignition delays and flame lift-off lengths to those of WD at 870-920 K. But the initial ignition locations of WDEP flame in different cycles were more concentrated, particularly under the condition of low oxygen atmosphere.

Homogeneous Charge Induced Ignition (HCII) combustion is believed to be a promising approach to achieve clean and high efficiency combustion. HCII can be realized by using port-injection of the high-volatile fuel (gasoline) to prepare in-cylinder homogeneous charge and direct injection of the high-ignitable fuel (diesel) near the top dead center to control the start of combustion. In the current study, a numerical study was carried out to understand the mixing and auto-ignition process in HCII combustion. A multicomponent chemical kinetic mechanism for gasoline and diesel, consisting of n-heptane, iso-octane, ethanol, toluene, diisobutylene and n-decane, has been developed for predicting their ignition and oxidation. The final mechanism consists of 104 species and 398 reactions. This mechanism was validated with the experimental data of ignition delay times and laminar flame speeds for each component and real transportation fuels.