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Early injection timing is an effective measure of pre-mixture formation for diesel low-temperature combustion. Three algebraic subgrid models (Smagorinsky model, dynamic Smagorinsky model and WALE model) and one-equation kinetic energy turbulent model using modified TAB breakup model (MTAB model) have been implemented into KIVA3V code to make a detailed large eddy simulation of the atomization and evaporation processes of early injection timing in a constant volume chamber and a Ford high-speed direct-injection diesel engine. The results show that the predictive vapor mass fraction and liquid penetration using LES is in good agreement with the experiment results. In combustion chamber, the sub-grid turbulent kinetic energy and viscosity using LES are less than with the RANS models, and following the increasing time, the sub-grid turbulent kinetic energy and viscosity also increase and are concentrated on the spray area.