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The urban mobility electrification has been proposed as the main solution to the vehicle emission issues in the next years. However, internal combustion engines have still great potential to decarbonize the transport sector through the use of low/zero-carbon fuels. Alcohols such us methanol, have long been considered attractive alternative fuels for spark ignition engines. They have properties similar to those of gasoline, are easy to transport and store. Recently, great attention has been devoted to gaseous fuels that can be used in existing engine after minor modification allowing to drastically reduce the pollutant emissions. In this regard, this study tries to provide an overview on the use of alternative fuels, both liquid and gaseous in spark ignition engines, highlighting the benefits as well as the criticalities. The investigation was carried out on a small displacement spark ignition engine capable to operate both in port fuel and direct injection mode.

Internal combustion engines performance greatly depends on the air-fuel mixture formation and combustion processes. In gasoline direct injection (GDI) engines, in particular, the impact of the liquid spray on the piston or cylinder walls is a key factor, especially if mixture formation occurs under the so-called wall-guided mode. Impact causes droplets rebound and/or deposition of a liquid film (wallfilm). After being rebounded, droplets undergo what is called secondary atomization. The wallfilm may remain of no negligible size, so that fuel vapor rich zones form around it leading to so-called pool-flames (flames placed in the piston pit), hence to unburned hydrocarbons (HC) and particulate matter (PM) formation. A basic study of the spray-wall interaction is here performed by directing a multi-hole GDI spray against a real shape engine piston, possibly heated, under standard air conditions.

The use of methane as supplement to liquid fuel is one of the solution proposed for the reduction of the internal combustion engine pollutant emissions. Its intrinsic properties as the high knocking resistance and the low carbon content makes methane the most promising clean fuel. The dual fuel combustion mode allows improving the methane combustion acting mainly on the methane slow burning velocity and allowing lean burn combustion mode. An experimental investigation was carried out to study the methane-gasoline dual fuel combustion. Methane was injected in combustion chamber (DI fuel) while gasoline was injected in the intake manifold (PFI fuel). The measurements were carried out in an optically accessible small single-cylinder four-stroke engine. It was equipped with the cylinder head of a commercial 250 cc motorcycles engine representative of the most popular two-wheel vehicles in Europe.

In the perspective of a reduction of emissions and a rapid decarbonisation, especially for compression ignition engines, hydrogen plays a decisive role. The dual fuel technology is perfectly suited to the use of hydrogen, a fuel characterized by great energy potential. In fact, replacing, at the same energy content, the fossil fuel with a totally carbon free one, a significant reduction of the greenhouse gases, like carbon dioxide and total hydrocarbon, as well as of the particulate matter can be obtained. The dual fuel with indirect injection of gaseous fuel in the intake manifold, involves the problem of hydrogen autoignition. In order to avoid this difficulty, the optimal conditions for the injection of the incoming mixture into the cylinder were experimentally investigated. All combustion processes are carried out on a research engine with optical access. The engine speed has is set at 1500 rpm, while the EGR valve is deactivated.

The use of lean or ultra-lean ratios is an efficient and proven strategy to reduce fuel consumption and pollutant emissions. However, the lower fuel concentration in the cylinder hinders the mixture ignition, requiring greater energy to start the combustion. The prechamber is an efficient method to provide high energy favoring the ignition process. It presents the potential to reduce the emission levels and the fuel consumption, operating with lean burn mixtures and expressive combustion stability. In this paper the analysis of the combustion process of SI engines equipped with an innovative architecture and operating in different injection modes was described. In particular, the effect of the prechamber ignition on the engine stability and the efficiency was investigated in stoichiometric and lean-burn operation conditions. The activity was carried out in two parts.

The growing concerns on the emission of particles smaller than 23 nm, which are harmful to human health, lead to the necessity of introducing a regulation for these particles not yet included in the current emission standards. Considering that measurements of concentration of sub-23 nm particles are particularly sensitive to the sampling conditions, it is important to identify an effective assessment procedure. Aim of this paper is the characterization of the effect of the sampling conditions on sub-23 nm particles, emitted by PFI (port fuel injection) and DI (direct injection) spark ignition engines fueled with gasoline, ethanol and a mixture of ethanol and gasoline (E30). The experimental activity was carried out on a 250 cm3 displacement four stroke GDI and PFI single cylinder engines. The tests were conducted at 2000 rpm and 4000 rpm full load, representative of the homologation urban driving cycle.

An innovative quasi-dimensional multizone combustion model for the spray formation, combustion and emission formation analysis in DI diesel engines was assessed and applied to an optical single cylinder engine. The model, which has been recently presented by the authors, integrates a predictive non stationary 1D spray model developed by the Sandia National Laboratory, with a diagnostic multizone thermodynamic model. The 1D spray model is capable of predicting the equivalence ratio of the fuel during the mixing process, as well as the spray penetration. The multizone approach is based on the application of the mass and energy conservation laws to several homogeneous zones identified in the combustion chamber. A specific submodel is also implemented to simulate the dilution of the burned gases. Soot formation is modeled by an expression which derives from Kitamura et al.'s results, in which an explicit dependence on the local equivalence ratio is considered.

The application of more efficient compression ignition combustion concepts requires advancement in terms of fuel injection technologies. The injector nozzle is the most critical component of the whole injection system for its impact on the combustion process. It is characterized by the number of holes, diameter, internal shape, and opening angle. The reduction of the nozzle hole diameter seems the simplest way to promote the atomization process but the number of holes must be increased to keep constant the injected fuel mass. This logic has been applied to the development of a new generation of injectors. First, the tendency to increase the nozzle number and to reduce the diameter has led to the replacement of the nozzle with a circular plate. The vertical movement of the needle generates an annulus area for the fuel delivery on 360 degrees, so controlling the atomization as a function of the vertical plate position.

Data decomposition techniques have become a standard approach for the analysis of 2D imaging data originating from optically accessible internal combustion engines. In particular, the method of Proper Orthogonal Decomposition (POD) has proven to be a valuable tool for the evaluation of cycle-to-cycle variability based on luminous combustion imaging and particle image velocimetry (PIV) measurements. POD basically permits to characterize the dominant structures of the process under consideration. Recently, an alternative procedure based on Independent Component Analysis (ICA) has been introduced in the engine field. Unlike POD, the method of ICA identifies the patterns corresponding to physical processes that are statistically independent. In this work, a Group-ICA approach is applied to 2D cycle-resolved images of the luminosity emitted by the combustion process. The analysis is meant to characterize cyclic variability of a port fuel injection spark ignition (PFI SI) engine.

In the last years, even more attention was paid to the alternative fuels which can allow both reducing the fuel consumption and the pollutant emissions. Among gaseous fuels, methane is considered one of the most interesting in terms of engine application. It represents an immediate advantage over other hydrocarbon fuels leading to lower CO₂ emissions; if compared to gasoline, CH₄ has wider flammable limits and better anti-knock properties, but lower flame speed. The addition of H₂ to CH₄ can improve the already good qualities of methane and compensate its weak points. In this paper a comparison was carried out between CH₄ and different CH₄/H₂ mixtures. The measurements were carried out in an optically accessible small single-cylinder, Port Fuel Injection spark ignition (PFI SI), four-stroke engine. It was equipped with the cylinder head of a commercial 250 cc motorcycle engine representative of the most popular two-wheel vehicles in Europe.

Gasoline direct injection (GDI) allows knock tendency reduction in spark-ignition engines mainly due to the cooling effect of the in-cylinder fuel evaporation. However, the charge formation and thus the injection timing and strategies deeply affect the flame propagation and consequently the knock occurrence probability and intensity. In particular, split injection allows a reduction of knock intensity by inducing different AFR gradient and turbulent energy distribution. Present work investigates the tendency to knock of a GDI engine at 1500 rpm full load under different injection strategies, single and double injections, obtained delivering the same amount of gasoline in two equal parts, the first during intake, the second during compression stroke. In these conditions, conventional and non-conventional measurements are performed on a 4-stroke, 4-cylinder, turbocharged GDI engine endowed of optical accesses to the combustion chamber.

This paper reports experiments on a single-cylinder direct-injection compression ignition engine operating in premixed charge compression ignition (PCCI) combustion mode. The engine was fuelled with pure rapeseed methyl ester (RME) and bio-ethanol. RME was injected in the combustion chamber by common rail (CR) injection system at 800 bar and bio-ethanol in the intake manifold by commercial port fuel injection system at 3.5 bar. The effects of different percentage of bio-ethanol were studied by means of both the in-cylinder heat release analysis and the high-speed UV-visible chemiluminescence visualization. The pollutant formation and exhaust emissions of the engine operating in dual fuel mode were evaluated. The increase of the bio-ethanol content improved the brake thermal efficiency slightly even if the brake fuel consumption increased. However, the choice to inject two biofuels decreases both the smoke opacity and NOx concentration.

Interest on the issue of diesel injector nozzle deposits is rising in the last years due to its effects on engine performance. The alteration of nozzles geometry can cause a difference in fuel mass flow and influence smoke emission. Investigation on the effects of nozzle coking in a diesel injector has been the topic of this paper. The experiments have been carried out in a single cylinder optical engine operating in premixed mode. The head of a Euro 5 production engine has been mounted on an elongated cylinder and the production CR injection system has been used. A sapphire window has been set in the piston head in order to have visible access to phenomena occurring in the combustion chamber. Three injectors with decreasing flow number (FN) have been tested. Engine has been fed with commercial diesel fuel. High spatial and temporal resolution camera has been used for the acquisition of in-cylinder injection and combustion images.

Methane supply in diesel engines operating in dual fuel mode has demonstrated to be effective for the reduction of particulate matter and nitric oxides emissions from this type of engine. In particular, methane is injected into the intake manifold to form a premixed charge with air, while a reduced amount of diesel oil is still directly injected to ignite the mixture inside the cylinder. As a matter of fact, the liquid fuel burns following the usual diffusive combustion, so activating the gaseous fuel oxidation in a premixed flame. Clearly, the whole combustion process appears to be more complex to be described in a CFD simulation, mainly because it is not always possible to select in the 3-dimensional codes a different combustion model for each fuel and, also, because other issues arise from the interaction of the two fuels.

Hydrogen is an energy vector with low environmental impact and will play a significant role in the future of transportation. Converting a spark ignition (SI) engine powered vehicle to H2 fueling has several challenges, but was overall found to be feasible with contained cost. Fuel delivery directly to the cylinder features numerous advantages and can successfully mitigate backfire, a major issue for H2 SI engines. Within this context, the present work investigated the specific fuel system requirements in port- (PFI) and direct-injection (DI) configurations. A 0D/1D model was used to simulate engine operating characteristics in several working conditions. As expected, the model predicted significant improvement of volumetric efficiency for DI compared to the PFI configuration. Boosting requirements were predicted to be at levels quite close to those for gasoline fueling.

In the context of increasing efforts towards zero emissions transport, hydrogen represents a valid alternative to electric powertrains. Spark ignition (SI) engines are well suited for this alternative fuel and its specific application requires relatively minor changes with respect to added components. Limited range is one of the main issues with hydrogen as an energy source for transportation, due to its low energy density. The present study looked at the possibility of converting a small size passenger car powered by a turbocharged SI unit to hydrogen fueling. Taking the electric version of the vehicle as benchmark, the initial evaluation of the hydrogen SI alternative appears feasible with an additional gas container comparable in size to the gasoline tank. As a result, further investigation was aimed at actual engine operation in port fuel injection mode, with a focus on rated power and injection phasing effects.

Converting spark ignition (SI) engines to H2 fueling is an attractive route for achieving zero carbon transportation and solving the legacy fleet problem in a future scenario in which electric powertrains will dominate. The current paper looks at a small size passenger car in terms of vehicle dynamics and electronic control unit (ECU) remapping requirements, in the hypothesis of using H2 as a gasoline replacement. One major issue with the use of H2 in port fuel injection (PFI) engines is that it causes reduced volumetric efficiency and thus low power. The vehicle considered for the study features turbocharging and therefore complete or partial recuperation of lost power is possible. Other specific requirements such as injection phasing were also under scrutiny, especially as PFI was hypothesized to maximize cost effectiveness. A 0D/1D model was used for simulating engine running characteristics as well as vehicle dynamics.

In this paper, the modifications realized to make optically accessible a commercial high performance spark ignition and direct injection (DI) 4-cylinder engine are reported. The engine has been designed trying to keep as much as possible its thermo-fluid dynamic configuration in order to maintain its performance and emissions. Two optical accesses have been realized in order to interfere as little as possible with the combustion chamber geometry. A first optical access has been achieved in the piston head and a second by inserting an endoscopic fiber probe in the head. Preliminary results demonstrated that this optical assessment responds to the design targets and allowed a characterization of a commercial GDI engine working with homogeneous and stratified charge mode.

Increasing demands on emissions reduction and efficiency encouraged a progressive introduction of cleaner combustion concepts. "Advanced" diesel combustions offer a high potential for simultaneous reduction of both NOx and soot within the engine through high inlet charge dilution and mixture homogenization. However, the potential benefits of these combustions in terms of emissions are counterbalanced by their high sensitivity to in-cylinder thermodynamic conditions. This sensitivity makes the engines require closed loop combustion control with real-time information about combustion quality. The parameter widely considered as the most important for the evaluation of the combustion quality in internal combustion engines is the cylinder pressure. However, this kind of measure involves an intrusive approach to the cylinder, expensive sensors and a special mounting process.

This work reports on the application of spectroscopic measurements coupled with data processing techniques in order to study, in terms of spectral emissions, the dynamic of the HCCI (Homogeneous charge compression ignition) combustion that occurs inside the combustion chamber of an optically accessible direct injection Diesel engine. A pre-processing of the recorded spectra is required for a correct analysis. The procedure of pre-processing consists of two main steps, that is: noise filtering with a technique based on the POD (Proper Orthogonal Decomposition); estimate and subtraction of the baseline. The analysis of the dynamics of the recorded spectra was carried out by the estimates of the synchronous and asynchronous 2D correlation spectra.